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You searched for subject:(tetraarylborate anions). Showing records 1 – 2 of 2 total matches.

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1. Broeke, J. (Joep) van den. Highly Fluorous Tetraarylborate Anions : Versatile Counterions for Homogeneous Catalysis in Novel Reaction Media.

Degree: 2003, University Utrecht

The recycling of homogeneous catalysts is highly desirable from both an environmental and an economical point of view. However, the fact that catalysts and products are distributed homogeneously throughout the reaction mixture hampers catalyst separation. An elegant approach facilitating catalyst recovery is its immobilisation in a liquid support. Three solvent systems that have shown promise in this respect are fluorous biphasic solvent systems, supercritical carbon dioxide and ionic liquids. This thesis addresses the development of highly fluorous tetraarylborate anions which can be employed as such, or in combination with fluorous ligands, to enhance the solubility and performance of ionic catalysts in perfluorinated solvents and supercritical carbon dioxide. Furthermore, these anions have been used in the design of ionic liquids with unprecedented physical properties.

Subjects/Keywords: homogeneous catalysis; tetraarylborate anions; fluorous biphasic catalyst separation; supercritical carbon dioxide; ionic liquids

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APA · Chicago · MLA · Vancouver · CSE | Export to Zotero / EndNote / Reference Manager

APA (6th Edition):

Broeke, J. (. v. d. (2003). Highly Fluorous Tetraarylborate Anions : Versatile Counterions for Homogeneous Catalysis in Novel Reaction Media. (Doctoral Dissertation). University Utrecht. Retrieved from https://dspace.library.uu.nl/handle/1874/771 ; URN:NBN:NL:UI:10-1874-771 ; 1874/771 ; URN:NBN:NL:UI:10-1874-771 ; https://dspace.library.uu.nl/handle/1874/771

Chicago Manual of Style (16th Edition):

Broeke, J (Joep) van den. “Highly Fluorous Tetraarylborate Anions : Versatile Counterions for Homogeneous Catalysis in Novel Reaction Media.” 2003. Doctoral Dissertation, University Utrecht. Accessed January 18, 2021. https://dspace.library.uu.nl/handle/1874/771 ; URN:NBN:NL:UI:10-1874-771 ; 1874/771 ; URN:NBN:NL:UI:10-1874-771 ; https://dspace.library.uu.nl/handle/1874/771.

MLA Handbook (7th Edition):

Broeke, J (Joep) van den. “Highly Fluorous Tetraarylborate Anions : Versatile Counterions for Homogeneous Catalysis in Novel Reaction Media.” 2003. Web. 18 Jan 2021.

Vancouver:

Broeke J(vd. Highly Fluorous Tetraarylborate Anions : Versatile Counterions for Homogeneous Catalysis in Novel Reaction Media. [Internet] [Doctoral dissertation]. University Utrecht; 2003. [cited 2021 Jan 18]. Available from: https://dspace.library.uu.nl/handle/1874/771 ; URN:NBN:NL:UI:10-1874-771 ; 1874/771 ; URN:NBN:NL:UI:10-1874-771 ; https://dspace.library.uu.nl/handle/1874/771.

Council of Science Editors:

Broeke J(vd. Highly Fluorous Tetraarylborate Anions : Versatile Counterions for Homogeneous Catalysis in Novel Reaction Media. [Doctoral Dissertation]. University Utrecht; 2003. Available from: https://dspace.library.uu.nl/handle/1874/771 ; URN:NBN:NL:UI:10-1874-771 ; 1874/771 ; URN:NBN:NL:UI:10-1874-771 ; https://dspace.library.uu.nl/handle/1874/771


Universiteit Utrecht

2. Broeke, J. (Joep) van den. Highly Fluorous Tetraarylborate Anions : Versatile Counterions for Homogeneous Catalysis in Novel Reaction Media.

Degree: 2003, Universiteit Utrecht

The recycling of homogeneous catalysts is highly desirable from both an environmental and an economical point of view. However, the fact that catalysts and products are distributed homogeneously throughout the reaction mixture hampers catalyst separation. An elegant approach facilitating catalyst recovery is its immobilisation in a liquid support. Three solvent systems that have shown promise in this respect are fluorous biphasic solvent systems, supercritical carbon dioxide and ionic liquids. This thesis addresses the development of highly fluorous tetraarylborate anions which can be employed as such, or in combination with fluorous ligands, to enhance the solubility and performance of ionic catalysts in perfluorinated solvents and supercritical carbon dioxide. Furthermore, these anions have been used in the design of ionic liquids with unprecedented physical properties.

Subjects/Keywords: Scheikunde; homogeneous catalysis; tetraarylborate anions; fluorous biphasic catalyst separation; supercritical carbon dioxide; ionic liquids

Record DetailsSimilar RecordsGoogle PlusoneFacebookTwitterCiteULikeMendeleyreddit

APA · Chicago · MLA · Vancouver · CSE | Export to Zotero / EndNote / Reference Manager

APA (6th Edition):

Broeke, J. (. v. d. (2003). Highly Fluorous Tetraarylborate Anions : Versatile Counterions for Homogeneous Catalysis in Novel Reaction Media. (Doctoral Dissertation). Universiteit Utrecht. Retrieved from http://dspace.library.uu.nl:8080/handle/1874/771

Chicago Manual of Style (16th Edition):

Broeke, J (Joep) van den. “Highly Fluorous Tetraarylborate Anions : Versatile Counterions for Homogeneous Catalysis in Novel Reaction Media.” 2003. Doctoral Dissertation, Universiteit Utrecht. Accessed January 18, 2021. http://dspace.library.uu.nl:8080/handle/1874/771.

MLA Handbook (7th Edition):

Broeke, J (Joep) van den. “Highly Fluorous Tetraarylborate Anions : Versatile Counterions for Homogeneous Catalysis in Novel Reaction Media.” 2003. Web. 18 Jan 2021.

Vancouver:

Broeke J(vd. Highly Fluorous Tetraarylborate Anions : Versatile Counterions for Homogeneous Catalysis in Novel Reaction Media. [Internet] [Doctoral dissertation]. Universiteit Utrecht; 2003. [cited 2021 Jan 18]. Available from: http://dspace.library.uu.nl:8080/handle/1874/771.

Council of Science Editors:

Broeke J(vd. Highly Fluorous Tetraarylborate Anions : Versatile Counterions for Homogeneous Catalysis in Novel Reaction Media. [Doctoral Dissertation]. Universiteit Utrecht; 2003. Available from: http://dspace.library.uu.nl:8080/handle/1874/771

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