Advanced search options

Advanced Search Options 🞨

Browse by author name (“Author name starts with…”).

Find ETDs with:

in
/  
in
/  
in
/  
in

Written in Published in Earliest date Latest date

Sorted by

Results per page:

You searched for subject:(pillared paddlewheel). One record found.

Search Limiters

Last 2 Years | English Only

No search limiters apply to these results.

▼ Search Limiters

1. Palukoshka, Andrei. Functionalization of 1,6,7,12-Tetrachloroperylene Tetracarboxylic Acid Anhydride for Synthesis of Metal-Organic Frameworks in Energy Applications.

Degree: MS, Chemistry, 2020, Clemson University

1,6,7,12-tetrachloroperylene tetracarboxylic acid anhydride (PDACl4) is a fluorescent dye with a wide range of tunability. This work explores the functionalization of PDACl4 to exploit its supramolecular and photovoltaic (PV) capabilities. Synthesis of a novel pillared paddlewheel (PPW) metal-organic framework (MOF) using a bipyridyl functionalized tetrachloro perylene diimide (BPyPDICl4) pillar with 2,6-naphthalenedicarboxylic acid (2,6-NDC) struts was successfully achieved and confirmed with X-ray diffraction (XRD). The growth of the new MOF as a thin film on both zinc oxide and titanium dioxide-coated fluorine-doped tin oxide (FTO) glass was explored for its potential use in dye-sensitized solar cell (DSSC) type application using powder x-ray diffraction (PXRD), UV-Vis, and diffuse reflectance (DR) spectroscopy. Other solvothermal syntheses of UiO, MOF-5, and PPF-type MOFs using tetrachloro perylene diimide (PDICl4) ligands were performed and discussed. Organic synthesis of a new 4-tert-butylaniline based tetrachloro perylene diimide is reported along with its potential as a reaction intermediate. Bay substitution with cyclohexylamine, pyrrolidine, 1,2-dimethylhydrazie, 2-methoxyethanol, and pentaethylene glycol on various PDICl4 derivatives is investigated through different synthetic routes with a final goal of substituting all four bay position with electron-rich or cation-coordinating moieties on a perylene diimide with metal-coordinating imide groups. Future direction for the novel MOF and the application of the newly synthesized PDI ligands in MOF application is discussed. Advisors/Committee Members: Sourav Saha, George Chumanov, Stephen Creager.

Subjects/Keywords: 2; 6-naphthalenedicarboxylic acid; metal-organic framework; perylene diimide; photovoltaic; pillared-paddlewheel; solar cell

…perylene diimide paddlewheel PPF… …porphyrin paddlewheel PPW… …pillar paddlewheel PV… …has been demonstrated on a ZnO surface with a porphyrin paddlewheel (PPF) MOF. 23… …x5D;-Oriented Pillared Porphyrin Framework-11 Films on ZnO/FTO Surfaces. ACS applied… 

Record DetailsSimilar RecordsGoogle PlusoneFacebookTwitterCiteULikeMendeleyreddit

APA · Chicago · MLA · Vancouver · CSE | Export to Zotero / EndNote / Reference Manager

APA (6th Edition):

Palukoshka, A. (2020). Functionalization of 1,6,7,12-Tetrachloroperylene Tetracarboxylic Acid Anhydride for Synthesis of Metal-Organic Frameworks in Energy Applications. (Masters Thesis). Clemson University. Retrieved from https://tigerprints.clemson.edu/all_theses/3311

Chicago Manual of Style (16th Edition):

Palukoshka, Andrei. “Functionalization of 1,6,7,12-Tetrachloroperylene Tetracarboxylic Acid Anhydride for Synthesis of Metal-Organic Frameworks in Energy Applications.” 2020. Masters Thesis, Clemson University. Accessed November 28, 2020. https://tigerprints.clemson.edu/all_theses/3311.

MLA Handbook (7th Edition):

Palukoshka, Andrei. “Functionalization of 1,6,7,12-Tetrachloroperylene Tetracarboxylic Acid Anhydride for Synthesis of Metal-Organic Frameworks in Energy Applications.” 2020. Web. 28 Nov 2020.

Vancouver:

Palukoshka A. Functionalization of 1,6,7,12-Tetrachloroperylene Tetracarboxylic Acid Anhydride for Synthesis of Metal-Organic Frameworks in Energy Applications. [Internet] [Masters thesis]. Clemson University; 2020. [cited 2020 Nov 28]. Available from: https://tigerprints.clemson.edu/all_theses/3311.

Council of Science Editors:

Palukoshka A. Functionalization of 1,6,7,12-Tetrachloroperylene Tetracarboxylic Acid Anhydride for Synthesis of Metal-Organic Frameworks in Energy Applications. [Masters Thesis]. Clemson University; 2020. Available from: https://tigerprints.clemson.edu/all_theses/3311

.