subject:(free energy barrier)

Penn State University

1. Shahraz, Azar. Wetting Characteristics of Physically-patterned Solid Surfaces.

Degree: 2013, Penn State University

URL: https://submit-etda.libraries.psu.edu/catalog/19585

► This work aims to clarify the effect of surface topology on the kinetic and equilibrium behavior of a droplet deposited on a grooved surface. Specifically… (more)

▼ This work aims to clarify the effect of surface topology on the kinetic and equilibrium behavior of a droplet deposited on a grooved surface. Specifically the wetting behavior of a droplet on a grooved surface was studied in two different length scales: nano-scale simulation using molecular dynamics (MD) and macro-scale modeling by minimizing expressions for the free energies of various droplet wetting modes. The main advantage of our proposed model is that it accounts for pinning/de-pinning of the contact line at step edges, a feature that is not captured by the Cassie and Wenzel models. We also accounted for the effects of gravity (via the Bond number) on various wetting configurations that can occur. Using free-energy minimization, we constructed phase diagrams depicting the dependence of the wetting modes (including the number of surface grooves involved in the wetting configuration) and their corresponding contact angles on the geometrical parameters characterizing the patterned surface. In the limit of vanishing Bond number, the predicted wetting modes and contact angles become independent of drop size if the geometrical parameters are scaled with drop radius. To investigate the relevance of nanoscale simulations to wetting on macroscopic patterned surfaces, we employed MD to simulate the wetting of Lennard-Jones cylindrical droplets on surfaces patterned with grooves. Using a systematic surface parameter study, we found that, similar to macro-scale, the radius of the droplet is an appropriate length scale at nanoscale where the gravity does not play a significant role. Drop-size-independent wetting phase diagrams were constructed representing the possible equilibrium wetting configurations of a droplet as a function of surface geometry. Unlike macroscopic model, MD simulations exhibit wetting-mode multiplicity in the regions neighboring wetting-mode boundaries predicted by the model. This is likely due to a large free-energy barrier separating wetting states. Using forward flux sampling, we quantified the rate of theses wetting transitions and the corresponding energy-barriers. Our results show that surface topology play a significant role in determining the kinetic and equilibrium wetting characteristics of the surfaces. Advisors/Committee Members: Kristen Ann Fichthorn, Dissertation Advisor/Co-Advisor, Ali Borhan, Dissertation Advisor/Co-Advisor, Richard Hogg, Committee Member, Themis Matsoukas, Committee Member.

Subjects/Keywords: wetting; molecular dynamics; surface topology; free-energy barrier; forward flux sampling

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APA (6^th Edition):

Shahraz, A. (2013). Wetting Characteristics of Physically-patterned Solid Surfaces. (Thesis). Penn State University. Retrieved from https://submit-etda.libraries.psu.edu/catalog/19585

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Chicago Manual of Style (16^th Edition):

Shahraz, Azar. “Wetting Characteristics of Physically-patterned Solid Surfaces.” 2013. Thesis, Penn State University. Accessed April 11, 2021. https://submit-etda.libraries.psu.edu/catalog/19585.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

MLA Handbook (7^th Edition):

Shahraz, Azar. “Wetting Characteristics of Physically-patterned Solid Surfaces.” 2013. Web. 11 Apr 2021.

Vancouver:

Shahraz A. Wetting Characteristics of Physically-patterned Solid Surfaces. [Internet] [Thesis]. Penn State University; 2013. [cited 2021 Apr 11]. Available from: https://submit-etda.libraries.psu.edu/catalog/19585.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Council of Science Editors:

Shahraz A. Wetting Characteristics of Physically-patterned Solid Surfaces. [Thesis]. Penn State University; 2013. Available from: https://submit-etda.libraries.psu.edu/catalog/19585

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

University of Alberta

2. Fang, Guoping. Understanding the Role of Surface Microgeometries on Wetting: Designing Robust Superhydrophobic Surfaces.

