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Kansas State University
1.
Arrieta-Martinez, Melania.
Biochemical
and rheological properties of waxy wheat flour dough.
Degree: MS, Department of Grain Science and
Industry, 2016, Kansas State University
URL: http://hdl.handle.net/2097/34455
► The rheological properties of two waxy and two normal wheat flours were investigated and the observed differences between them were explained by biochemical analysis. Protein…
(more)
▼ The
rheological properties of two waxy and two normal
wheat flours were investigated and the observed differences between
them were explained by biochemical analysis. Protein analysis
showed that waxy flour had lower polymeric to monomeric ratio (0.70
and 0.58 for waxy flour compared to 0.75 and 0.76 for normal flour)
and higher gliadin content in waxy wheat dough (43.9 and 47.3 for
waxy wheat dough compared to 41.0 and 41.7 for normal wheat dough).
Waxy flour had high amounts of insoluble (IPP) and unextractable
(UPP) polymeric protein despite the poor dough forming
properties
of the waxy flours, contrary to previous correlations made between
IPP, UPP and dough strength. Gluten index determination showed a
clear difference between waxy and normal flour; there was no gluten
aggregation when the waxy samples were tested. The determination of
gluten index done on a variety of water washed flour samples
indicated that the water-extractable fraction may contain compounds
that affect gluten aggregation. HPLC analysis coupled with
arabinose/xylose ratio and viscosity determination of the water
extractable portion of the flour indicated that water extractable
arabinoxylans (WEAX) in waxy wheat flour were different in
composition and conformation. Further research is needed to
determine if they could be responsible for the lack of gluten
aggregation in waxy flour.
Advisors/Committee Members: Yong-Cheng Shi
Jon Faubion.
Subjects/Keywords: waxy; dough; wheat flour; rheological
properties
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APA ·
Chicago ·
MLA ·
Vancouver ·
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APA (6th Edition):
Arrieta-Martinez, M. (2016). Biochemical
and rheological properties of waxy wheat flour dough. (Masters Thesis). Kansas State University. Retrieved from http://hdl.handle.net/2097/34455
Chicago Manual of Style (16th Edition):
Arrieta-Martinez, Melania. “Biochemical
and rheological properties of waxy wheat flour dough.” 2016. Masters Thesis, Kansas State University. Accessed March 04, 2021.
http://hdl.handle.net/2097/34455.
MLA Handbook (7th Edition):
Arrieta-Martinez, Melania. “Biochemical
and rheological properties of waxy wheat flour dough.” 2016. Web. 04 Mar 2021.
Vancouver:
Arrieta-Martinez M. Biochemical
and rheological properties of waxy wheat flour dough. [Internet] [Masters thesis]. Kansas State University; 2016. [cited 2021 Mar 04].
Available from: http://hdl.handle.net/2097/34455.
Council of Science Editors:
Arrieta-Martinez M. Biochemical
and rheological properties of waxy wheat flour dough. [Masters Thesis]. Kansas State University; 2016. Available from: http://hdl.handle.net/2097/34455

Penn State University
2.
Gholizadeh Vayghan, Asghar.
CHARACTERIZATION OF THE RHEOLOGICAL AND SWELLING PROPERTIES OF SYNTHETIC ALKALI SILICATE GELS IN ORDER TO PREDICT THEIR BEHAVIOR IN ASR DAMAGED CONCRETE.
Degree: 2017, Penn State University
URL: https://submit-etda.libraries.psu.edu/catalog/14066axg402
► Alkali–silica reaction (ASR) is a major concrete durability concern that is responsible for the deterioration of concrete infrastructure in the world. The resultant of the…
(more)
▼ Alkali–silica reaction (ASR) is a major concrete durability concern that is responsible for the deterioration of concrete infrastructure in the world. The resultant of the reaction between the cement alkali hydroxides and the metastable silicates in the aggregates is a hygroscopic and expansive alkali–silicate gel (referred to as ASR gel in this document). The swelling behavior of ASR gels determines the extent of damage to concrete structures and, as such, mitigation of ASR relies on understanding these gels and finding ways to prevent them either from formation, or from swelling after formation. This dissertation focuses on the synthesis and characterization of ASR gels with wide ranges of compositions similar to what has been reported for the filed ASR gels in the literature. The experimental work consisted of three phases as follow.
Phase I: Investigation of rheology, chemistry and physics of ASR gels produced through sol–method. Inspired from the existing literature, two sol–gel methods have been developed for the synthesis of ASR gels. The
rheological (primarily gelation time, yield stress, and equilibrium stress), chemical (pore solution pH, pore solution composition, osmotic pressure, solid phase composition, stoichiometry of gelation reactions) and physical (evaporable water, solid content, etc.)
properties of synthetic ASR gels have been extensively investigated in this phase. Ca/Si, Na/Si and K/Si, and water content were considered as the main chemical composition variables. In order to investigate the suppressing effects of lithium on the swelling
properties of ASR gels, the gels were added with lithium in a part of the experimental program. The results strongly suggested that Ca/Si has a positive effect on the yield stress of the gels and their rate of gelation. Na/Si was found to have a decreasing effect on the yield stress and gelation rate (especially at low Ca/Si levels). K/Si and Li/Si had second–order (i.e., polynomial) effects on the yield stress of the gels, causing a significant drop in this parameter followed by some increase as they approached their upper values. Na/Si and K/Si were both found contribute to the osmotic potential of the ASR gels, while increase in Ca/Si generally led to a drop in this parameter. The presence of all components (Ca, Na, and K) were found to contribute to the pH of the gels’ pore solution, and Ca/Si and Na/Si showed a synergistic effect on this parameter. Lithium, on the other hand, was found to be able to drop the OH- concentration of the pore solution by a factor of five in the case of high–sodium gels, which could partially explain its ASR mitigating effect.
Phase II: Investigation of the free and restrained swelling behavior, hydrophilic potential and viscoelastic
properties of ASR gels produced through the “paste method”. 20 gel compositions were selected (using the central composite design method) with Ca/Si, Na/Si and K/Si molar ratios varying in the ranges (0.05–0.5), (0.1–1.0) and (0.0–0.3), respectively. The gels were produced by batching…
Advisors/Committee Members: Farshad Rajabipour, Dissertation Advisor/Co-Advisor, Farshad Rajabipour, Committee Chair/Co-Chair, William D. Burgos, Committee Member, Carlo G. Pantano, Committee Member, James L. Rosenberger, Outside Member.
Subjects/Keywords: Alkali-silica reaction; Alkali-silicate gels; Swelling properties; Rheological properties
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APA (6th Edition):
Gholizadeh Vayghan, A. (2017). CHARACTERIZATION OF THE RHEOLOGICAL AND SWELLING PROPERTIES OF SYNTHETIC ALKALI SILICATE GELS IN ORDER TO PREDICT THEIR BEHAVIOR IN ASR DAMAGED CONCRETE. (Thesis). Penn State University. Retrieved from https://submit-etda.libraries.psu.edu/catalog/14066axg402
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Gholizadeh Vayghan, Asghar. “CHARACTERIZATION OF THE RHEOLOGICAL AND SWELLING PROPERTIES OF SYNTHETIC ALKALI SILICATE GELS IN ORDER TO PREDICT THEIR BEHAVIOR IN ASR DAMAGED CONCRETE.” 2017. Thesis, Penn State University. Accessed March 04, 2021.
https://submit-etda.libraries.psu.edu/catalog/14066axg402.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Gholizadeh Vayghan, Asghar. “CHARACTERIZATION OF THE RHEOLOGICAL AND SWELLING PROPERTIES OF SYNTHETIC ALKALI SILICATE GELS IN ORDER TO PREDICT THEIR BEHAVIOR IN ASR DAMAGED CONCRETE.” 2017. Web. 04 Mar 2021.
Vancouver:
Gholizadeh Vayghan A. CHARACTERIZATION OF THE RHEOLOGICAL AND SWELLING PROPERTIES OF SYNTHETIC ALKALI SILICATE GELS IN ORDER TO PREDICT THEIR BEHAVIOR IN ASR DAMAGED CONCRETE. [Internet] [Thesis]. Penn State University; 2017. [cited 2021 Mar 04].
Available from: https://submit-etda.libraries.psu.edu/catalog/14066axg402.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Gholizadeh Vayghan A. CHARACTERIZATION OF THE RHEOLOGICAL AND SWELLING PROPERTIES OF SYNTHETIC ALKALI SILICATE GELS IN ORDER TO PREDICT THEIR BEHAVIOR IN ASR DAMAGED CONCRETE. [Thesis]. Penn State University; 2017. Available from: https://submit-etda.libraries.psu.edu/catalog/14066axg402
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

University of Manitoba
3.
Johnson, Praveen.
Characterizing the disintegration behavior of distiller’s spent grain compacts during drying in superheated steam.
Degree: Biosystems Engineering, 2010, University of Manitoba
URL: http://hdl.handle.net/1993/30286
► Biomass such as spent grain is difficult to dry when it is in the slurry form. Proposed industrial solutions are to compact wet biomass first…
(more)
▼ Biomass such as spent grain is difficult to dry when it is in the slurry form. Proposed industrial solutions are to compact wet biomass first and then dry it. Compaction develops desired granular form and increases surface area for drying but also brings new technical challenges. Superheated steam (SS) drying is advantageous over hot-air drying as it is more energy efficient. A problem associated SS drying is the initial condensation leading to disintegration of biomass compacts. The current research investigates the disintegration characteristics of distiller’s spent grain (DSG) compacts while being dried in SS. The study focuses on the DSG flowability, densification characteristics and disintegration behavior of DSG compacts as affected by SS drying conditions, soluble content and particle size distribution (PSD).
DSG fractions with particle sizes from 300 to 850 µm were dried in SS at 150°C and hot-air at 45 and 150°C. Under these drying conditions bulk density and angle of repose (AOR) varied from 0.379 to 0.435 g/cm3 and 46.0 to 50.4°, respectively. The stress-relaxation data obtained during the compaction of DSG at different levels of compressive pressure (60.3-135.7 MPa), initial moisture content (15, 20 and 25% wet basis- wb) and soluble content (15 and 30%) were normalized and analyzed to determine the asymptotic modulus (EA) of the compacts. The highest EA of 174 MPa was obtained for DSG compacts produced with a compressive force of 135.7 MPa, initial moisture of 25% wb and soluble content of 0%.
The percentage increase in volume of DSG compacts during drying in SS at 110 to 150°C temperature range was between 78 to 130%. A comparison between the physical
properties of SS dried and hot-air dried compacts revealed the role of SS in accelerating the release of mechanical energy stored in the compacts. An increase of dimensions and a considerable increase in the hardness and EA of the compacts was obtained by adding up to 70% (w/w) solubles or by decreasing the PSD of wet distiller’s spent grain from d(0.9)=1283.6 to 812.8 µm. This study establishes that compaction of wet biomass followed by SS drying can lead to its effective utilization.
Advisors/Committee Members: Paliwal, Jitendra (Biosystems Engineering) Cenkowski, Stefan (Biosystems Engineering) (supervisor), Arntfield, Susan (Food Science) Kudra, Tadeusz (Biosystems Engineering) Tabil, Lope (University of Saskatchewan) (examiningcommittee).
Subjects/Keywords: Distiller’s spent grain; Superheated steam drying; Compacts; Physical properties; Rheological properties
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Johnson, P. (2010). Characterizing the disintegration behavior of distiller’s spent grain compacts during drying in superheated steam. (Thesis). University of Manitoba. Retrieved from http://hdl.handle.net/1993/30286
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Johnson, Praveen. “Characterizing the disintegration behavior of distiller’s spent grain compacts during drying in superheated steam.” 2010. Thesis, University of Manitoba. Accessed March 04, 2021.
http://hdl.handle.net/1993/30286.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Johnson, Praveen. “Characterizing the disintegration behavior of distiller’s spent grain compacts during drying in superheated steam.” 2010. Web. 04 Mar 2021.
Vancouver:
Johnson P. Characterizing the disintegration behavior of distiller’s spent grain compacts during drying in superheated steam. [Internet] [Thesis]. University of Manitoba; 2010. [cited 2021 Mar 04].
Available from: http://hdl.handle.net/1993/30286.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Johnson P. Characterizing the disintegration behavior of distiller’s spent grain compacts during drying in superheated steam. [Thesis]. University of Manitoba; 2010. Available from: http://hdl.handle.net/1993/30286
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

University of Georgia
4.
Sivanandan, Litha.
Characterization of soymilk produced by continuous flow high pressure throttling process.
Degree: 2014, University of Georgia
URL: http://hdl.handle.net/10724/24494
► Standard soymilk processing uses filtration or centrifugation step to remove coarse solids in the comminuted soy. The objectives were to produce soymilk from dehulled beans…
(more)
▼ Standard soymilk processing uses filtration or centrifugation step to remove coarse solids in the comminuted soy. The objectives were to produce soymilk from dehulled beans by Gaulin homogenizer or produce sterile soymilk using
microfluidizer-throttling or continuous flow high pressure throttling (CFHPT) to retain retaining all essential soybean solids. The soymilk was characterized for particle size distribution, rheological and ultra-structural properties, to establish an
empirical model to characterize the distribution of particle size of particles in the soymilk, and to evaluate the consumer acceptability. Whole dehulled soybeans were blanched, mixed with deionized water, and comminuted coarsely in a food-processor. An
intermediate comminution step in Megatron (process M) or Fitzmill (process F) or Stonemill (process S) was followed by homogenization at selected pressures using Gaulin homogenizer or microfluidizer-throttling or CFHPT system. The combined process M and
CFHPT treated samples at the highest pressure showed the smallest particle size and the highest apparent viscosity. All samples showed pseudoplastic flow behavior. Ultrastructural images elucidated particle microstructure in the soymilk and homogeneity
of suspended particles. The very small fat globules at highest CFHPT pressure treatment of process M were seen entrapped in the network and was uniformly distributed. Thus combined process M and the highest CFHPT pressure was considered the best
treatment. Therefore, the high pressure throttling process will allow utilization of the whole soybean to produce excellent quality soymilk with high emulsion stability. The increase in the CFHPT flow rate significantly affected size reduction of
particles of soymilk. The empirical models were established which can be used to predict the size of particles in soymilk, at different volume fractions, processed using high pressure throttling processes at various pressures and flow rates. Consumer
acceptability test showed that more research is needed to make a soymilk that appeal to the taste of the American consumer before the CFHPT process can be used commercially to produce soymilk. Thus, soymilk with all the essential solids can be made
available to the public and processors benefit from the high processing yields since none of the essential solids of the beans are discarded.
Subjects/Keywords: high pressure throttling; soymilk; particle size distribution; rheological properties; ultrastructural properties
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Sivanandan, L. (2014). Characterization of soymilk produced by continuous flow high pressure throttling process. (Thesis). University of Georgia. Retrieved from http://hdl.handle.net/10724/24494
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Sivanandan, Litha. “Characterization of soymilk produced by continuous flow high pressure throttling process.” 2014. Thesis, University of Georgia. Accessed March 04, 2021.
http://hdl.handle.net/10724/24494.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Sivanandan, Litha. “Characterization of soymilk produced by continuous flow high pressure throttling process.” 2014. Web. 04 Mar 2021.
Vancouver:
Sivanandan L. Characterization of soymilk produced by continuous flow high pressure throttling process. [Internet] [Thesis]. University of Georgia; 2014. [cited 2021 Mar 04].
Available from: http://hdl.handle.net/10724/24494.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Sivanandan L. Characterization of soymilk produced by continuous flow high pressure throttling process. [Thesis]. University of Georgia; 2014. Available from: http://hdl.handle.net/10724/24494
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