Degree: MS, Department of Mechanical Engineering, 2014, University of Alberta

URL: https://era.library.ualberta.ca/files/n296wz44w

► This thesis is concerned with effects of surface microgeometries on wetting, aiming at providing instructions for reproducing controllable wettability on artificial surfaces and designing robust… (more)

Subjects/Keywords: Superhydrophobic Surface; Re-entrant Microstructures; Transition Energy Barrier; Contact Angle; Anti-Icing; Freezing Delay; Roughness; Frosting; Freezing Point; Thermodynamic; Drop Freezing; DSC; Wetting Map; Wetting Transition; Length Scale; Free Energy Barrier; Microgeometries; Microfabrication; Composite State; Edge Effect

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APA (6^th Edition):

Fang, G. (2014). Understanding the Role of Surface Microgeometries on Wetting: Designing Robust Superhydrophobic Surfaces. (Masters Thesis). University of Alberta. Retrieved from https://era.library.ualberta.ca/files/n296wz44w

Chicago Manual of Style (16^th Edition):

Fang, Guoping. “Understanding the Role of Surface Microgeometries on Wetting: Designing Robust Superhydrophobic Surfaces.” 2014. Masters Thesis, University of Alberta. Accessed April 11, 2021. https://era.library.ualberta.ca/files/n296wz44w.

MLA Handbook (7^th Edition):

Fang, Guoping. “Understanding the Role of Surface Microgeometries on Wetting: Designing Robust Superhydrophobic Surfaces.” 2014. Web. 11 Apr 2021.

Vancouver:

Fang G. Understanding the Role of Surface Microgeometries on Wetting: Designing Robust Superhydrophobic Surfaces. [Internet] [Masters thesis]. University of Alberta; 2014. [cited 2021 Apr 11]. Available from: https://era.library.ualberta.ca/files/n296wz44w.

Council of Science Editors:

Fang G. Understanding the Role of Surface Microgeometries on Wetting: Designing Robust Superhydrophobic Surfaces. [Masters Thesis]. University of Alberta; 2014. Available from: https://era.library.ualberta.ca/files/n296wz44w

Brno University of Technology

3. Kucserová, Aneta. Příprava a charakterizace vrstev deponovaných metodou plazmové polymerace na bázi 2-ethyl-2-oxazolinu: Preparation and characterization of layers deposited by plasma polymerization based on 2-Ethyl-2-oxazoline.

Degree: 2020, Brno University of Technology

URL: http://hdl.handle.net/11012/191038

► The diploma thesis deals with the deposition of layers of 2-ethyl-2-oxazoline monomer in a dielectric barrier discharge in a nitrogen atmosphere. The theoretical part describes… (more)

Subjects/Keywords: polyoxazolin; plazmová polymerace; plazma; dielektrický bariérový výboj; kontaktní úhel; volná povrchová energie; FTIR; XPS; polyoxazoline; plasma polymerization; plasma; dielectric barrier discharge; contact angle; free surface energy; FTIR; XPS

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APA (6^th Edition):

Kucserová, A. (2020). Příprava a charakterizace vrstev deponovaných metodou plazmové polymerace na bázi 2-ethyl-2-oxazolinu: Preparation and characterization of layers deposited by plasma polymerization based on 2-Ethyl-2-oxazoline. (Thesis). Brno University of Technology. Retrieved from http://hdl.handle.net/11012/191038

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Chicago Manual of Style (16^th Edition):

Kucserová, Aneta. “Příprava a charakterizace vrstev deponovaných metodou plazmové polymerace na bázi 2-ethyl-2-oxazolinu: Preparation and characterization of layers deposited by plasma polymerization based on 2-Ethyl-2-oxazoline.” 2020. Thesis, Brno University of Technology. Accessed April 11, 2021. http://hdl.handle.net/11012/191038.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

MLA Handbook (7^th Edition):

Kucserová, Aneta. “Příprava a charakterizace vrstev deponovaných metodou plazmové polymerace na bázi 2-ethyl-2-oxazolinu: Preparation and characterization of layers deposited by plasma polymerization based on 2-Ethyl-2-oxazoline.” 2020. Web. 11 Apr 2021.