University of Alberta
5.
Lu, Xinyao.
Transglutaminase catalyzed amination of food protein and
peptides with biogenic amines: studies on functionality and
antioxidant activity.
Degree: MS, Department of Agricultural, Food, and Nutritional
Science, 2016, University of Alberta
URL: https://era.library.ualberta.ca/files/cbr86b377c
► There is a growing demand for innovative and affordable technologies in the food industry to modify ingredient functionality and to ensure product safety. Proteins are…
(more)
▼ There is a growing demand for innovative and
affordable technologies in the food industry to modify ingredient
functionality and to ensure product safety. Proteins are essential
components in many food systems, and their structure can be
modified in a variety of ways to control and improve functional
characteristics of a food system. The enzymatic modification of
proteins with transglutaminase is one such novel technology that
has a broad range of applications, and was the focus of this
research. In the first study of this research, hydrolyzed pea
protein were modified by microbial transglutaminase (MTGase) from
the Streptomyces mobaraensis species. Biologically active
(biogenic) amines histamine and tyramine were used as amine donor
substrates in this enzyme-catalyzed reaction. Conjugation of
biogenic amines and pea protein hydrolysates was achieved in the
presence of MTGase after 6 h of incubation at 37°C. Conjugation
progress was monitored by high performance liquid chromatography
and fluorescence spectroscopy. Seventy six percent of histamine was
covalently incorporated to protein hydrolysates by MTGase, thereby
reduced the concentration of undesirable biogenic amine. Also, the
MTGase-catalyzed introduction of tyramine into pea protein
hydrolysates substantially improved the antioxidant potential of
the newly formed conjugates. In the second study, porcine skin
gelatin was modified by MTGase-induced amination with tyramine in
an aqueous media at 50°C. Gelation and melting iii temperatures,
viscoelastic behaviour, as well as gelation rate and gel strength
of tyramine-gelatin conjugates and MTGase-cross-linked gelatin were
determined. MTGase-catalyzed cross-linking increased the gelation
and melting temperatures of the gel. Incorporation of tyramine via
MTGase did not change the gelling and melting temperatures of the
gelatin. Tyramine incorporation negatively affected the gelling
behaviour of the gelatin and was likely due to covalent
tyramine-gelatin bonds that interfered with the normal formation of
triple helix networks. Overall, this research demonstrated biogenic
amines, as potential substrates for MTGase, were able to introduce
into food proteins and peptides. A combination of
glutamine-containing peptides together with MTGase has the
potential to decontaminate fermented foods and beverages for
biogenic amines.
Subjects/Keywords: Biogenic amines; Transglutaminase; Protein hydrolysates; Gelatin; Antioxidant activity; Rheological properties
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Lu, X. (2016). Transglutaminase catalyzed amination of food protein and
peptides with biogenic amines: studies on functionality and
antioxidant activity. (Masters Thesis). University of Alberta. Retrieved from https://era.library.ualberta.ca/files/cbr86b377c
Chicago Manual of Style (16th Edition):
Lu, Xinyao. “Transglutaminase catalyzed amination of food protein and
peptides with biogenic amines: studies on functionality and
antioxidant activity.” 2016. Masters Thesis, University of Alberta. Accessed March 04, 2021.
https://era.library.ualberta.ca/files/cbr86b377c.
MLA Handbook (7th Edition):
Lu, Xinyao. “Transglutaminase catalyzed amination of food protein and
peptides with biogenic amines: studies on functionality and
antioxidant activity.” 2016. Web. 04 Mar 2021.
Vancouver:
Lu X. Transglutaminase catalyzed amination of food protein and
peptides with biogenic amines: studies on functionality and
antioxidant activity. [Internet] [Masters thesis]. University of Alberta; 2016. [cited 2021 Mar 04].
Available from: https://era.library.ualberta.ca/files/cbr86b377c.
Council of Science Editors:
Lu X. Transglutaminase catalyzed amination of food protein and
peptides with biogenic amines: studies on functionality and
antioxidant activity. [Masters Thesis]. University of Alberta; 2016. Available from: https://era.library.ualberta.ca/files/cbr86b377c

Cape Peninsula University of Technology
6.
Mbasha Migabo, Willy.
The effect of portland cements and superplasticisers on the rheology of cement paste
.
Degree: 2015, Cape Peninsula University of Technology
URL: http://etd.cput.ac.za/handle/20.500.11838/2169
► Self-compacting concrete is very sensitive to variation in cement properties and to the interaction between cement paste and additives such as superplasticisers. The assessment of…
(more)
▼ Self-compacting concrete is very sensitive to variation in cement
properties and to the interaction between cement paste and additives such as superplasticisers. The assessment of these interactions can be done rheologically but there is as yet no consensus on how to evaluate the
rheological properties (yield stress and viscosity) of cementitious materials. In addition, there is no clear understanding of the dependency of these
rheological properties on early hydration, evaluations which are recommended to be done at paste scale.
The evolution of
rheological parameters in the early stage of hydration, of four CEM I 52.5N cements manufactured at different factories in South Africa, and their interaction with two different commercial superplasticisers (SPs) were investigated using three different rheometric techniques: conventional flow curve from hysteresis loops, amplitude sweep in oscillation mode and construction of flow curve.
Amplitude sweep, time sweep, viscosity-time sweep as well as thixotropy tests were conducted to investigate the effect of hydration and the rate of rebuilding of each cement in the presence and absence of SP. The experiments were done on a MCR51 rheometer with roughened parallel plates under controlled temperatures and relative humidity.
Advisors/Committee Members: Haldenwang, Rainer (advisor), Masalova, Irina (advisor).
Subjects/Keywords: Self-consolidating concrete;
Cement – Additives;
Portland cement;
Cement – Rheological properties;
Superplasticisers
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Mbasha Migabo, W. (2015). The effect of portland cements and superplasticisers on the rheology of cement paste
. (Thesis). Cape Peninsula University of Technology. Retrieved from http://etd.cput.ac.za/handle/20.500.11838/2169
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Mbasha Migabo, Willy. “The effect of portland cements and superplasticisers on the rheology of cement paste
.” 2015. Thesis, Cape Peninsula University of Technology. Accessed March 04, 2021.
http://etd.cput.ac.za/handle/20.500.11838/2169.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Mbasha Migabo, Willy. “The effect of portland cements and superplasticisers on the rheology of cement paste
.” 2015. Web. 04 Mar 2021.
Vancouver:
Mbasha Migabo W. The effect of portland cements and superplasticisers on the rheology of cement paste
. [Internet] [Thesis]. Cape Peninsula University of Technology; 2015. [cited 2021 Mar 04].
Available from: http://etd.cput.ac.za/handle/20.500.11838/2169.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Mbasha Migabo W. The effect of portland cements and superplasticisers on the rheology of cement paste
. [Thesis]. Cape Peninsula University of Technology; 2015. Available from: http://etd.cput.ac.za/handle/20.500.11838/2169
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Technical University of Lisbon
7.
Santos, Sandra Isabel Almeida.
Emulsões estabilizadas pelo polissacárido microbiano FucoPol: produção e caracterização.
Degree: 2014, Technical University of Lisbon
URL: https://www.rcaap.pt/detail.jsp?id=oai:www.repository.utl.pt:10400.5/6985
► Mestrado em Engenharia Alimentar - Instituto Superior de Agronomia
The present work is focused on the production and characterization of oil in water emulsions stabilized…
(more)
▼ Mestrado em Engenharia Alimentar - Instituto Superior de Agronomia
The present work is focused on the production and characterization of oil in water emulsions stabilized with a bacterial exopolyssacharide (EPS), named FucoPol, produced by the bacterium Enterobacter A47 using glycerol as carbon source.
The stabilizing ability of FucoPol was studied using aqueous biopolymer solutions with concentrations of 0.5%, 1.0% and 1.5% w/w, and sunflower oil, in ratios oil/water (O:W): 20:80, 40:60, 60:40 and 80:20. It was observed that the majority of the emulsions, except the proportions 80:20, showed no phase separation after 24 hours of maturation at 4 ºC. Emulsions had a shear thinning behavior, and it was observed that, for the same oil/water ratio, the apparent viscosity increased with increasing of FucoPol’s concentration in the aqueous phase. It was also found that either the apparent viscosity or viscoelastic properties remained quite similar over 72h, indicating the presence of stable emulsions during this period of time.
The effect of FucoPol on the production of low-fat emulsions was also studied using pea protein (3% w/w) as emulsifier. It was studied the effect of FucoPol and oil concentrations on the characteristics of the emulsions obtained, keeping constant the emulsifier concentration. It was observed that for oil concentrations between 20% and 40% w/w, there’s a significant increase in viscosity with increasing of FucoPol’s concentration, but for oil contents between 40% and 60% w/w, no significant influence was observed. Still, for the whole range of oil concentrations tested it was observed that an increase in FucoPol concentration allows to produce emulsions with a stronger internal structure.
Therefore, it was concluded that the adding of this biopolymer allows to produce emulsions with a fat content below 60%.
Advisors/Committee Members: Alves, Vitor Manuel Delgado, Sousa, Isabel Maria Nunes de.
Subjects/Keywords: microbial exopolysaccharide; FucoPol; emulsions; rheological properties; pea protein
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Santos, S. I. A. (2014). Emulsões estabilizadas pelo polissacárido microbiano FucoPol: produção e caracterização. (Thesis). Technical University of Lisbon. Retrieved from https://www.rcaap.pt/detail.jsp?id=oai:www.repository.utl.pt:10400.5/6985
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Santos, Sandra Isabel Almeida. “Emulsões estabilizadas pelo polissacárido microbiano FucoPol: produção e caracterização.” 2014. Thesis, Technical University of Lisbon. Accessed March 04, 2021.
https://www.rcaap.pt/detail.jsp?id=oai:www.repository.utl.pt:10400.5/6985.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Santos, Sandra Isabel Almeida. “Emulsões estabilizadas pelo polissacárido microbiano FucoPol: produção e caracterização.” 2014. Web. 04 Mar 2021.
Vancouver:
Santos SIA. Emulsões estabilizadas pelo polissacárido microbiano FucoPol: produção e caracterização. [Internet] [Thesis]. Technical University of Lisbon; 2014. [cited 2021 Mar 04].
Available from: https://www.rcaap.pt/detail.jsp?id=oai:www.repository.utl.pt:10400.5/6985.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Santos SIA. Emulsões estabilizadas pelo polissacárido microbiano FucoPol: produção e caracterização. [Thesis]. Technical University of Lisbon; 2014. Available from: https://www.rcaap.pt/detail.jsp?id=oai:www.repository.utl.pt:10400.5/6985
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
8.
Gallo, Juliana Maria Altavista Sagretti.
Avaliação do comportamento reológico e das propriedades sensoriais de molhos comerciais para salada tratados por irradiação.
Degree: Mestrado, Tecnologia Nuclear - Aplicações, 2013, University of São Paulo
URL: http://www.teses.usp.br/teses/disponiveis/85/85131/tde-29052013-104833/
;
► Neste trabalho avaliou-se o comportamento reológico dos 11 molhos comerciais para salada, tratados pelo processo de irradiação por raios gama, nas doses: 3 kGy e…
(more)
▼ Neste trabalho avaliou-se o comportamento reológico dos 11 molhos comerciais para salada, tratados pelo processo de irradiação por raios gama, nas doses: 3 kGy e 5 kGy. Essa avaliação foi realizada por meio de reogramas traçados por medidas de viscosidade e tensão de cisalhamento por taxa de cisalhamento. Parâmetros matemáticos, obtidos destas medidas, também contribuiram para a conclusão do comportamento apresentado e do melhor modelo matemático aplicável a cada molho. As medidas foram realizadas em um viscosímetro de Brookfield modelo LVDV III. O banho térmico Neslab foi empregado para manter a tempertura ambiente durante toda a análise. Realizou-se o protocolo de estudo em duas fases. Na fase 1, a avaliação ocorreu logo após as amostras terem sido irradiadas, as quais se encontravam próximas a suas datas de fabricação. Na fase 2 as amostras foram reavalidas após um período de armazenamento, próximo a data de expiração de suas validades. Paralelamente realizou-se medida de pH para avaliar sua estabilidade diante dos tratamentos e análises sensoriais, de dois dos onze molhos estudados, a fim de verificar a aceitação desses diante da irradiação. O comportamento pseudoplástico foi confirmado para todos os molhos através do modelo matemático, da lei da potência, que melhor se aplica a este, nas duas fases das análises. A irradiação, nas doses absorvidas estudadas, não influênciou nesse comportamento. Os resultados da análise sensorial indicaram boa aceitação dos molhos irradiados, pelos provadores.
This study evaluated the rheological behavior of 11 salad dressings ready to eat, processed by gamma irradiation, at doses: 3 kGy and 5 kGy. This assessment was made by rheograms traced by measurements of viscosity and shear stress by shear rate. Mathematical parameters obtained from these measures also contributed to the conclusion of the behavior exhibited and for choosing the best mathematical model applicable to them. The measurements were performed on a Brookfield viscometer Model LVDV - III. The Neslab thermal bath was used to maintain ambient temperature during the whole analysis. This study protocol was done in two stages. In step 1, the evaluation was performed soon after the samples have been irradiated when these were close to their dates of manufacture. In phase 2 the samples were reassessed after a period of storage, near the expiration date of their validity. Simultaneously pH measurement was performed to evaluate their stability in the face of treatment and sensory analyzes of two salad dressings were studied, in order to verify the acceptance of these when submitted to irradiation. The shear-thinning behavior was confirmed for all dressings through the mathematical model, the power law, that best model apply to this, in both phases. The irradiation at the absorbed doses studied did not influence this behavior. The results of sensory evaluation indicated good acceptance of irradiated sauces for the tasters.
Advisors/Committee Members: Sabato, Susy Frey.
Subjects/Keywords: dressing; irradiação; irradiation; molho; reologia; rheological behavior; sensorial; sensory properties
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APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
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APA (6th Edition):
Gallo, J. M. A. S. (2013). Avaliação do comportamento reológico e das propriedades sensoriais de molhos comerciais para salada tratados por irradiação. (Masters Thesis). University of São Paulo. Retrieved from http://www.teses.usp.br/teses/disponiveis/85/85131/tde-29052013-104833/ ;
Chicago Manual of Style (16th Edition):
Gallo, Juliana Maria Altavista Sagretti. “Avaliação do comportamento reológico e das propriedades sensoriais de molhos comerciais para salada tratados por irradiação.” 2013. Masters Thesis, University of São Paulo. Accessed March 04, 2021.
http://www.teses.usp.br/teses/disponiveis/85/85131/tde-29052013-104833/ ;.
MLA Handbook (7th Edition):
Gallo, Juliana Maria Altavista Sagretti. “Avaliação do comportamento reológico e das propriedades sensoriais de molhos comerciais para salada tratados por irradiação.” 2013. Web. 04 Mar 2021.
Vancouver:
Gallo JMAS. Avaliação do comportamento reológico e das propriedades sensoriais de molhos comerciais para salada tratados por irradiação. [Internet] [Masters thesis]. University of São Paulo; 2013. [cited 2021 Mar 04].
Available from: http://www.teses.usp.br/teses/disponiveis/85/85131/tde-29052013-104833/ ;.
Council of Science Editors:
Gallo JMAS. Avaliação do comportamento reológico e das propriedades sensoriais de molhos comerciais para salada tratados por irradiação. [Masters Thesis]. University of São Paulo; 2013. Available from: http://www.teses.usp.br/teses/disponiveis/85/85131/tde-29052013-104833/ ;

Texas A&M University
9.
Alhadi, Almostafa Ali Adam.
Evaluation of New Generation of Viscoelastic Surfactants as Diverting Agents for High-Temperature Formations.
Degree: MS, Energy, 2017, Texas A&M University
URL: http://hdl.handle.net/1969.1/165884
► The viscoelastic surfactant (VES) is one of the newest chemicals that have been used as diverting agents to divert the acid to the desirable zones…
(more)
▼ The viscoelastic surfactant (VES) is one of the newest chemicals that have been used as diverting agents to divert the acid to the desirable zones through directing the acid to the lowest permeability formations by building in-situ viscosity. This technique shows valuable
properties in diverting and cleaning processes. However, the main problem associated with this technique is a temperature limitation; therefore, the research is continuing developing new chemicals that overcome the high-temperature short come.
This study aims to evaluate the
rheological properties of five new types of the VES that are proposed to be used in oil industry through conducting the lab tests on this new generation of the VES. The spent acid system which contains 6 vol% VES was prepared and the PH was adjusted between 4 and 5 while the pressure was maintained at 400 psi.
The different types showed various performances in different conditions, VES001 showed high viscosity around 100 cp at a shear rate of 10 s-1 and temperature of 2000F. while VES002 didn’t show any viscosity building in high temperatures (200 and 2500F). VES003 and VES004 showed a high viscosity building around120 cp in temperature of 2500F at a shear rate of 10 s-1. Type 5 showed promising
properties in high temperatures since it showed viscosity of 120 and 220 cp in 200 and 2500F, respectively. Moreover, its viscosity didn’t peak even at 3700F when it showed viscosity of 550 Cp at a shear rate of 87s-1.
Further tests were obtained on the VES005 to deeply evaluate both its capability as diverting agent and its compatibility with the other acid additives. The effects of several corrosion inhibitors on the performance of the VES were studied then the optimal inhibitor was used for the further studies. Core-flood tests were conducted to emulate the performance of the system inside the formations. Two types of Indiana limestone cores, 150 mD and 12 mD, were used. The exciting diverting performance was observed through the low permeability core; however, some diverting performances were observed in the high permeability core. CT scan was used to reinforce these results.
Advisors/Committee Members: Nasr-El-Din, Hisham (advisor), Holditch, Stephen (committee member), El-Halwagi, Mahmoud (committee member).
Subjects/Keywords: viscoelastic surfactant; acidizing; rheological properties; matrix acidizing; diverting agents
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Alhadi, A. A. A. (2017). Evaluation of New Generation of Viscoelastic Surfactants as Diverting Agents for High-Temperature Formations. (Masters Thesis). Texas A&M University. Retrieved from http://hdl.handle.net/1969.1/165884
Chicago Manual of Style (16th Edition):
Alhadi, Almostafa Ali Adam. “Evaluation of New Generation of Viscoelastic Surfactants as Diverting Agents for High-Temperature Formations.” 2017. Masters Thesis, Texas A&M University. Accessed March 04, 2021.
http://hdl.handle.net/1969.1/165884.
MLA Handbook (7th Edition):
Alhadi, Almostafa Ali Adam. “Evaluation of New Generation of Viscoelastic Surfactants as Diverting Agents for High-Temperature Formations.” 2017. Web. 04 Mar 2021.
Vancouver:
Alhadi AAA. Evaluation of New Generation of Viscoelastic Surfactants as Diverting Agents for High-Temperature Formations. [Internet] [Masters thesis]. Texas A&M University; 2017. [cited 2021 Mar 04].
Available from: http://hdl.handle.net/1969.1/165884.
Council of Science Editors:
Alhadi AAA. Evaluation of New Generation of Viscoelastic Surfactants as Diverting Agents for High-Temperature Formations. [Masters Thesis]. Texas A&M University; 2017. Available from: http://hdl.handle.net/1969.1/165884

Texas A&M University
10.
Tian, Zhida.
Studying the Breaking Mechanism of Polymer-Based In-Situ Gelled Acids using Solid Breaker.
Degree: MS, Petroleum Engineering, 2012, Texas A&M University
URL: http://hdl.handle.net/1969.1/ETD-TAMU-2012-08-11491
► In situ gelled acids that are based on polymers have been used in the field for several years as an acid diversion agent. These acids…
(more)
▼ In situ gelled acids that are based on polymers have been used in the field for several years as an acid diversion agent. These acids should not cause permanent formation damage, and should clean-up rapidly and completely when the well is put back on production. However, recent lab studies indicated that a significant amount of gel was retained inside the core even when the recommended breaker concentration was used. This gel significantly reduced the core permeability. Therefore, the objective of this study is to examine the working mechanisms of the solid breaker and the factors that affect the breaking time. The flowback of the spent acid and the core damage induced by it will also be assessed in detail.
Viscosity and
rheological experimental studies were conducted using polymer-based in situ gelled acids that used Zr as a crosslinker agent. To form the gel, this acid was neutralized using Pink Desert limestone to pH 3.5-4.The
rheological properties of the gel were measured under different breaking conditions for 2 hr using HPHT rotational and oscillatory rheometers. Temperature (150 to 250 degrees F), shear rate (0.1 to 1000 s^-1), and breaker concentrations (0 to 32 lb/Mgal) were the main parameters that were investigated in this study. Experimental results showed that there is no need to add more than 16-ppg breaker concentration at 150 degrees F, while 4-ppg breaker concentration is enough at temperatures higher than 200 degrees F. A full breaking of these acids was obtained when the values of elastic modulus (G') were equalized with the viscose modules (G").
An HPHT filter press was used to simulate the flowback of the spent acid. Viscosity measurements of filtered fluids were used to determine the degree of gel degradation. Carbonate cores that had a 2.5 in. diameter and 0.25 in.thickness were used. Temperature (75 to 250 degrees F) and breaker concentrations (0 to 16 lb/Mgal) were the main parameters that were investigated in this study. Experimental results showed that there was always a gel left inside the rock, and such caused permeability reduction. Time needed to flowback the solution decreased by 50% when the temperature was increased from 150 to 200 degrees F, while it decreased by only 30% when the breaker concentration was doubled. At 150 degrees F, 16-ppg breaker concentration was recommended for breaking the gel. At higher temperatures (>150 degrees F), 8-ppg breaker concentration was enough to help degrade the gel.
Advisors/Committee Members: Nasr-El-Din, Hisham A. (advisor), Schubert, Jerome J. (committee member), El-Halwagi, Mahmoud (committee member).
Subjects/Keywords: In-situ gelled acids; solid breaker; rheological properties
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Tian, Z. (2012). Studying the Breaking Mechanism of Polymer-Based In-Situ Gelled Acids using Solid Breaker. (Masters Thesis). Texas A&M University. Retrieved from http://hdl.handle.net/1969.1/ETD-TAMU-2012-08-11491
Chicago Manual of Style (16th Edition):
Tian, Zhida. “Studying the Breaking Mechanism of Polymer-Based In-Situ Gelled Acids using Solid Breaker.” 2012. Masters Thesis, Texas A&M University. Accessed March 04, 2021.
http://hdl.handle.net/1969.1/ETD-TAMU-2012-08-11491.
MLA Handbook (7th Edition):
Tian, Zhida. “Studying the Breaking Mechanism of Polymer-Based In-Situ Gelled Acids using Solid Breaker.” 2012. Web. 04 Mar 2021.
Vancouver:
Tian Z. Studying the Breaking Mechanism of Polymer-Based In-Situ Gelled Acids using Solid Breaker. [Internet] [Masters thesis]. Texas A&M University; 2012. [cited 2021 Mar 04].
Available from: http://hdl.handle.net/1969.1/ETD-TAMU-2012-08-11491.
Council of Science Editors:
Tian Z. Studying the Breaking Mechanism of Polymer-Based In-Situ Gelled Acids using Solid Breaker. [Masters Thesis]. Texas A&M University; 2012. Available from: http://hdl.handle.net/1969.1/ETD-TAMU-2012-08-11491
11.
Odeh, Joud.
Correlating Self-Consolidating Concrete mixture composition to its rheological properties.
Degree: MASc, 2018, McMaster University
URL: http://hdl.handle.net/11375/22831
► Self-Consolidating concrete (SCC), a highly flowable concrete, is gaining wide acceptance in the concrete industries due to a higher productivity, lower energy consumption, improved working…
(more)
▼ Self-Consolidating concrete (SCC), a highly flowable concrete, is gaining wide acceptance in the concrete industries due to a higher productivity, lower energy consumption, improved working environment and increase quality. SCC is susceptible to segregation and therefore a balance between flow-ability and stability is required. The absence of a comprehensive SCC mixture composition design guidelines merits investigating the effects of SCC mixture variables on the properties affecting its performance, namely flow and stability.
An experimental and analytical study were carried out to study the influence of 5 design variables, namely water to binder ratio (w/b), percent addition of silica fume (SF), percent addition of Ground Granulated Blast Furnace Slag (GGBFS), bulk volume of coarse aggregates and binder content, on the workability and rheology of SCC. Workability measurements, specifically the slump flow, T50, L-Box and segregation column, and rheological properties, namely plastic viscosity, yield stress, and thixotropy were measured to evaluate SCC’s performance. A revised modified Bingham model was proposed to adequately account for the linear and non-linear responses of the concrete flow. It postulates that the flow is divided into a linear and non-linear part. The revised model is found to provide more consistent and precise estimate of the rheological properties. Using regression analyses, yield stress and plastic viscosity models that account for the statistically significant variables were derived from experimental test data. Yield stress is found to depend on the bulk volume fraction of the coarse aggregate, Silica Fume content, High Range Water Reducing Agent (HRWRA) and Viscosity Modifying Agent (VMA), and plastic viscosity on w/b, HRWRA and Average Paste Thickness (APT).
Thesis
Master of Applied Science (MASc)
Advisors/Committee Members: Chidiac, Samir, Civil Engineering.
Subjects/Keywords: SCC; SCC mixture composition; Workability; Rheology; Rheological properties
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APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Odeh, J. (2018). Correlating Self-Consolidating Concrete mixture composition to its rheological properties. (Masters Thesis). McMaster University. Retrieved from http://hdl.handle.net/11375/22831
Chicago Manual of Style (16th Edition):
Odeh, Joud. “Correlating Self-Consolidating Concrete mixture composition to its rheological properties.” 2018. Masters Thesis, McMaster University. Accessed March 04, 2021.
http://hdl.handle.net/11375/22831.
MLA Handbook (7th Edition):
Odeh, Joud. “Correlating Self-Consolidating Concrete mixture composition to its rheological properties.” 2018. Web. 04 Mar 2021.
Vancouver:
Odeh J. Correlating Self-Consolidating Concrete mixture composition to its rheological properties. [Internet] [Masters thesis]. McMaster University; 2018. [cited 2021 Mar 04].
Available from: http://hdl.handle.net/11375/22831.
Council of Science Editors:
Odeh J. Correlating Self-Consolidating Concrete mixture composition to its rheological properties. [Masters Thesis]. McMaster University; 2018. Available from: http://hdl.handle.net/11375/22831