Vancouver:

Kucserová A. Příprava a charakterizace vrstev deponovaných metodou plazmové polymerace na bázi 2-ethyl-2-oxazolinu: Preparation and characterization of layers deposited by plasma polymerization based on 2-Ethyl-2-oxazoline. [Internet] [Thesis]. Brno University of Technology; 2020. [cited 2021 Apr 11]. Available from: http://hdl.handle.net/11012/191038.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Council of Science Editors:

Kucserová A. Příprava a charakterizace vrstev deponovaných metodou plazmové polymerace na bázi 2-ethyl-2-oxazolinu: Preparation and characterization of layers deposited by plasma polymerization based on 2-Ethyl-2-oxazoline. [Thesis]. Brno University of Technology; 2020. Available from: http://hdl.handle.net/11012/191038

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

4. Feng, Lu. Experimental Study of Nucleation in Polystyrene/CO2 System.

Degree: PhD, Chemical and Biomolecular Engineering, 2012, The Ohio State University

URL: http://rave.ohiolink.edu/etdc/view?acc_num=osu1330866154

► Polymer foams have many applications, e.g., being used as insulation material, sound-adsorbing material, and packaging material, due to their features and enhanced performance, compared to… (more)

▼ Polymer foams have many applications, e.g., being used as insulation material, sound-adsorbing material, and packaging material, due to their features and enhanced performance, compared to the counterpart, namely pure polymers. Therefore, both industrial and academic communities have put much effort to investigate polymer foams from exploring new applications to enhancing the performance. Although progress has been made on those paths; one challenge remains, i.e., poor control of morphology of polymer foams. In order to fully address this challenge, fundamental understanding of morphology evolution is needed.Additionally, the traditional blowing agents for polymer foams, i.e., chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs), are banned from the market according to the Montreal protocol as these chemicals cause ozone depletion. Therefore, it is necessary to find a replacement for CFCs and HCFCs as blowing agents. Among all the promising alternatives, CO2 has attracted much interest due to being environmentally benign and it's relative ease of use, compared to other candidates, e.g., water and N2. In present study, nucleation, an important stage of morphology evolution in the polymer foaming process, is experimentally studied in the polystyrene/CO2 system. Specifically, nucleation experiments are conducted on different polystyrene/CO2 systems where polystyrene has different molecular weights. Then, based on the information extracted from nucleation experiments, a scaling curve in terms of free energy barrier of nucleation is constructed for the purpose of providing insight into the connection between phase equilibrium boundaries and nucleation phenomena. The result shows that the scaling curve is practically independent of molecular weight, indicating that the same scaling curve could be applied to different polystyrene/CO2 systems where polystyrene has different molecular weights for the prediction of free energy barrier of nucleation. Further, the finding that the scaling curve is practically independent of molecular weight of polystyrene partially confirms the claim that scaling curve is practically independent of intermolecular potentials. Advisors/Committee Members: Tomasko, David (Committee Chair).

Subjects/Keywords: Chemical Engineering; Polystyrene; Carbon dioxide; nucleation; foaming; free energy barrier

…131 A. The expression of free energy barrier of nucleation… …Accordingly, the free energy barrier is raised due to increased interfacial tension, leading to a… …their sizes are greater than the critical size [36], meaning the free energy barrier… …of 13 free energy barrier of nucleation is constructed for the purpose of providing… …nucleation experiment in chapter 4. In chapter 5, scaling curve in terms of free energy barrier of…

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APA (6^th Edition):

Feng, L. (2012). Experimental Study of Nucleation in Polystyrene/CO2 System. (Doctoral Dissertation). The Ohio State University. Retrieved from http://rave.ohiolink.edu/etdc/view?acc_num=osu1330866154

Chicago Manual of Style (16^th Edition):

Feng, Lu. “Experimental Study of Nucleation in Polystyrene/CO2 System.” 2012. Doctoral Dissertation, The Ohio State University. Accessed April 11, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=osu1330866154.

MLA Handbook (7^th Edition):

Feng, Lu. “Experimental Study of Nucleation in Polystyrene/CO2 System.” 2012. Web. 11 Apr 2021.