Texas A&M University
12.
Mahmoud, Omar Saad Ahmed.
Improving the Characteristics of Water-Based Drilling Fluids Using Nanoparticles.
Degree: PhD, Petroleum Engineering, 2017, Texas A&M University
URL: http://hdl.handle.net/1969.1/187287
► The capabilities of different types of nanoparticles (NPs) had been exploited to develop a water-based drilling fluid having better characteristics for harsh drilling conditions. More…
(more)
▼ The capabilities of different types of nanoparticles (NPs) had been exploited to develop a water-based drilling fluid having better characteristics for harsh drilling conditions. More specifically, the objectives of this work are to: 1) investigate the effectiveness of using different oxide NPs: ferric oxide (of sizes< 50 nm), magnetic iron oxide (of average particle size 50 –100 nm), silica NPs (size =12 nm), and zinc oxide NPs (of sizes < 100 nm) on the
rheological properties and filter cake characteristics of Ca-bentonite-based drilling fluid at downhole conditions, 2) conduct a sensitivity analysis of the
rheological properties of these drilling fluids and investigate the effect of charge potential, 3) determine the optimum concentration of NPs, and 4) evaluate the effect of different drilling fluid additives on the performance of NPs/Ca-bentonite fluids by formulating and testing a complete bentonite-based drilling fluid formula.
A reduction of 43% in the fluid loss volume was achieved when using 0.5 wt% of ferric oxide NPs with 7 wt% Ca-bentonite suspension compared to that without NPs. However, using silica or zinc oxide NPs at different concentrations resulted in an increase in the fluid loss volume and filter cake thickness. The inductively coupled plasma (ICP) analysis of the filtrate fluids and the scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) of the filter cakes revealed the replacement of the cations dissociated from the Ca-bentonite by ferric oxide NPs at the investigated conditions, which promoted the formation of rigid clay platelet structure. Furthermore, using 0.5 wt% of NPs provided less agglomeration, as shown by the SEM images, and less filter cake permeability. Moreover, the produced filter cake consisted of two layers, as indicated by the computed-tomography (CT) scan. Increasing the concentration of NPs resulted in an increase in the fluid loss and filter cake thickness. At high NP concentration (2.5 wt%), a new layer of the agglomerated NPs generated in the filter cake close to the surface of formation, which adversely affected the cake characteristics. The ferric oxide and magnetic iron oxide NPs/Ca-bentonite fluids were found to have stable
rheological properties at different NP concentrations and temperatures (up to 200°F). Additionally, thermally aging these fluids at 350°F for 16 hours showed minor changes in their
rheological properties, which confirmed their applicability in drilling downhole environments.
The ferric oxide NPs improved the filter cake and filtration
properties of Ca-bentonite-based drilling fluids in the presence of polymer and other additives under both static and dynamic filtration (at 100 rpm). The best filter cake characteristics were obtained when using a NP concentration of 0.3-0.5 wt%. Furthermore, the formulated NPs/Ca-bentonite-based drilling fluids could withstand downhole conditions up to 500 psi and 350°F and produced a filter cake that has 0.151-in. thickness, 6.9 ml filtrate loss volume, and 0.428 µd permeability at this…
Advisors/Committee Members: Nasr-El-Din, Hisham A (advisor), Schubert, Jerome (committee member), Hascakir, Berna (committee member), El-Halwagi, Mahmoud (committee member).
Subjects/Keywords: Drilling Fluids; Nanoparticles; Bentonite; FIlter Cake; Rheological Properties
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APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Mahmoud, O. S. A. (2017). Improving the Characteristics of Water-Based Drilling Fluids Using Nanoparticles. (Doctoral Dissertation). Texas A&M University. Retrieved from http://hdl.handle.net/1969.1/187287
Chicago Manual of Style (16th Edition):
Mahmoud, Omar Saad Ahmed. “Improving the Characteristics of Water-Based Drilling Fluids Using Nanoparticles.” 2017. Doctoral Dissertation, Texas A&M University. Accessed March 04, 2021.
http://hdl.handle.net/1969.1/187287.
MLA Handbook (7th Edition):
Mahmoud, Omar Saad Ahmed. “Improving the Characteristics of Water-Based Drilling Fluids Using Nanoparticles.” 2017. Web. 04 Mar 2021.
Vancouver:
Mahmoud OSA. Improving the Characteristics of Water-Based Drilling Fluids Using Nanoparticles. [Internet] [Doctoral dissertation]. Texas A&M University; 2017. [cited 2021 Mar 04].
Available from: http://hdl.handle.net/1969.1/187287.
Council of Science Editors:
Mahmoud OSA. Improving the Characteristics of Water-Based Drilling Fluids Using Nanoparticles. [Doctoral Dissertation]. Texas A&M University; 2017. Available from: http://hdl.handle.net/1969.1/187287

Univerzitet u Beogradu
13.
Pavlićević, Milica Ž., 1983-.
Uticaj sadržaja [beta] podjedinica konglicinina na
tehnološke funkcionalne osobine proteina soje.
Degree: Poljoprivredni fakultet, 2017, Univerzitet u Beogradu
URL: https://fedorabg.bg.ac.rs/fedora/get/o:14811/bdef:Content/get
► Biotehničke nauke - Prehrambena tehnologija / Biotechnical Sciences - Food Technology
Zbog značajne nutritivne vrednosti i visokog sadržaja proteina, antioksidanasa i nezasićenih masnih kiselina soja…
(more)
▼ Biotehničke nauke - Prehrambena tehnologija /
Biotechnical Sciences - Food Technology
Zbog značajne nutritivne vrednosti i visokog
sadržaja proteina, antioksidanasa i nezasićenih masnih kiselina
soja se svrstava u kategoriju funkcionalne hranu. Zdravstveni
efekti soje u humanoj ishrani su brojni: doprinosi smanjenju
koncentracije glukoze i holesterola u krvi, pokazuje
antioksidativni efekat, povoljno utiče na održavanje hormonske
ravnoteže, sprečava osteoporozu i deluje preventivno na različite
tipove kancera. Na tehnološki značajne funkcionalne osobine
proteina semena soje najviše utiču dva glavna rezervna proteina:
glicinin (11S protein) i β konglicinin (7S protein). I 11S i 7S
proteini se javljaju u više izoformi. Molekul glicinin čine dva
neglikozilovana heksamera koji se sastoje iz parova kiselih i
baznih polipeptida povezanih disulfidnim mostom.β konglicinin je
glikozilovani trimerni protein koji se sastoji iz tri podjedinice-
α, α' i β. Pojedine sorte soje, među kojima su naročito brojne
domaće sorte, sintetišu dodatnu β' podjedinicu. Premda je efekat
ostalih podjedinica β konglicinina na tehnološka funkcionalna
svojstva proteina soje intenzivno proučavan, u literaturi postoji
veliki broj kontradiktornih podataka. O efektima β' podjedinice na
rastvorljivost, emulgujuća i gelirajuća svojstva sojinih proteina
veoma malo se zna. Cilj ovog rada bio je da se ispita efekat
polipeptidnog sastava glicinina i β konglicinina na rastvorljivost,
emulgujuća i gelirajuća svojstva proteina na različitim pH
vrednostima (3, 5, 6 i 8) na seriji od 9 različitih genotipova soje
gajenih u dve sukcesivne godine. Uspostavljanje korelacija između
specifičnih podjedinica sojinih proteina i željenog svojstva pri
datoj pH vrednosti, omogućilo bi ne samo selekciju sorti pogodnih
za dati tehnološki proces, već bi uticalo i na osobine gotovih
proizvoda. Povećana rastvorljivost obezbeđivala bi lakše usvajanje
aminokiselina i bolju svarljivost. Pored povećane biološke
vrednosti, visoka rastvorljivost je u pozitivnoj korelaciji sa
funkcionalnim svojstvima poput geliranja i
penivosti...
Advisors/Committee Members: Vucelić-Radović, Biljana, 1954-.
Subjects/Keywords: β conglycinin; β' subunit; soybean; solubility;
emulsion and rheological properties
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Pavlićević, Milica Ž., 1. (2017). Uticaj sadržaja [beta] podjedinica konglicinina na
tehnološke funkcionalne osobine proteina soje. (Thesis). Univerzitet u Beogradu. Retrieved from https://fedorabg.bg.ac.rs/fedora/get/o:14811/bdef:Content/get
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Pavlićević, Milica Ž., 1983-. “Uticaj sadržaja [beta] podjedinica konglicinina na
tehnološke funkcionalne osobine proteina soje.” 2017. Thesis, Univerzitet u Beogradu. Accessed March 04, 2021.
https://fedorabg.bg.ac.rs/fedora/get/o:14811/bdef:Content/get.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Pavlićević, Milica Ž., 1983-. “Uticaj sadržaja [beta] podjedinica konglicinina na
tehnološke funkcionalne osobine proteina soje.” 2017. Web. 04 Mar 2021.
Vancouver:
Pavlićević, Milica Ž. 1. Uticaj sadržaja [beta] podjedinica konglicinina na
tehnološke funkcionalne osobine proteina soje. [Internet] [Thesis]. Univerzitet u Beogradu; 2017. [cited 2021 Mar 04].
Available from: https://fedorabg.bg.ac.rs/fedora/get/o:14811/bdef:Content/get.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Pavlićević, Milica Ž. 1. Uticaj sadržaja [beta] podjedinica konglicinina na
tehnološke funkcionalne osobine proteina soje. [Thesis]. Univerzitet u Beogradu; 2017. Available from: https://fedorabg.bg.ac.rs/fedora/get/o:14811/bdef:Content/get
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Oklahoma State University
14.
Goswami, Subhasree.
Effects of Fermented Products and Sodium Chloride Substitutes on Selected Properties of White Bread and Dough.
Degree: Food Science, 2014, Oklahoma State University
URL: http://hdl.handle.net/11244/14853
► Reducing sodium content in bread is a challenging proposition since sodium chloride contributes to more than saltiness perception in bread products. The objective of this…
(more)
▼ Reducing sodium content in bread is a challenging proposition since sodium chloride contributes to more than saltiness perception in bread products. The objective of this study was to assess the effect of salt substitutes and fermented products (wheat-soybean tempe flour and sourdough) on flavor profile and
rheological properties of bread. Tempe is an Indonesian traditional fermented food which is made by fungi fermentation of soybeans and other legumes.The desirable taste, flavor, texture, acidity and aroma are produced by the hydrolysis of substrates by enzymes. Sourdough process is very simple and is based on naturally occurring yeasts in the cereal grains. A commercial wheat flour with protein content 11 ± 0.5% was treated with sourdough (0, 11, 17 and 33% w/w) and tempe (0, 2, 3.5 and 5% w/w) and baked. Three sensory analysis sessions were conducted to determine the seven parameters flavor profile by 80 untrained panelists. This study showed that for saltiness score, the combination of 17% sourdough, 3.5%, panelists could not detect the difference in saltiness perception between 0.75 and 1.5% NaCl. One commercial wheat flour with protein content 11.8% was treated with different levels sodium chloride (0.75, 1.5 and 2.0%), wheat-soybean tempe flour (2 and 3.5%) and sourdough (17 and 33%) following a Randomized Complete Block Design with 3 replicates to analyze the
rheological properties. Increase in development time, stability time and breakdown time was observed with elevation of NaCl levels. Development time and breakdown time decreased with increase in sourdough (17 vs 33%). A set of three commercial wheat flours with protein content 9.8, 10.9 and 13.4% was treated with sodium chloride (control) as well as five commercial NaCl substitutes following a Randomized Complete Block Design with 3 replicates to analyze the effect on
rheological properties. Mixing
properties showed that development time and stability time were directly proportional to the level of salt. Maximum resistance to extension (Rmax) and area under the curve increased with an increase of NaCl level. NaCl resulted in a higher area than commercial NaCl substitutes when each level of salt was analyzed.
Advisors/Committee Members: Rayas-Duarte, Patricia (advisor), Ramanathan, Ranjith (committee member), McGlynn, William (committee member).
Subjects/Keywords: bread; cereal; dough; fermented products; rheological properties; sodium chloride substitutes
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APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Goswami, S. (2014). Effects of Fermented Products and Sodium Chloride Substitutes on Selected Properties of White Bread and Dough. (Thesis). Oklahoma State University. Retrieved from http://hdl.handle.net/11244/14853
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Goswami, Subhasree. “Effects of Fermented Products and Sodium Chloride Substitutes on Selected Properties of White Bread and Dough.” 2014. Thesis, Oklahoma State University. Accessed March 04, 2021.
http://hdl.handle.net/11244/14853.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Goswami, Subhasree. “Effects of Fermented Products and Sodium Chloride Substitutes on Selected Properties of White Bread and Dough.” 2014. Web. 04 Mar 2021.
Vancouver:
Goswami S. Effects of Fermented Products and Sodium Chloride Substitutes on Selected Properties of White Bread and Dough. [Internet] [Thesis]. Oklahoma State University; 2014. [cited 2021 Mar 04].
Available from: http://hdl.handle.net/11244/14853.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Goswami S. Effects of Fermented Products and Sodium Chloride Substitutes on Selected Properties of White Bread and Dough. [Thesis]. Oklahoma State University; 2014. Available from: http://hdl.handle.net/11244/14853
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Brno University of Technology
15.
Debnáriková, Michaela.
Příprava chitinových filmů: Preparation of chitin film.
Degree: 2019, Brno University of Technology
URL: http://hdl.handle.net/11012/173473
► The bachelor thesis deals with the extraction, purification, dissolution and preparation of film based on chitin/ polyvinyl alcohol (PVA). The pure chitin was fully characterized…
(more)
▼ The bachelor thesis deals with the extraction, purification, dissolution and preparation of film based on chitin/ polyvinyl alcohol (PVA). The pure chitin was fully characterized by different techniques like potentiometric titration, FT-IR, TGA, XRD, SEM and solid NMR. The solubility, purity of extracted chitin was investigated and evaluated by measuring the protein percent, rheology, and time need for dissolution. The chitin/PVA films were prepared using different ratio between chitin and PVA solution and film was prepared by casting method. The surface morphology,
rheological and mechanical
properties of the film were measured and evaluated.
Advisors/Committee Members: Abdellatif, Abdelmohsan (advisor), Abdelrahman, Rasha (referee).
Subjects/Keywords: Chitin; Polyvinylalkohol; film; reologické vlastnosti; Chitin; Polyvinyl alcohol; film; rheological properties
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Debnáriková, M. (2019). Příprava chitinových filmů: Preparation of chitin film. (Thesis). Brno University of Technology. Retrieved from http://hdl.handle.net/11012/173473
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Debnáriková, Michaela. “Příprava chitinových filmů: Preparation of chitin film.” 2019. Thesis, Brno University of Technology. Accessed March 04, 2021.
http://hdl.handle.net/11012/173473.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Debnáriková, Michaela. “Příprava chitinových filmů: Preparation of chitin film.” 2019. Web. 04 Mar 2021.
Vancouver:
Debnáriková M. Příprava chitinových filmů: Preparation of chitin film. [Internet] [Thesis]. Brno University of Technology; 2019. [cited 2021 Mar 04].
Available from: http://hdl.handle.net/11012/173473.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Debnáriková M. Příprava chitinových filmů: Preparation of chitin film. [Thesis]. Brno University of Technology; 2019. Available from: http://hdl.handle.net/11012/173473
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
16.
Lê, Van Nha Phuong.
Influence des propriétés physicochimiques du principe actif et du transporteur sur la performance aérodynamique des mélanges de poudre pour inhalation : Influence of the physicochemical properties of drug and carrier on the performance of powders for inhalation.
Degree: Docteur es, Sciences physico-chimiques et techniques pharmaceutiques, 2011, Université Lille II – Droit et Santé
URL: http://www.theses.fr/2011LIL2S012
► Les inhalateurs à poudre sèche (DPI) sont une alternative attractive aux inhalateurs pressurisés à valve doseuse (pMDI) du fait de leur absence de gaz propulseur.…
(more)
▼ Les inhalateurs à poudre sèche (DPI) sont une alternative attractive aux inhalateurs pressurisés à valve doseuse (pMDI) du fait de leur absence de gaz propulseur. Pour pénétrer dans les poumons profonds, la taille optimale du principe actif est généralement inférieure à 5 μm. Leur mélange avec un transporteur de taille plus importante, principalement le lactose alpha monohydrate, est classiquement utilisé pour améliorer leur écoulement, faciliter le remplissage dans les inhalateurs et améliorer leur dispersion. Cependant, la formulation et la production des mélanges de poudres pour inhalation demandent une optimisation adéquate pour des-agglomérer les particules cohésives de principe actif et assurer l’homogénéité de ces mélanges contenant un faible pourcentage de principe actif (1,5 à 2,5 %). De plus, l’amélioration de la performance aérodynamique de ces mélanges est nécessaire. Le contrôle des propriétés physico-chimiques du principe actif et du transporteur est critique pour atteindre et maintenir la qualité de la formulation des poudres pour inhalation. Dans cette étude, le lactose alpha monohydrate est utilisé comme transporteur. Des lactoses de grade et de qualité différents sont comparés. Le propionate de fluticasone et le sulfate de terbutaline sont utilisés comme principes actifs modèles. Différentes techniques sont utilisées pour caractériser les principes actifs et les transporteurs: la distribution granulométrique mesurée par la méthode de diffraction laser, les propriétés thermiques par la méthode de calorimétrie (DSC), l’analyse d’image par microscopie électronique à balayage (MEB), l’énergie de surface par la méthode de chromatographie gazeuse inverse (iGC)…Le mélange principe actif et transporteur est réalisé grâce au mélangeur type Turbula, l’influence des conditions opératoires a été étudiée. La performance aérodynamique est évaluée par l’impacteur à cascade en verre (Pharmacopée Européenne). Nous avons développé des techniques de caractérisation des mélanges : l’évaluation de l’adhésion par le tamiseur à dépression d’air, la perméabilité des poudres mesurée par le perméabilimètre de Blaine ; la taille des agglomérats de principe actifs déterminée par la méthode de diffraction laser en milieu liquide. Enfin, les propriétés rhéologiques de poudre et en particulier sa fluidisation sont évaluées par un nouveau rhéomètre, le Freeman FT4. La taille des particules de transporteur exerce une influence importante sur la performance des mélanges pour inhalation. La réduction de taille du transporteur diminue les interactions entre le principe actif et le transporteur. Le détachement du principe de son transporteur est ainsi facilité ce qui augmente le pourcentage de principe actif susceptible de pénétrer dans les poumons c’est-à-dire la fraction respirable de principe actif. Différents grades et qualités de lactose de répartition granulométrique similaire mais obtenus par différentes méthodes de production ont été étudiés et comparés. Ces lactoses différaient essentiellement par le procédé de…
Advisors/Committee Members: Flament, Marie-Pierre (thesis director).
Subjects/Keywords: Mélange interactif; Propriétés rhéologiques; Rheological properties; Interactive mixing
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Lê, V. N. P. (2011). Influence des propriétés physicochimiques du principe actif et du transporteur sur la performance aérodynamique des mélanges de poudre pour inhalation : Influence of the physicochemical properties of drug and carrier on the performance of powders for inhalation. (Doctoral Dissertation). Université Lille II – Droit et Santé. Retrieved from http://www.theses.fr/2011LIL2S012
Chicago Manual of Style (16th Edition):
Lê, Van Nha Phuong. “Influence des propriétés physicochimiques du principe actif et du transporteur sur la performance aérodynamique des mélanges de poudre pour inhalation : Influence of the physicochemical properties of drug and carrier on the performance of powders for inhalation.” 2011. Doctoral Dissertation, Université Lille II – Droit et Santé. Accessed March 04, 2021.
http://www.theses.fr/2011LIL2S012.
MLA Handbook (7th Edition):
Lê, Van Nha Phuong. “Influence des propriétés physicochimiques du principe actif et du transporteur sur la performance aérodynamique des mélanges de poudre pour inhalation : Influence of the physicochemical properties of drug and carrier on the performance of powders for inhalation.” 2011. Web. 04 Mar 2021.
Vancouver:
Lê VNP. Influence des propriétés physicochimiques du principe actif et du transporteur sur la performance aérodynamique des mélanges de poudre pour inhalation : Influence of the physicochemical properties of drug and carrier on the performance of powders for inhalation. [Internet] [Doctoral dissertation]. Université Lille II – Droit et Santé 2011. [cited 2021 Mar 04].
Available from: http://www.theses.fr/2011LIL2S012.
Council of Science Editors:
Lê VNP. Influence des propriétés physicochimiques du principe actif et du transporteur sur la performance aérodynamique des mélanges de poudre pour inhalation : Influence of the physicochemical properties of drug and carrier on the performance of powders for inhalation. [Doctoral Dissertation]. Université Lille II – Droit et Santé 2011. Available from: http://www.theses.fr/2011LIL2S012

University of Texas – Austin
17.
Lee, Sang Ki, M.S. in Engineering.
Evaluation of asphalt binder and mixture properties that incorporate reclaimed asphalt pavement.
Degree: MSin Engineering, Civil Engineering, 2018, University of Texas – Austin
URL: http://hdl.handle.net/2152/68995
► Several private and public agencies are exploring ways in which the use of reclaimed asphalt pavement (RAP) can be increased in the construction of new…
(more)
▼ Several private and public agencies are exploring ways in which the use of reclaimed asphalt pavement (RAP) can be increased in the construction of new pavements. However, such an increase must not come at the expense of reduced durability or life cycle cost. The use of RAP is often accompanied by some form of adjustment to the virgin binder that is being used. In Texas, the current practice of incorporating RAP is controlled by a simplified table that lists a substitute binder grade and recycled binder ratio (RBR) when RAP is incorporated in a mix. There are a few shortcomings with this simple approach of specifying a maximum ratio: (1) it does not address the potential difference in the quality of recycled binders from RAP, (2) it may result in the use of substituted binders with little or no polymer (elastomer) and (3) it does not account for the influence of recycling agents. The goal of this study was to evaluate the change in performance of binders and mixtures using different grades of virgin binder and percentages of RAP. Two different Job Mix Formulae (JMF) and corresponding materials were obtained from asphalt plants in the state of Texas. A test matrix was developed to evaluate binders and mixtures with different ratios of recycled binder to virgin binder and different ratios of RAP to virgin material, respectively. The results from this study show that addition of RAP or recycled binder (from RAP) results in an increase in stiffness and resistance to rutting, which was expected. However, the resistance to cracking showed mixed results. The test results also show that the
properties of the recycled binder from RAP can vary significantly with source and have a drastic effect on the
properties of the binder and mixture.
Advisors/Committee Members: Bhasin, Amit (advisor).
Subjects/Keywords: Reclaimed asphalt pavement (RAP); Recycled binder ratio (RBR); Rheological properties; Asphalt
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Lee, Sang Ki, M. S. i. E. (2018). Evaluation of asphalt binder and mixture properties that incorporate reclaimed asphalt pavement. (Masters Thesis). University of Texas – Austin. Retrieved from http://hdl.handle.net/2152/68995
Chicago Manual of Style (16th Edition):
Lee, Sang Ki, M S in Engineering. “Evaluation of asphalt binder and mixture properties that incorporate reclaimed asphalt pavement.” 2018. Masters Thesis, University of Texas – Austin. Accessed March 04, 2021.
http://hdl.handle.net/2152/68995.
MLA Handbook (7th Edition):
Lee, Sang Ki, M S in Engineering. “Evaluation of asphalt binder and mixture properties that incorporate reclaimed asphalt pavement.” 2018. Web. 04 Mar 2021.
Vancouver:
Lee, Sang Ki MSiE. Evaluation of asphalt binder and mixture properties that incorporate reclaimed asphalt pavement. [Internet] [Masters thesis]. University of Texas – Austin; 2018. [cited 2021 Mar 04].
Available from: http://hdl.handle.net/2152/68995.
Council of Science Editors:
Lee, Sang Ki MSiE. Evaluation of asphalt binder and mixture properties that incorporate reclaimed asphalt pavement. [Masters Thesis]. University of Texas – Austin; 2018. Available from: http://hdl.handle.net/2152/68995

Technical University of Lisbon
18.
Salgado, Rita Alexandra Fernandes.
Caracterização e recuperação de proteínas de subprodutos de pescado.
Degree: 2015, Technical University of Lisbon
URL: https://www.rcaap.pt/detail.jsp?id=oai:www.repository.utl.pt:10400.5/11170
► Mestrado em Engenharia Alimentar - Qualidade e Segurança Alimentar - Instituto Superior de Agronomia
Fish byproducts are a source of proteins and lipids liable to…
(more)
▼ Mestrado em Engenharia Alimentar - Qualidade e Segurança Alimentar - Instituto Superior de Agronomia
Fish byproducts are a source of proteins and lipids liable to improvement.
The aims of this work were: protein recovery by the shifting pH method and isoelectric precipitation; phospholipids removal on soluble proteins by adding CaCl2 and citric acid; characterization of functional, textural and rheological properties of recovered proteins.
Alkaline recovered proteins (PR_ALC) contained 75.9 % protein and 14.4 % fat and acidic recovered proteins (PR_AC) contained 47.8 % e 17.0 %, respectively.
PR_ALC had higher water holding capacity (2.97 g/ g-sample) and emulsion stability (88,5 %), but none of them exhibited foaming capacity. Fat absorption was 2.95 and 3.28 g/g-sample of PR_ALC e PR_AC, respectively. Emulsifying activity index was respectively 3.19 and 3.67 m2/g for PR_AC and PR_AC respectively. The gel strength of PR_ALC was 381.83 g.cm and hardness was 24.37 N.
Rheological behavior of recovery proteins was similar, but the G’ and G’’ moduli were higher in PR_ALC.
The L* and a* value were higher in PR_ALC but had a lower b* value. PR_ALC was also whiter than PR_AC.
The acid solubilization led to a decrease of 90 % of phospholipids with 1:6 fish:water ratio and 82 % with 1:9 ratio. At alkali solubilization the phospholipids removal was about 75 % with 1:9 relation.
At 5-10 mM CaCl2 and 1-5 mM citric acid showed an optimal effect on phospholipids removal.
In the presence of citric acid and CaCl2 phospholipid removal from PR_AC was 59 % (1:6 ratio) and 41 % (1:9 ratio) and 74 % for PR_ALC (1:9 ratio).
Advisors/Committee Members: Pires, Carla Maria Feio, Mourato, Miguel Barbosa.
Subjects/Keywords: acid and alkaline solubilization; recovered proteins; functional properties; texture; rheological properties; phospholopids removal
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Salgado, R. A. F. (2015). Caracterização e recuperação de proteínas de subprodutos de pescado. (Thesis). Technical University of Lisbon. Retrieved from https://www.rcaap.pt/detail.jsp?id=oai:www.repository.utl.pt:10400.5/11170
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Salgado, Rita Alexandra Fernandes. “Caracterização e recuperação de proteínas de subprodutos de pescado.” 2015. Thesis, Technical University of Lisbon. Accessed March 04, 2021.
https://www.rcaap.pt/detail.jsp?id=oai:www.repository.utl.pt:10400.5/11170.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Salgado, Rita Alexandra Fernandes. “Caracterização e recuperação de proteínas de subprodutos de pescado.” 2015. Web. 04 Mar 2021.
Vancouver:
Salgado RAF. Caracterização e recuperação de proteínas de subprodutos de pescado. [Internet] [Thesis]. Technical University of Lisbon; 2015. [cited 2021 Mar 04].
Available from: https://www.rcaap.pt/detail.jsp?id=oai:www.repository.utl.pt:10400.5/11170.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Salgado RAF. Caracterização e recuperação de proteínas de subprodutos de pescado. [Thesis]. Technical University of Lisbon; 2015. Available from: https://www.rcaap.pt/detail.jsp?id=oai:www.repository.utl.pt:10400.5/11170
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Delft University of Technology
19.
Aldin, Zainab (author).
3D printing of Geopolymer Concrete.
Degree: 2019, Delft University of Technology
URL: http://resolver.tudelft.nl/uuid:7862fc20-7b66-40ca-957a-7bca1ec20e54
► In spite of the fact that there are many advantages of alkali activated materials (also called geopolymers) over the cement-based materials, geopolymer concrete has been…
(more)
▼ In spite of the fact that there are many advantages of alkali activated materials (also called geopolymers) over the cement-based materials, geopolymer concrete has been used in the past for construction purposes on a very limited level. Among the many advantages of geopolymers compared with the cement-based materials is less CO2 emission, it uses byproducts as a binder, less energy consumption during its production, more durable as a material, fast setting time and high strength development. This work is an attempt to exert some light on the usability and applicability of geopolymers in the field of construction with concentration on its use in the 3D printing. The main aim of this study is to propose a design methodology for geopolymer paste mixture to be used in 3D printing process. For achieving this goal, one paste mixture design was selected among six ones on the bases of longer workability/flowability, suitable extrudability and specific setting time. These six designs have different binder ratios. The selected mixture design, named S20, was tested further to find out its suitability for 3D printing process. This S20 mixture was tested on compressive strength, setting time, rheological properties, open time, buildability and 28 days tensile bonding strength of two layers. To find the best suitable design, modifications were done on the S20 mixture by changing the ratios between the used alkaline solutions Na2SiO3 and NaOH (0.25 was selected). These alkaline solutions played a major role in delaying the initial setting time for rheological tests (90 minutes were selected) and the extrudability for the 3D printing process. Another factor for the best design is the Acti-gel as an additive. This additive has a direct link with the buildability, extrudability and viscosity when added with different percentages. The best selected percentage of the Acti-gel was 0.75% for this mixture design. The open time and the 28 days tensile bonding strength tests were selected to be 33 minutes and 1.32 MPa respectively. Comparing the measured plastic viscosity to the open time test, the extrudability of the mixture is not anymore valid beyond 8.8 Pa.s plastic viscosity. This short open time of 33 minutes for such geopolymer mixture design needs a fast-performing 3D printer. This might help in achieving construction projects within short time.
Civil Engineering
Advisors/Committee Members: Ye, Guang (mentor), Schlangen, Erik (graduation committee), Nugteren, Henk (graduation committee), Delft University of Technology (degree granting institution).
Subjects/Keywords: 3D Printing; Alkaline activated materials; geopolymers; Rheological properties; Mechanical properties; Setting time
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Aldin, Z. (. (2019). 3D printing of Geopolymer Concrete. (Masters Thesis). Delft University of Technology. Retrieved from http://resolver.tudelft.nl/uuid:7862fc20-7b66-40ca-957a-7bca1ec20e54
Chicago Manual of Style (16th Edition):
Aldin, Zainab (author). “3D printing of Geopolymer Concrete.” 2019. Masters Thesis, Delft University of Technology. Accessed March 04, 2021.
http://resolver.tudelft.nl/uuid:7862fc20-7b66-40ca-957a-7bca1ec20e54.
MLA Handbook (7th Edition):
Aldin, Zainab (author). “3D printing of Geopolymer Concrete.” 2019. Web. 04 Mar 2021.
Vancouver:
Aldin Z(. 3D printing of Geopolymer Concrete. [Internet] [Masters thesis]. Delft University of Technology; 2019. [cited 2021 Mar 04].
Available from: http://resolver.tudelft.nl/uuid:7862fc20-7b66-40ca-957a-7bca1ec20e54.
Council of Science Editors:
Aldin Z(. 3D printing of Geopolymer Concrete. [Masters Thesis]. Delft University of Technology; 2019. Available from: http://resolver.tudelft.nl/uuid:7862fc20-7b66-40ca-957a-7bca1ec20e54