Vancouver:

Feng L. Experimental Study of Nucleation in Polystyrene/CO2 System. [Internet] [Doctoral dissertation]. The Ohio State University; 2012. [cited 2021 Apr 11]. Available from: http://rave.ohiolink.edu/etdc/view?acc_num=osu1330866154.

Council of Science Editors:

Feng L. Experimental Study of Nucleation in Polystyrene/CO2 System. [Doctoral Dissertation]. The Ohio State University; 2012. Available from: http://rave.ohiolink.edu/etdc/view?acc_num=osu1330866154

University of Maryland

5. Naganathan, Athi Narayanan. Barrier Heights and Diffusion Coefficients in Protein Folding.

Degree: Biochemistry, 2007, University of Maryland

URL: http://hdl.handle.net/1903/7321

► A widely held view with respect to the folding of single-domain proteins is that they are two-state. In other words, it is seemingly sufficient to… (more)

▼ A widely held view with respect to the folding of single-domain proteins is that they are two-state. In other words, it is seemingly sufficient to invoke just two thermodynamic macrostates - folded and unfolded - to explain the experimental data with a transition-state like picture. Unfortunately, a chemical two-state model and the resulting conventional analyses do not estimate the barrier height which is essential in determining whether protein folding can be approximated as a two-state, all-or-none transition. However, the energy landscape theory of protein folding predicts small and even zero folding free energy barriers (downhill folding) because of partial or complete compensation between large enthalpic and entropic terms as folding proceeds. They have been recently validated by the thorough experimental characterization of proteins that fold globally downhill (BBL) and those that fold over marginal free energy barriers. In light of these findings, the question of whether this observation is an exception or merely the tip of the iceberg assumes primary importance. Analyzing the experimental data on previously characterized proteins with statistical mechanical models, it is shown here that the barrier to folding are indeed small and the folding phase space can be quantitatively classified into four regimes - global downhill, marginal barrier, twilight-zone and two-state like. The average effective diffusion coefficient to folding (D_eff) is predicted to be strongly temperature dependent changing from 1/(20-25 microseconds) at 298 K to 1/(2 microseconds) at ~330-340 K. The activation term on the D_eff is found to scale linearly with the protein size while the folding rates themselves scale inversely with the square root of protein length. This work further highlights the importance of baselines and proposes additional thermodynamic and kinetic signatures of downhill folding. A comprehensive experimental and theoretical characterization of PDD, a structural and functional homolog of BBL is also presented. The results indicate that PDD folds downhill at 298 K while crossing a marginal barrier at the apparent T_m. The evolutionary conservation of downhill folding indirectly suggests that this folding behavior has a functional consequence. In short, this work underlines the need for a fundamental shift towards physical models in characterizing protein folding processes. Advisors/Committee Members: Munoz, Victor (advisor).

Subjects/Keywords: Chemistry, Biochemistry; Biophysics, General; Chemistry, Physical; downhill folding; free energy surface; diffusion coefficient; free energy barrier height; differential scanning calorimetry; spectroscopy

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APA (6^th Edition):

Naganathan, A. N. (2007). Barrier Heights and Diffusion Coefficients in Protein Folding. (Thesis). University of Maryland. Retrieved from http://hdl.handle.net/1903/7321

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Chicago Manual of Style (16^th Edition):

Naganathan, Athi Narayanan. “Barrier Heights and Diffusion Coefficients in Protein Folding.” 2007. Thesis, University of Maryland. Accessed April 11, 2021. http://hdl.handle.net/1903/7321.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

MLA Handbook (7^th Edition):

Naganathan, Athi Narayanan. “Barrier Heights and Diffusion Coefficients in Protein Folding.” 2007. Web. 11 Apr 2021.