Brno University of Technology
20.
Hampapa, Břetislav.
Reakce HDPE v tavenině iniciované peroxidy: Reactions of HDPE in the melt initiated by peroxides.
Degree: 2019, Brno University of Technology
URL: http://hdl.handle.net/11012/6159
► The thesis deals with HDPE modification by crosslinking. In the theoretical part, data available in the literature were reviewed. Modifications of the selected HDPE copolymer…
(more)
▼ The thesis deals with HDPE modification by crosslinking. In the theoretical part, data available in the literature were reviewed. Modifications of the selected HDPE copolymer grade were carried out in a kneading device Brabender using 25 ml chamber size. After having optimized process conditions, there were performed a series of experiments in dependence on concentration of the initiator. Reological
properties of polymer samples were investigated by melt flow indexes measured under different conditions. Changes in crystallinity and melting temperatures were evaluated from DSC heat flow measurements. The samples meeting characteristics supposed were selected for measuring complex viscosity on the Rheometer AR-G2 TA and for testing some mechanical
properties on the device Zwick.
Advisors/Committee Members: Petrůj, Jaroslav (advisor), Kučera, František (referee).
Subjects/Keywords: polyethylen; síťování; reologické vlastnosti; mechanické vlastnosti. krystalinita; polyethylene; crosslinking; rheological properties; mechanical properties; crystallinity
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Hampapa, B. (2019). Reakce HDPE v tavenině iniciované peroxidy: Reactions of HDPE in the melt initiated by peroxides. (Thesis). Brno University of Technology. Retrieved from http://hdl.handle.net/11012/6159
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Hampapa, Břetislav. “Reakce HDPE v tavenině iniciované peroxidy: Reactions of HDPE in the melt initiated by peroxides.” 2019. Thesis, Brno University of Technology. Accessed March 04, 2021.
http://hdl.handle.net/11012/6159.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Hampapa, Břetislav. “Reakce HDPE v tavenině iniciované peroxidy: Reactions of HDPE in the melt initiated by peroxides.” 2019. Web. 04 Mar 2021.
Vancouver:
Hampapa B. Reakce HDPE v tavenině iniciované peroxidy: Reactions of HDPE in the melt initiated by peroxides. [Internet] [Thesis]. Brno University of Technology; 2019. [cited 2021 Mar 04].
Available from: http://hdl.handle.net/11012/6159.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Hampapa B. Reakce HDPE v tavenině iniciované peroxidy: Reactions of HDPE in the melt initiated by peroxides. [Thesis]. Brno University of Technology; 2019. Available from: http://hdl.handle.net/11012/6159
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

University of Bradford
21.
Shriky, Banah.
Thermosensitive injectable pluronic hydrogels for controlled drug release : characterisation of thermal, rheological and structural properties of injectable pharmaceutical formulations.
Degree: PhD, 2018, University of Bradford
URL: http://hdl.handle.net/10454/17364
► This study seeks to develop smart hydrogel formulations for injectable controlled drug delivery from Pluronics to enhance patients compliance, decrease side effects, reduce dose and…
(more)
▼ This study seeks to develop smart hydrogel formulations for injectable controlled drug delivery from Pluronics to enhance patients compliance, decrease side effects, reduce dose and frequency. A biocompatible copolymer, Pluronic F127 was probed as the main ingredient for the injectable systems owing its low gelation concentration and ease of modification the system properties through excipients addition. The matrix properties were studied through a series of thermal, rheological and structural (SAXS/SANS) experiments as a function of concentration and shear rate, covering both static and dynamic environments. It has shown that gelled viscosity (and structure) can be critically controlled by shear rate and the structures recorded do not match those predicted for sheared colloids. Two further Pluronics F68 and F108, were studied showing similar but shifted gelation properties to F127. Effects of additives were studied by introducing different Mw PEGs and a model hydrophobic drug 'ibuprofen' to a F127 20% formulation. PEGs addition effects on the system properties and gelation transition were largely dependent on the Mw used in the blend, which became more prominent with increasing chain length. Ibuprofen's addition has resulted in reduced gelation temperature and smaller hard spheres without having a great effect on the system rheological properties compared to neat gels. Blends containing both additives PEG and ibuprofen exhibited a synergistic effect, where comparisons show that Ibuprofen had the largest effect on the blends lowering gelation boundaries and slightly increasing the size of the hard spheres indicating the necessity of full characterisation of the formulation with any API.
Subjects/Keywords: Thermosensitive; Gel; Thermal properties; Rheological properties; SAXS; SANS; Drug release; Pluronic; Colloidal crystals; Delivery systems
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Shriky, B. (2018). Thermosensitive injectable pluronic hydrogels for controlled drug release : characterisation of thermal, rheological and structural properties of injectable pharmaceutical formulations. (Doctoral Dissertation). University of Bradford. Retrieved from http://hdl.handle.net/10454/17364
Chicago Manual of Style (16th Edition):
Shriky, Banah. “Thermosensitive injectable pluronic hydrogels for controlled drug release : characterisation of thermal, rheological and structural properties of injectable pharmaceutical formulations.” 2018. Doctoral Dissertation, University of Bradford. Accessed March 04, 2021.
http://hdl.handle.net/10454/17364.
MLA Handbook (7th Edition):
Shriky, Banah. “Thermosensitive injectable pluronic hydrogels for controlled drug release : characterisation of thermal, rheological and structural properties of injectable pharmaceutical formulations.” 2018. Web. 04 Mar 2021.
Vancouver:
Shriky B. Thermosensitive injectable pluronic hydrogels for controlled drug release : characterisation of thermal, rheological and structural properties of injectable pharmaceutical formulations. [Internet] [Doctoral dissertation]. University of Bradford; 2018. [cited 2021 Mar 04].
Available from: http://hdl.handle.net/10454/17364.
Council of Science Editors:
Shriky B. Thermosensitive injectable pluronic hydrogels for controlled drug release : characterisation of thermal, rheological and structural properties of injectable pharmaceutical formulations. [Doctoral Dissertation]. University of Bradford; 2018. Available from: http://hdl.handle.net/10454/17364