Vancouver:

Naganathan AN. Barrier Heights and Diffusion Coefficients in Protein Folding. [Internet] [Thesis]. University of Maryland; 2007. [cited 2021 Apr 11]. Available from: http://hdl.handle.net/1903/7321.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Council of Science Editors:

Naganathan AN. Barrier Heights and Diffusion Coefficients in Protein Folding. [Thesis]. University of Maryland; 2007. Available from: http://hdl.handle.net/1903/7321

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

University of Manchester

6. Guerriero, Andrew. Variable pressure NMR analyses to assess compressive motion in PETNR and catalytically germane PETNR:Ligand complexes.

Degree: PhD, 2012, University of Manchester

URL: https://www.research.manchester.ac.uk/portal/en/theses/variable-pressure-nmr-analyses-to-assess-compressive-motion-in-petnr-and-catalytically-germane-petnrligand-complexes(f9d8a882-b05b-47ac-86c4-3987c78e5494).html ; http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.553374

► The involvement of dynamical fluctuations in driving enzymatic processes is widely accepted. With respect to NQM tunnelling enzymes, the role of promoting motions in facilitating… (more)

▼ The involvement of dynamical fluctuations in driving enzymatic processes is widely accepted. With respect to NQM tunnelling enzymes, the role of promoting motions in facilitating hydrogenic transfers is well studied. Few studies have however, specifically attributed, dedicated dynamical fluctuations characterised by their timescales and magnitudes, as a function of a reaction coordinate, to specific groups in a protein system. An effectively full suite of backbone resonance assignments were obtained for PETNR and on relevant ligand complexes. This provided an essential platform on which residue specific, backbone amide fluctuations were assessed. This thesis documents the application of pressure up to 1500 bar, in tandem with high resolution TROSY based NMR analysis, as a means of studying residue specific, conformer exchange perturbations. Residue specific amide compression profiles of the PETNR:FMN free enzyme system, and complexes with progesterone and tetrahydropyridine dinucleotides have been obtained. The binding of progesterone appears to induce conformational tightening of residues within the active site vicinity. The complexation of PETNR:FMN with tetrahydropyridine dinucleotides, appears to stimulate conformational shifts towards intermediate, and in some cases, slow exchange regimes in multiple residues about the active site vicinity. This is evidenced by extensive intensity attenuation of 1H-15N TROSY resonances, on the binding of tetrahydropyridine dinucleotides at 1 bar pressure, and on going from 1 bar to 1500 bar pressure. Multiple regions of sequence, spatially clustering about the active site vicinity within a 10 Å sphere of the FMN binding pocket, display appreciable sensitivity to ligand binding. Differential responses of residues to the application of high pressure between complexes was noted within segments of these regions. A region of sequence, named the β-hairpin flap displays significant differential compression profiles between the PETNR:FMN free enzyme system, and associated progesterone and tetrahydropyridine dinucleotide complexes. A role in mediating ligand engagement is proposed for R130 and R142 in the β-hairpin flap. A central hydrogen bonding network, perhaps constituting a putative proton wire in the active site of the PETNR:FMN:Progesterone complex, has been identified that could enable the shuttling of protons following catalytic protonation of oxidative substrate. The resonance response behaviour of G185 acts as a sensitive reporter on the formation of these interactions, revealed by an interrogation of the differences in chemical shift changes on progesterone binding, and in response to high pressure. The recruitment of high resolution crystallographic data sets readily supported a structural and dynamical interpretation of the observed chemical shift responses to ligand binding at 1 bar pressure, and on the application high pressure. A definitive atomistic identification of fast motion contribution to activation barrier compression was not obtained. Nevertheless, detailed,…

Subjects/Keywords: 572.7; Conformational exchange regimes; Variable pressure NMR; TROSY NMR; High pressure protein NMR; Pressure perturbation; Free energy landscape description of protein systems; Large protein NMR; Atomic fluctuations; Inter-atomic compression; Backbone amide fluctuation; Nuclear tunnelling enzyme system; Activation barrier compression; Pressure induced chemical shift changes

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APA (6^th Edition):

Guerriero, A. (2012). Variable pressure NMR analyses to assess compressive motion in PETNR and catalytically germane PETNR:Ligand complexes. (Doctoral Dissertation). University of Manchester. Retrieved from https://www.research.manchester.ac.uk/portal/en/theses/variable-pressure-nmr-analyses-to-assess-compressive-motion-in-petnr-and-catalytically-germane-petnrligand-complexes(f9d8a882-b05b-47ac-86c4-3987c78e5494).html ; http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.553374

Chicago Manual of Style (16^th Edition):

Guerriero, Andrew. “Variable pressure NMR analyses to assess compressive motion in PETNR and catalytically germane PETNR:Ligand complexes.” 2012. Doctoral Dissertation, University of Manchester. Accessed April 11, 2021. https://www.research.manchester.ac.uk/portal/en/theses/variable-pressure-nmr-analyses-to-assess-compressive-motion-in-petnr-and-catalytically-germane-petnrligand-complexes(f9d8a882-b05b-47ac-86c4-3987c78e5494).html ; http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.553374.

MLA Handbook (7^th Edition):

Guerriero, Andrew. “Variable pressure NMR analyses to assess compressive motion in PETNR and catalytically germane PETNR:Ligand complexes.” 2012. Web. 11 Apr 2021.

Vancouver:

Guerriero A. Variable pressure NMR analyses to assess compressive motion in PETNR and catalytically germane PETNR:Ligand complexes. [Internet] [Doctoral dissertation]. University of Manchester; 2012. [cited 2021 Apr 11]. Available from: https://www.research.manchester.ac.uk/portal/en/theses/variable-pressure-nmr-analyses-to-assess-compressive-motion-in-petnr-and-catalytically-germane-petnrligand-complexes(f9d8a882-b05b-47ac-86c4-3987c78e5494).html ; http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.553374.

Council of Science Editors:

Guerriero A. Variable pressure NMR analyses to assess compressive motion in PETNR and catalytically germane PETNR:Ligand complexes. [Doctoral Dissertation]. University of Manchester; 2012. Available from: https://www.research.manchester.ac.uk/portal/en/theses/variable-pressure-nmr-analyses-to-assess-compressive-motion-in-petnr-and-catalytically-germane-petnrligand-complexes(f9d8a882-b05b-47ac-86c4-3987c78e5494).html ; http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.553374

Osaka University

7. Lee, Yong-hee; 李, 容喜. Kinetics of martensitic transformation in a Ni_<45>Co_5Mn_<36.5>In_<13.5> and magnetic transition in an FeRh : Ni_<45>Co_5Mn_<36.5>In_<13.5> におけるマルテンサイト変態ならびに FeRh における磁気転移のカイネティクス; Ni_<45>Co_5Mn_<36.5>In_<13.5>　ニ　オケル　マルテンサイト　ヘンタイ　ナラビニ　FeRh　ニ　オケル　ジキ　テンイ　ノ　カイネティクス.

Degree: 博士（工学）, 2013, Osaka University

URL: http://hdl.handle.net/11094/27570

博士（工学）

2013-03-25

大阪大学

14401甲第16415号

26201

Subjects/Keywords: Kinetics; Isothermal martensitic transformation; TTT diagram; Gibbs free energy; First order magnetic transition; Potential barrier

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APA (6^th Edition):

Lee, Yong-hee; 李, �. (2013). Kinetics of martensitic transformation in a Ni_<45>Co_5Mn_<36.5>In_<13.5> and magnetic transition in an FeRh : Ni_<45>Co_5Mn_<36.5>In_<13.5> におけるマルテンサイト変態ならびに FeRh における磁気転移のカイネティクス; Ni_<45>Co_5Mn_<36.5>In_<13.5>　ニ　オケル　マルテンサイト　ヘンタイ　ナラビニ　FeRh　ニ　オケル　ジキ　テンイ　ノ　カイネティクス. (Thesis). Osaka University. Retrieved from http://hdl.handle.net/11094/27570

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Chicago Manual of Style (16^th Edition):