Texas State University – San Marcos
22.
Kim, Hyunhwan.
Characterization of Rubberized Binders with Wax Additives.
Degree: PhD, Materials Science, Engineering, and Commercialization, 2016, Texas State University – San Marcos
URL: https://digital.library.txstate.edu/handle/10877/11611
► Crumb rubber is widely used as an environment-friendly material in asphalt industry to improve pavement performance properties. Warm mixture asphalt (WMA) refers to the technologies…
(more)
▼ Crumb rubber is widely used as an environment-friendly material in asphalt industry to improve pavement performance
properties. Warm mixture asphalt (WMA) refers to the technologies which allow a substantial reduction of mixing and compaction temperatures of asphalt mixtures through decreasing the viscosity of asphalt binders. In general, the crumb rubber modified (CRM) asphalt mixes require higher temperatures compared to conventional hot mix asphalt (HMA). However, if the technologies of WMA are incorporated, it is predicted to reduce the mixing and compaction temperatures of rubberized asphalt mixtures. For utilization of rubberized mixes in WMA industry, it is needed to investigate the
properties of CRM binders with warm additives depending on CRM contents, additive types, aging states, and other experiment variables. This research investigated CRM binders with wax warm additives, and the objectives included: 1) quantifying viscosity changes dependent upon mixing temperature and hauling period through Rotational viscometer test; 2) evaluating the effect of blending time on viscosity; 3) investigating the performance
properties of recycled aged CRM binders containing wax additives through Superpave binder tests; 4) evaluating the microstructural
properties using an environmental scanning electron microscope (ESEM) and an atomic force microscopy (AFM). The following conclusions were drawn based on the comprehensive laboratory investigation: 1) crumb rubber contents and wax types were found to have significantinfluence on the viscosity
properties of CRM binders; 2) CRM binder with wax additive (LEADCAP) showed better rutting and cracking resistance compared to the control CRM binder for all aging states; 3) the wax additive in recycled CRM binder is observed to play an important role in binder
properties even after subjecting to long-term aging processes; 4) the microstructures on morphology images seemed to have a good relation with the engineering
properties of warm CRM binders.
Advisors/Committee Members: Lee, Soon-Jae (advisor), Sriraman, Vedaraman (committee member), Kim, Yoo Jae (committee member), You, Byoung Hee (committee member), Song, In-Hyouk (committee member), Torres, Anthony (committee member).
Subjects/Keywords: Rubberized binder; Warm mix asphalt binder; Viscosity; Rheological properties; Recycling; Microstructural properties
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Kim, H. (2016). Characterization of Rubberized Binders with Wax Additives. (Doctoral Dissertation). Texas State University – San Marcos. Retrieved from https://digital.library.txstate.edu/handle/10877/11611
Chicago Manual of Style (16th Edition):
Kim, Hyunhwan. “Characterization of Rubberized Binders with Wax Additives.” 2016. Doctoral Dissertation, Texas State University – San Marcos. Accessed March 04, 2021.
https://digital.library.txstate.edu/handle/10877/11611.
MLA Handbook (7th Edition):
Kim, Hyunhwan. “Characterization of Rubberized Binders with Wax Additives.” 2016. Web. 04 Mar 2021.
Vancouver:
Kim H. Characterization of Rubberized Binders with Wax Additives. [Internet] [Doctoral dissertation]. Texas State University – San Marcos; 2016. [cited 2021 Mar 04].
Available from: https://digital.library.txstate.edu/handle/10877/11611.
Council of Science Editors:
Kim H. Characterization of Rubberized Binders with Wax Additives. [Doctoral Dissertation]. Texas State University – San Marcos; 2016. Available from: https://digital.library.txstate.edu/handle/10877/11611
23.
Chia, Christine.
Comparative Evaluation of Field and Laboratory-Produced Foamed Asphalt Mixture from Reno, Nevada.
Degree: 2012, University of Nevada – Reno
URL: http://hdl.handle.net/11714/3706
► This study evaluated the properties and performance of field-produced HMA and foamed WMA mixtures from the Bravo Ave project in Reno, Nevada in comparison to…
(more)
▼ This study evaluated the
properties and performance of field-produced HMA and foamed WMA mixtures from the Bravo Ave project in Reno, Nevada in comparison to respective laboratory-produced mixtures utilizing the same materials and mix design. Each mixture contained 15% RAP and was produced with a polymer-modified PG64-28NV asphalt binder. The
rheological properties were evaluated for virgin, RAP and extracted/recovered asphalt binders from field and plant-produced mixtures. The mixtures were evaluated for their resistance to moisture damage by means of measuring the dynamic modulus |E*| and the indirect tensile strength as a function of multiple freeze-thaw cycling. The resistance of the mixtures to permanent deformation was evaluated through the use of the repeated load triaxial (RLT) to measure the flow number (FN). The low-temperature cracking resistance of the mixtures was evaluated using the thermal stress restrained specimen test (TSRST). From this study it was determined that the HMA had better resistance to moisture damage and permanent deformation than the foamed WMA mixtures. Between the HMA and foamed WMA mixtures, similar asphalt
properties and resistance to thermal cracking were seen. The laboratory-produced mixtures did not exhibit similar behaviors as those seen with the field-produced mixtures. Also, reheating of the mixtures from an ambient temperature after mixing seems to only improve the resistance of the mixtures to moisture damage. The non-reheated mixtures had equal or better resistance to permanent deformation and thermal cracking than their reheated counterparts.
Advisors/Committee Members: Sebaaly, Peter E. (advisor), Hajj, Elie Y. (advisor), Sebaaly, Peter (committee member), Hajj, Elie Y. (committee member), Siddharthan, Raj (committee member), Quint, Thomas (committee member).
Subjects/Keywords: FMLC Asphalt Mixtures; Foamed WMA; LMLC Asphalt Mixtures; Mechanical Properties; RAP; Rheological Properties; WRSC
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Chia, C. (2012). Comparative Evaluation of Field and Laboratory-Produced Foamed Asphalt Mixture from Reno, Nevada. (Thesis). University of Nevada – Reno. Retrieved from http://hdl.handle.net/11714/3706
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Chia, Christine. “Comparative Evaluation of Field and Laboratory-Produced Foamed Asphalt Mixture from Reno, Nevada.” 2012. Thesis, University of Nevada – Reno. Accessed March 04, 2021.
http://hdl.handle.net/11714/3706.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Chia, Christine. “Comparative Evaluation of Field and Laboratory-Produced Foamed Asphalt Mixture from Reno, Nevada.” 2012. Web. 04 Mar 2021.
Vancouver:
Chia C. Comparative Evaluation of Field and Laboratory-Produced Foamed Asphalt Mixture from Reno, Nevada. [Internet] [Thesis]. University of Nevada – Reno; 2012. [cited 2021 Mar 04].
Available from: http://hdl.handle.net/11714/3706.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Chia C. Comparative Evaluation of Field and Laboratory-Produced Foamed Asphalt Mixture from Reno, Nevada. [Thesis]. University of Nevada – Reno; 2012. Available from: http://hdl.handle.net/11714/3706
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Universidade do Rio Grande do Norte
24.
Santana, Keila Regina.
Interações entre a carboximetilcelulose, carbonato de cálcio
e bentonita: repercussões sobre as propriedades dos fluidos de
perfuração aquosos
.
Degree: 2014, Universidade do Rio Grande do Norte
URL: http://repositorio.ufrn.br/handle/123456789/17795
► The role of carboxymethylcellulose (CMC) in association to calcium carbonate particles (CaCO3) in most water-based drilling fluids is to reduce the fluid loss to the…
(more)
▼ The role of carboxymethylcellulose (CMC) in association to calcium carbonate particles
(CaCO3) in most water-based drilling fluids is to reduce the fluid loss to the surrounding
formation. Another essential function is to provide
rheological properties capable of
maintaining in suspension the cuttings during drilling operation. Therefore, it is
absolutely essential to correlate the polymer chemical structure (degree of substitution,
molecular weight and distribution of substituent) with the physical-chemical
properties
of CaCO3, in order to obtain the better result at lower cost. Another important aspect
refers to the clay hydration inhibitive
properties of carboxymethylcellulose (CMC) in
drilling fluids systems. The clay swelling promotes an undesirable damage that reduces
the formation permeability and causes serious problems during the drilling operation. In
this context, this thesis consists of two main parts. The first part refers to understanding
of interactions CMC-CaCO3, as well as the corresponding effects on the fluid
properties. The second part is related to understanding of mechanisms by which CMC
adsorption occurs onto the clay surface, where, certainly, polymer chemical structure,
ionic strength, molecular weight and its solvency in the medium are responsible to
affect intrinsically the clay layers stabilization. Three samples of carboximetilcellulose
with different molecular weight and degree of substitution (CMC A (9 x 104 gmol DS
0.7), CMC B (2.5 x 105 gmol DS 0.7) e CMC C (2.5 x 105 gmol DS 1.2)) and three
samples of calcite with different average particle diameter and particle size distribution
were used. The increase of CMC degree of substitution contributed to increase of
polymer charge density and therefore, reduced its stability in brine, promoting the
aggregation with the increase of filtrate volume. On the other hand, the increase of
molecular weight promoted an increase of
rheological properties with reduction of
filtrate volume. Both effects are directly associated to hydrodynamic volume of polymer
molecule in the medium. The granulometry of CaCO3 particles influenced not only the
rheological properties, due to adsorption of polymers, but also the filtration
properties.
It was observed that the lower filtrate volume was obtained by using a CaCO3 sample of
a low average size particle with wide dispersion in size. With regards to inhibition of
clay swelling, the CMC performance was compared to other products often used
(sodium chloride (NaCl), potassium chloride (KCl) and quaternary amine-based
commercial inhibitor). The low molecular weight CMC (9 x 104 g/mol) showed slightly
lower swelling degree compared to the high molecular weight (2.5 x 105 g/mol) along to
180 minutes. In parallel, it can be visualized by Scanning Electron Microscopy (SEM)
that the high molecular weight CMC (2.5 x 105 g/mol e DS 0.7) promoted a reduction in
pores formation and size of clay compared to low molecular weight CMC (9.0 x 104
g/mol e DS 0.7), after 1000 minutes in aqueous medium.…
Advisors/Committee Members: Balaban, Rosângela de Carvalho (advisor), CPF:65946499734 (advisor), http://lattes.cnpq.br/7711521318854102 (advisor).
Subjects/Keywords: Carboximetilcelulose. Filtração. Propriedades reológicas. Inchamento de
argila;
Carboxymethylcellulose. Filter loss. Rheological properties. Clay swelling
Record Details
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Santana, K. R. (2014). Interações entre a carboximetilcelulose, carbonato de cálcio
e bentonita: repercussões sobre as propriedades dos fluidos de
perfuração aquosos
. (Thesis). Universidade do Rio Grande do Norte. Retrieved from http://repositorio.ufrn.br/handle/123456789/17795
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Santana, Keila Regina. “Interações entre a carboximetilcelulose, carbonato de cálcio
e bentonita: repercussões sobre as propriedades dos fluidos de
perfuração aquosos
.” 2014. Thesis, Universidade do Rio Grande do Norte. Accessed March 04, 2021.
http://repositorio.ufrn.br/handle/123456789/17795.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Santana, Keila Regina. “Interações entre a carboximetilcelulose, carbonato de cálcio
e bentonita: repercussões sobre as propriedades dos fluidos de
perfuração aquosos
.” 2014. Web. 04 Mar 2021.
Vancouver:
Santana KR. Interações entre a carboximetilcelulose, carbonato de cálcio
e bentonita: repercussões sobre as propriedades dos fluidos de
perfuração aquosos
. [Internet] [Thesis]. Universidade do Rio Grande do Norte; 2014. [cited 2021 Mar 04].
Available from: http://repositorio.ufrn.br/handle/123456789/17795.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Santana KR. Interações entre a carboximetilcelulose, carbonato de cálcio
e bentonita: repercussões sobre as propriedades dos fluidos de
perfuração aquosos
. [Thesis]. Universidade do Rio Grande do Norte; 2014. Available from: http://repositorio.ufrn.br/handle/123456789/17795
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Universidade do Rio Grande do Norte
25.
Santana, Keila Regina.
Interações entre a carboximetilcelulose, carbonato de cálcio
e bentonita: repercussões sobre as propriedades dos fluidos de
perfuração aquosos
.
Degree: 2014, Universidade do Rio Grande do Norte
URL: http://repositorio.ufrn.br/handle/123456789/17795
► The role of carboxymethylcellulose (CMC) in association to calcium carbonate particles (CaCO3) in most water-based drilling fluids is to reduce the fluid loss to the…
(more)
▼ The role of carboxymethylcellulose (CMC) in association to calcium carbonate particles
(CaCO3) in most water-based drilling fluids is to reduce the fluid loss to the surrounding
formation. Another essential function is to provide
rheological properties capable of
maintaining in suspension the cuttings during drilling operation. Therefore, it is
absolutely essential to correlate the polymer chemical structure (degree of substitution,
molecular weight and distribution of substituent) with the physical-chemical
properties
of CaCO3, in order to obtain the better result at lower cost. Another important aspect
refers to the clay hydration inhibitive
properties of carboxymethylcellulose (CMC) in
drilling fluids systems. The clay swelling promotes an undesirable damage that reduces
the formation permeability and causes serious problems during the drilling operation. In
this context, this thesis consists of two main parts. The first part refers to understanding
of interactions CMC-CaCO3, as well as the corresponding effects on the fluid
properties. The second part is related to understanding of mechanisms by which CMC
adsorption occurs onto the clay surface, where, certainly, polymer chemical structure,
ionic strength, molecular weight and its solvency in the medium are responsible to
affect intrinsically the clay layers stabilization. Three samples of carboximetilcellulose
with different molecular weight and degree of substitution (CMC A (9 x 104 gmol DS
0.7), CMC B (2.5 x 105 gmol DS 0.7) e CMC C (2.5 x 105 gmol DS 1.2)) and three
samples of calcite with different average particle diameter and particle size distribution
were used. The increase of CMC degree of substitution contributed to increase of
polymer charge density and therefore, reduced its stability in brine, promoting the
aggregation with the increase of filtrate volume. On the other hand, the increase of
molecular weight promoted an increase of
rheological properties with reduction of
filtrate volume. Both effects are directly associated to hydrodynamic volume of polymer
molecule in the medium. The granulometry of CaCO3 particles influenced not only the
rheological properties, due to adsorption of polymers, but also the filtration
properties.
It was observed that the lower filtrate volume was obtained by using a CaCO3 sample of
a low average size particle with wide dispersion in size. With regards to inhibition of
clay swelling, the CMC performance was compared to other products often used
(sodium chloride (NaCl), potassium chloride (KCl) and quaternary amine-based
commercial inhibitor). The low molecular weight CMC (9 x 104 g/mol) showed slightly
lower swelling degree compared to the high molecular weight (2.5 x 105 g/mol) along to
180 minutes. In parallel, it can be visualized by Scanning Electron Microscopy (SEM)
that the high molecular weight CMC (2.5 x 105 g/mol e DS 0.7) promoted a reduction in
pores formation and size of clay compared to low molecular weight CMC (9.0 x 104
g/mol e DS 0.7), after 1000 minutes in aqueous medium.…
Advisors/Committee Members: Balaban, Rosângela de Carvalho (advisor), CPF:65946499734 (advisor), http://lattes.cnpq.br/7711521318854102 (advisor).
Subjects/Keywords: Carboximetilcelulose. Filtração. Propriedades reológicas. Inchamento de
argila;
Carboxymethylcellulose. Filter loss. Rheological properties. Clay swelling
Record Details
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Share »
Record Details
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Santana, K. R. (2014). Interações entre a carboximetilcelulose, carbonato de cálcio
e bentonita: repercussões sobre as propriedades dos fluidos de
perfuração aquosos
. (Doctoral Dissertation). Universidade do Rio Grande do Norte. Retrieved from http://repositorio.ufrn.br/handle/123456789/17795
Chicago Manual of Style (16th Edition):
Santana, Keila Regina. “Interações entre a carboximetilcelulose, carbonato de cálcio
e bentonita: repercussões sobre as propriedades dos fluidos de
perfuração aquosos
.” 2014. Doctoral Dissertation, Universidade do Rio Grande do Norte. Accessed March 04, 2021.
http://repositorio.ufrn.br/handle/123456789/17795.
MLA Handbook (7th Edition):
Santana, Keila Regina. “Interações entre a carboximetilcelulose, carbonato de cálcio
e bentonita: repercussões sobre as propriedades dos fluidos de
perfuração aquosos
.” 2014. Web. 04 Mar 2021.
Vancouver:
Santana KR. Interações entre a carboximetilcelulose, carbonato de cálcio
e bentonita: repercussões sobre as propriedades dos fluidos de
perfuração aquosos
. [Internet] [Doctoral dissertation]. Universidade do Rio Grande do Norte; 2014. [cited 2021 Mar 04].
Available from: http://repositorio.ufrn.br/handle/123456789/17795.
Council of Science Editors:
Santana KR. Interações entre a carboximetilcelulose, carbonato de cálcio
e bentonita: repercussões sobre as propriedades dos fluidos de
perfuração aquosos
. [Doctoral Dissertation]. Universidade do Rio Grande do Norte; 2014. Available from: http://repositorio.ufrn.br/handle/123456789/17795

Iowa State University
26.
Gopalakrishnan Deivanai, Karthick Manikandan.
Additive printing for civil infrastructure: Assessing concrete mix design, printability and nozzle effects.
Degree: 2020, Iowa State University
URL: https://lib.dr.iastate.edu/etd/17937
► The need to automate the construction process for civil infrastructures has been perpetually propelled by the reported number of detrimental site accidents, enormous time, and…
(more)
▼ The need to automate the construction process for civil infrastructures has been perpetually propelled by the reported number of detrimental site accidents, enormous time, and material wastages in the current labor-intensive approaches. Additive 3D printing applications in the construction sector could revolutionize the construction sites. The 3D printing technologies will be an eco-friendly variant and will relax the formwork requirement, giving wider build customizability when compared to the traditional construction methods. The notable advantages of 3D printing over conventional construction techniques include safer work ambiance, reduced cost and time for construction.
The first objective of this research work is to identify the concrete mixture that is readily available for 3D printing and establish their material characteristics. This work serves up a model schema for researchers to look up and identify desired mixture properties for instantaneous concrete printing. In this study, ready-to-print fresh cementitious mixtures were characterized for printability and buildability based on their rheological and mechanical properties. Admixtures such as Silica fume and Superplasticizer were added to the ordinary Portland cement in different proportions to test and improve the yield stress and attain the desired viscosity for 3D printing.
The other objective is to study the impacts of using different nozzle geometries in the printed constructs. In the additive 3D printing process, choosing the right nozzle geometry before printing is critical as it affects the surface finish as well as the mechanical properties of the constructs. This study utilizes point cloud data of the printed samples obtained from Structured Light System- a scanning technique to measure the contour deviation and surface roughness. The compression strength of the mixtures was determined to explore the mechanical properties, by conducting compression tests as per the ASTM standards. A comparative study on the compression strength of 3D printed constructs with precast was made to identify the impacts of nozzle geometry in the compression strength.
To summarize, a concrete extrusion system has been built and the concrete flow properties that are desirable for instantaneous 3D printing have been identified. The rheological properties, printability, and buildability of all the identified concrete mixtures were evaluated and the best mixture proportions were advanced for printing constructs. The nozzle geometry study has established the impacts on the contour as well as the mechanical properties on the constructs, and hence urging the need to choose the right nozzle geometry before 3D printing.
Subjects/Keywords: Cement Additives; Concrete 3D Printing; Contour Deviation; Extrudability and Buildability; Nozzle Geometry; Rheological Properties
Record Details
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Gopalakrishnan Deivanai, K. M. (2020). Additive printing for civil infrastructure: Assessing concrete mix design, printability and nozzle effects. (Thesis). Iowa State University. Retrieved from https://lib.dr.iastate.edu/etd/17937
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Gopalakrishnan Deivanai, Karthick Manikandan. “Additive printing for civil infrastructure: Assessing concrete mix design, printability and nozzle effects.” 2020. Thesis, Iowa State University. Accessed March 04, 2021.
https://lib.dr.iastate.edu/etd/17937.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Gopalakrishnan Deivanai, Karthick Manikandan. “Additive printing for civil infrastructure: Assessing concrete mix design, printability and nozzle effects.” 2020. Web. 04 Mar 2021.
Vancouver:
Gopalakrishnan Deivanai KM. Additive printing for civil infrastructure: Assessing concrete mix design, printability and nozzle effects. [Internet] [Thesis]. Iowa State University; 2020. [cited 2021 Mar 04].
Available from: https://lib.dr.iastate.edu/etd/17937.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Gopalakrishnan Deivanai KM. Additive printing for civil infrastructure: Assessing concrete mix design, printability and nozzle effects. [Thesis]. Iowa State University; 2020. Available from: https://lib.dr.iastate.edu/etd/17937
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Univerzitet u Beogradu
27.
Laličić-Petronijević, Jovanka G., 1971-.
Senzorna, antioksidativna i reološka svojstva različitih
vrsta čokolada sa probioticima.
Degree: Poljoprivredni fakultet, 2013, Univerzitet u Beogradu
URL: https://fedorabg.bg.ac.rs/fedora/get/o:6488/bdef:Content/get
► Prehrambena tehnologija - Tehnologija ratarskih proizvoda / Food technology - Technology of crop products
Prehrambeni proizvodi koji sadrže probiotske mikroorganizme, uglavnom bakterije mlečne kiseline, sa…
(more)
▼ Prehrambena tehnologija - Tehnologija ratarskih
proizvoda / Food technology - Technology of crop
products
Prehrambeni proizvodi koji sadrže probiotske
mikroorganizme, uglavnom bakterije mlečne kiseline, sa pozitivnim
učincima po zdravlje, predstavljaju jedno od najvećih tržišta
funkcionalne hrane, među kojima su proizvodi od mleka
najdostupniji. Težnja da korisne, probiotske bakterije bezbednije i
lakše prežive uslove gastrointestinalnog trakta, kao i potreba da
budu dostupne tokom dužeg vremenskog perioda u odnosu na onaj koji
je ograničen trajnošću proizvoda od mleka, nametnula je ideju da se
obave opsežnija ispitivanja primene probiotika na čokoladi kao
nosaču. Program istraživanja u okviru ove doktorske disertacije bio
je usmeren na ispitivanje mogućnosti primene probiotika u različite
vrste čokolada, zbog njihove osetljivosti prema velikom broju
procesnih faktora i uslovima okoline, a imajući u vidu da je
održivost esencijalno svojstvo koje uslovljava njihovu efikasnost.
Inkluzijom probiotskih kultura uvodi se dodatna disperzna faza u
sastav čokolada, što može imati uticaja na njihovu mikrostrukturu i
usloviti promene izgleda - boje, teskture, topivosti i reoloških
svojstava. Pored navedenog, pojedina istraživanja ukazuju na
mogućnost postojanja interakcija između probiotskih mikroorganizama
i polifenolnih komponenata namirnice u koje su dodati, što može
dovesti do promene njenog antioksidativnog kapaciteta. Kako bi se
ustanovilo u kojoj meri je inkorporiranje probiotika uticalo na
dominantna svojstva različitih vrsta čokolada, obavljeno je
ispitivanje njihovih senzornih, antioksidativnih i reoloških
karakteristika neposredno nakon proizvodnje (0-30 dana) i tokom
skladištenja od 90, odnosno 180 dana. Radi utvrđivanja svih faktora
koji mogu uticati na funcionalnost čokolada sa probioticima
obavljene su i analize upotrebljenih ambalažnih materijala, koje su
obuhvatale ispitivanje fizičkomehaničkih i barijernih
svojstava...
Advisors/Committee Members: Popov-Raljić, Jovanka, 1953-.
Subjects/Keywords: Milk and dark chocolates; probiotics; sensory;
antioxidant and rheological properties; packaging;
functionality
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APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
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APA (6th Edition):
Laličić-Petronijević, Jovanka G., 1. (2013). Senzorna, antioksidativna i reološka svojstva različitih
vrsta čokolada sa probioticima. (Thesis). Univerzitet u Beogradu. Retrieved from https://fedorabg.bg.ac.rs/fedora/get/o:6488/bdef:Content/get
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Laličić-Petronijević, Jovanka G., 1971-. “Senzorna, antioksidativna i reološka svojstva različitih
vrsta čokolada sa probioticima.” 2013. Thesis, Univerzitet u Beogradu. Accessed March 04, 2021.
https://fedorabg.bg.ac.rs/fedora/get/o:6488/bdef:Content/get.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Laličić-Petronijević, Jovanka G., 1971-. “Senzorna, antioksidativna i reološka svojstva različitih
vrsta čokolada sa probioticima.” 2013. Web. 04 Mar 2021.
Vancouver:
Laličić-Petronijević, Jovanka G. 1. Senzorna, antioksidativna i reološka svojstva različitih
vrsta čokolada sa probioticima. [Internet] [Thesis]. Univerzitet u Beogradu; 2013. [cited 2021 Mar 04].
Available from: https://fedorabg.bg.ac.rs/fedora/get/o:6488/bdef:Content/get.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Laličić-Petronijević, Jovanka G. 1. Senzorna, antioksidativna i reološka svojstva različitih
vrsta čokolada sa probioticima. [Thesis]. Univerzitet u Beogradu; 2013. Available from: https://fedorabg.bg.ac.rs/fedora/get/o:6488/bdef:Content/get
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Loughborough University
28.
Sirisinha, Chakrit.
Mechanisms of extrudate swell and melt fracture in SBR compounds.
Degree: PhD, 1996, Loughborough University
URL: http://hdl.handle.net/2134/13770
► The purpose of this study is to identify and quantify factors governing extrudate swell and melt fracture. In the first part, the factors which control…
(more)
▼ The purpose of this study is to identify and quantify factors governing extrudate swell and melt fracture. In the first part, the factors which control the extrudate swell of carbon black (N330) filled styrene-butadiene rubber (SBR) compounds at various states-of-mix were investigated. State-of-mix is quantified by effective filler volume fraction (EFVF), based on an estimate of the amount of rubber immobilised in the carbon black agglomerates. Extrudate swell was found to be dominated by recoverable strain and relaxation time, which are controlled by EFVF. In contrast, shear rate and the rubber-carbon black tridimensional transient network were not found to influence extrudate swell significantly. In the second part, melt fracture of the rubber compounds was investigated in terms of surface texture wavelength. The longer the wavelength, the greater the severity of the surface disruption. It was found that wavelength was controlled strongly by state-of mix (or by EFVF). In addition, a mechanism for melt fracture of the compounds studied has been proposed, based on average energy at the extrudate surface (t.E). Lastly, the influences of additives; paraffinic processing oil, stearic acid or a mixture of predominantly calcium fatty acid soaps on extrudate swell and melt fracture were investigated. For the rubber compounds with paraffinic processing oil or stearic acid, EFVF was found to play an important role in extrudate swell. The mixture of fatty acid soaps was shown to reduce significantly extrudate swell due to the presence of wall slip. The influence of the fatty acid soaps on extrudate swell is more noticeable for extrudates obtained from long dies, in which flow is dominated by shear. The major factors shown to exert a significant influence on melt fracture for the compounds with paraffinic processing oil or stearic acid are EFVF and green strength of the extrudate. Wall slip, promoted by a mixture of fatty acid soaps, was also found to decrease the melt fracture severity, particularly for long dies in which shear stresses are dominant.
Subjects/Keywords: 678; Polymer melt flows; Rheological properties
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Sirisinha, C. (1996). Mechanisms of extrudate swell and melt fracture in SBR compounds. (Doctoral Dissertation). Loughborough University. Retrieved from http://hdl.handle.net/2134/13770
Chicago Manual of Style (16th Edition):
Sirisinha, Chakrit. “Mechanisms of extrudate swell and melt fracture in SBR compounds.” 1996. Doctoral Dissertation, Loughborough University. Accessed March 04, 2021.
http://hdl.handle.net/2134/13770.
MLA Handbook (7th Edition):
Sirisinha, Chakrit. “Mechanisms of extrudate swell and melt fracture in SBR compounds.” 1996. Web. 04 Mar 2021.
Vancouver:
Sirisinha C. Mechanisms of extrudate swell and melt fracture in SBR compounds. [Internet] [Doctoral dissertation]. Loughborough University; 1996. [cited 2021 Mar 04].
Available from: http://hdl.handle.net/2134/13770.
Council of Science Editors:
Sirisinha C. Mechanisms of extrudate swell and melt fracture in SBR compounds. [Doctoral Dissertation]. Loughborough University; 1996. Available from: http://hdl.handle.net/2134/13770