Lee, Yong-hee; 李, 容喜. “Kinetics of martensitic transformation in a Ni_<45>Co_5Mn_<36.5>In_<13.5> and magnetic transition in an FeRh : Ni_<45>Co_5Mn_<36.5>In_<13.5> におけるマルテンサイト変態ならびに FeRh における磁気転移のカイネティクス; Ni_<45>Co_5Mn_<36.5>In_<13.5>　ニ　オケル　マルテンサイト　ヘンタイ　ナラビニ　FeRh　ニ　オケル　ジキ　テンイ　ノ　カイネティクス.” 2013. Thesis, Osaka University. Accessed April 11, 2021. http://hdl.handle.net/11094/27570.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

MLA Handbook (7^th Edition):

Lee, Yong-hee; 李, 容喜. “Kinetics of martensitic transformation in a Ni_<45>Co_5Mn_<36.5>In_<13.5> and magnetic transition in an FeRh : Ni_<45>Co_5Mn_<36.5>In_<13.5> におけるマルテンサイト変態ならびに FeRh における磁気転移のカイネティクス; Ni_<45>Co_5Mn_<36.5>In_<13.5>　ニ　オケル　マルテンサイト　ヘンタイ　ナラビニ　FeRh　ニ　オケル　ジキ　テンイ　ノ　カイネティクス.” 2013. Web. 11 Apr 2021.

Vancouver:

Lee, Yong-hee; 李 �. Kinetics of martensitic transformation in a Ni_<45>Co_5Mn_<36.5>In_<13.5> and magnetic transition in an FeRh : Ni_<45>Co_5Mn_<36.5>In_<13.5> におけるマルテンサイト変態ならびに FeRh における磁気転移のカイネティクス; Ni_<45>Co_5Mn_<36.5>In_<13.5>　ニ　オケル　マルテンサイト　ヘンタイ　ナラビニ　FeRh　ニ　オケル　ジキ　テンイ　ノ　カイネティクス. [Internet] [Thesis]. Osaka University; 2013. [cited 2021 Apr 11]. Available from: http://hdl.handle.net/11094/27570.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Council of Science Editors:

Lee, Yong-hee; 李 �. Kinetics of martensitic transformation in a Ni_<45>Co_5Mn_<36.5>In_<13.5> and magnetic transition in an FeRh : Ni_<45>Co_5Mn_<36.5>In_<13.5> におけるマルテンサイト変態ならびに FeRh における磁気転移のカイネティクス; Ni_<45>Co_5Mn_<36.5>In_<13.5>　ニ　オケル　マルテンサイト　ヘンタイ　ナラビニ　FeRh　ニ　オケル　ジキ　テンイ　ノ　カイネティクス. [Thesis]. Osaka University; 2013. Available from: http://hdl.handle.net/11094/27570

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Brno University of Technology

8. Dlabaja, Adam. Sídlo firmy Dlabaja a.s.: Corporate headquarters Dlabaja a.s.

Degree: 2019, Brno University of Technology

URL: http://hdl.handle.net/11012/175324

► The project documentation, processed in the framework of the diploma thesis, solves the new building of the administrative building of the building company in the… (more)

Subjects/Keywords: Administrativní budova; administrativa; kancelářská budova; kanceláře; moderní; nízkoenergetický objekt; pasivní výstavba; vegetační střecha; vegetační fasáda; zelená fasáda; zelená střecha; plochá střecha; bez zateplení; bezbariérový provoz; přírodě odpovědný objekt; vodní hospodářství; Administrative building; administration; office building; modern; low-energy building; passive construction; vegetation roof; vegetation facade; green façade; green roof; flat roof; no insulation; barrier-free operation; nature responsible building; water management

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APA · Chicago · MLA · Vancouver · CSE | Export to Zotero / EndNote / Reference Manager

APA (6^th Edition):

Dlabaja, A. (2019). Sídlo firmy Dlabaja a.s.: Corporate headquarters Dlabaja a.s. (Thesis). Brno University of Technology. Retrieved from http://hdl.handle.net/11012/175324

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Chicago Manual of Style (16^th Edition):

Dlabaja, Adam. “Sídlo firmy Dlabaja a.s.: Corporate headquarters Dlabaja a.s.” 2019. Thesis, Brno University of Technology. Accessed April 11, 2021. http://hdl.handle.net/11012/175324.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

MLA Handbook (7^th Edition):

Dlabaja, Adam. “Sídlo firmy Dlabaja a.s.: Corporate headquarters Dlabaja a.s.” 2019. Web. 11 Apr 2021.