Michigan Technological University
29.
You, Lingyun.
EVALUATION OF RHEOLOGICAL AND MECHANICAL PROPERTIES OF FOAMED AND EMULSIFIED ASPHALT MATERIALS.
Degree: PhD, Department of Civil and Environmental Engineering, 2019, Michigan Technological University
URL: https://digitalcommons.mtu.edu/etdr/963
► Foamed asphalt (water-foamed asphalt in this study) is formed by combining hot asphalt with a small amount of cold water, while emulsified asphalt is…
(more)
▼ Foamed asphalt (water-foamed asphalt in this study) is formed by combining hot asphalt with a small amount of cold water, while emulsified asphalt is simply a suspension of small asphalt cement globules in water, which is assisted by an emulsifying agent (or surfactant). The foaming and emulsifying processes are the water-based physical and chemical processes in decreasing the apparent viscosity of asphalt, respectively. Both foamed and emulsified asphalt materials containing some free water, and have been widely used in the cold, half-warm, and warm mix asphalt productions. Also, the pavement surface treatments and maintenances are involved in these asphalt materials. However, it is limited to a profound understanding of mechanical performance and corresponding physicochemical
properties. The objectives of this study are 1) to characterize the
rheological properties of foamed and emulsified asphalt materials, 2) and to evaluate the mechanical
properties of its mixtures in the applications of pavement construction, surface treatments, and pavement maintenances.
The
rheological behavior of foamed asphalt was measured at various temperatures and with different water content can provide the apparent viscosity and agitation torque of the foamed asphalt. Besides, according to the dynamic foaming processes of the foamed asphalt, this study successfully applied the dynamic movement of water vapor or bubble in foamed asphalt to disperse the nano hydrated lime (NHL) particles in the suspensions into the asphalt. The dispersion condition and the microstructure of the nanoparticles in the asphalt were evaluated via scanning electron microscopy (SEM) and X-ray diffraction (XRD), respectively. A surfactant of sodium dodecylbenzene sulfonate was added to the water to form suspensions before inserted into the hot asphalt. Also, the study characterized the impacts of the foaming condition and the multiple freeze-thaw cycles on the laboratory tensile strength tests via Materials Testing System (MTS) of the foamed asphalt mixtures. Then, the nondestructive ultrasonic direct test was applied to assess the foamed asphalt mixture damage level after the multiple freeze-thaw cycles.
Meanwhile, for another kind of asphalt material containing free water (emulsified asphalt), the interactions of asphalt and water in the emulsified asphalt were characterized first. The moisture (or water) retention of emulsified asphalts during the oven heating was applied to assess the emulsification stability at different acidic and alkaline levels. The dynamic shear rheometer (DSR) experiments characterized the apparent viscosity and rutting indicator as to the parameters for expressing the
rheological properties of both emulsified asphalts and the individual residues. The Fourier-transform infrared spectroscopy (FT/IR) analyzed the interactions of asphalt and water in emulsified asphalt from the perspective of molecular chemistry. After that, the application of emulsified asphalt on pavement maintenance; the example of chip-seal was…
Advisors/Committee Members: Zhanping You, Qingli Dai.
Subjects/Keywords: Adhesion; Bond Strength; Emulsified Asphalt; Foamed Asphalt; Nano Hydrated Lime; Rheological Properties; Civil Engineering
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
You, L. (2019). EVALUATION OF RHEOLOGICAL AND MECHANICAL PROPERTIES OF FOAMED AND EMULSIFIED ASPHALT MATERIALS. (Doctoral Dissertation). Michigan Technological University. Retrieved from https://digitalcommons.mtu.edu/etdr/963
Chicago Manual of Style (16th Edition):
You, Lingyun. “EVALUATION OF RHEOLOGICAL AND MECHANICAL PROPERTIES OF FOAMED AND EMULSIFIED ASPHALT MATERIALS.” 2019. Doctoral Dissertation, Michigan Technological University. Accessed March 04, 2021.
https://digitalcommons.mtu.edu/etdr/963.
MLA Handbook (7th Edition):
You, Lingyun. “EVALUATION OF RHEOLOGICAL AND MECHANICAL PROPERTIES OF FOAMED AND EMULSIFIED ASPHALT MATERIALS.” 2019. Web. 04 Mar 2021.
Vancouver:
You L. EVALUATION OF RHEOLOGICAL AND MECHANICAL PROPERTIES OF FOAMED AND EMULSIFIED ASPHALT MATERIALS. [Internet] [Doctoral dissertation]. Michigan Technological University; 2019. [cited 2021 Mar 04].
Available from: https://digitalcommons.mtu.edu/etdr/963.
Council of Science Editors:
You L. EVALUATION OF RHEOLOGICAL AND MECHANICAL PROPERTIES OF FOAMED AND EMULSIFIED ASPHALT MATERIALS. [Doctoral Dissertation]. Michigan Technological University; 2019. Available from: https://digitalcommons.mtu.edu/etdr/963

University of New Mexico
30.
Pan, Jielin.
A study of Asphalt Aging Behavior Using Molecular Dynamics Simulations.
Degree: Civil Engineering, 2016, University of New Mexico
URL: http://hdl.handle.net/1928/31738
► Oxidative aging is a major issue in asphalt pavements that leads to hardening of the asphalt, which further contributes significantly to asphalt pavement embrittlement and…
(more)
▼ Oxidative aging is a major issue in asphalt pavements that leads to hardening of the asphalt, which further contributes significantly to asphalt pavement embrittlement and eventually results in excessive pavement cracking. In addition, the performance of asphalt binder is also highly related to its service conditions which involve climatic conditions and traffic conditions, such as temperature, moisture and traffic loads. Generally, the mechanical
properties of asphalt before and after oxidative aging can be tested in the laboratory; however, the fundamental material science of asphalt before and after oxidative aging is difficult to be investigated in the laboratory regarding chemical composition and property change due to the difficulties of studying the molecular structures and their dynamic behavior in asphalt. Therefore, Molecular Dynamics (MD) simulation method is used in this study to understand how the chemical composition and property changes of asphalt after oxidative aging affect the physical, thermodynamic,
rheological and mechanical performance of the asphalt, and how the oxidized asphalt acts under different conditions, such as loading, temperature, and moisture, compared to the unoxidized asphalt. MD simulation is a computational method used to simulate the physical movements of atoms and molecules depending on time and force field chosen under different conditions, such as temperature, pressure, and loading. Asphalt models before and after oxidative aging are developed for MD simulations in this study under different temperatures, loading and moisture contents. Simulation results show that the oxidized functional groups in asphalt molecules increase the strength of intermolecular bonds of asphalt, which further contributes to the hardening of the oxidized asphalt. Specifically, the internal energy changes, especially for higher magnitude of intermolecular and lower kinetic energies, are responsible for the hardening of oxidized asphalt, and the higher potential energies and for oxidized asphalt further proves that oxidation increases the polarity of molecules in asphalt and forms strongly interacting components. The internal property change is consistent with the external physical and
rheological property change after oxidation, which is revealed by the increase of density, bulk modulus and viscosity. Considering the mechanical property of asphalt using MD simulations, both the unoxidized and oxidized asphalts deform more and fail faster with an increase in both compressive and tensile stress rates, especially under tensile stresses. However, the oxidized asphalt is stiffer than the unoxidized asphalt, which shows slower and less deformation, further validating the hardening of asphalt after oxidation. Asphalt is significantly susceptible to temperature. Simulation results show that density, and zero shear viscosity of asphalt decrease with an increase in temperature. Isothermal compressibility and bulk modulus also change under different temperatures. Moreover, the density, bulk modulus (inverse of…
Advisors/Committee Members: Tarefder, Rafiqul, Shen, Yu-Lin, Ng, Tang-Tat, Zhang, Guohui, Tarefder, Rafiqul.
Subjects/Keywords: Molecular Dynamics Simulation; Asphalt Oxidative Aging; Physical; Rheological and Mechanical Properties; Temperature and Mositure Impacts
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Pan, J. (2016). A study of Asphalt Aging Behavior Using Molecular Dynamics Simulations. (Doctoral Dissertation). University of New Mexico. Retrieved from http://hdl.handle.net/1928/31738
Chicago Manual of Style (16th Edition):
Pan, Jielin. “A study of Asphalt Aging Behavior Using Molecular Dynamics Simulations.” 2016. Doctoral Dissertation, University of New Mexico. Accessed March 04, 2021.
http://hdl.handle.net/1928/31738.
MLA Handbook (7th Edition):
Pan, Jielin. “A study of Asphalt Aging Behavior Using Molecular Dynamics Simulations.” 2016. Web. 04 Mar 2021.
Vancouver:
Pan J. A study of Asphalt Aging Behavior Using Molecular Dynamics Simulations. [Internet] [Doctoral dissertation]. University of New Mexico; 2016. [cited 2021 Mar 04].
Available from: http://hdl.handle.net/1928/31738.
Council of Science Editors:
Pan J. A study of Asphalt Aging Behavior Using Molecular Dynamics Simulations. [Doctoral Dissertation]. University of New Mexico; 2016. Available from: http://hdl.handle.net/1928/31738
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