Vancouver:

Dlabaja A. Sídlo firmy Dlabaja a.s.: Corporate headquarters Dlabaja a.s. [Internet] [Thesis]. Brno University of Technology; 2019. [cited 2021 Apr 11]. Available from: http://hdl.handle.net/11012/175324.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Council of Science Editors:

Dlabaja A. Sídlo firmy Dlabaja a.s.: Corporate headquarters Dlabaja a.s. [Thesis]. Brno University of Technology; 2019. Available from: http://hdl.handle.net/11012/175324

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Brno University of Technology

9. Dlabaja, Adam. Sídlo firmy Dlabaja a.s.: Corporate headquarters Dlabaja a.s.

Degree: 2019, Brno University of Technology

URL: http://hdl.handle.net/11012/137564

► The project documentation, processed in the framework of the diploma thesis, solves the new building of the administrative building of the building company in the… (more)

Subjects/Keywords: Administrativní budova; administrativa; kancelářská budova; kanceláře; moderní; nízkoenergetický objekt; pasivní výstavba; vegetační střecha; vegetační fasáda; zelená fasáda; zelená střecha; plochá střecha; bez zateplení; bezbariérový provoz; přírodě odpovědný objekt; vodní hospodářství; Administrative building; administration; office building; modern; low-energy building; passive construction; vegetation roof; vegetation facade; green façade; green roof; flat roof; no insulation; barrier-free operation; nature responsible building; water management

Record Details Similar Records Cite « Share

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APA · Chicago · MLA · Vancouver · CSE | Export to Zotero / EndNote / Reference Manager

APA (6^th Edition):

Dlabaja, A. (2019). Sídlo firmy Dlabaja a.s.: Corporate headquarters Dlabaja a.s. (Thesis). Brno University of Technology. Retrieved from http://hdl.handle.net/11012/137564

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Chicago Manual of Style (16^th Edition):

Dlabaja, Adam. “Sídlo firmy Dlabaja a.s.: Corporate headquarters Dlabaja a.s.” 2019. Thesis, Brno University of Technology. Accessed April 11, 2021. http://hdl.handle.net/11012/137564.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

MLA Handbook (7^th Edition):

Dlabaja, Adam. “Sídlo firmy Dlabaja a.s.: Corporate headquarters Dlabaja a.s.” 2019. Web. 11 Apr 2021.

Vancouver:

Dlabaja A. Sídlo firmy Dlabaja a.s.: Corporate headquarters Dlabaja a.s. [Internet] [Thesis]. Brno University of Technology; 2019. [cited 2021 Apr 11]. Available from: http://hdl.handle.net/11012/137564.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Council of Science Editors:

Dlabaja A. Sídlo firmy Dlabaja a.s.: Corporate headquarters Dlabaja a.s. [Thesis]. Brno University of Technology; 2019. Available from: http://hdl.handle.net/11012/137564

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Brno University of Technology

10. Pilík, Václav. Bydlení pro seniory: Housing for Seniors.

Degree: 2020, Brno University of Technology

URL: http://hdl.handle.net/11012/184553

► The diploma thesis is elaboration of project documentation of the object Housing for seniors in Brno - Dolní Heršpice. The site is located un the… (more)

Subjects/Keywords: Diplomová práce; bydlení pro seniory; bezbariérový objekt; malometrážní bydlení; budova s téměř nulovou spotřebou energie; kontaktní zateplovací systém; centrální nucená výměna vzduchu; tepelné čerpadlo země-voda; podlahové vytápění; specializace betonové konstrukce; železobeton; bílá vana; lokálně podepřená stropní deska; spojitá stropní deska; Diploma thesis; housing for seniors; barrier-free building; modest living; almost zero energy building; contact thermal insulation system; central forced air exchange; ground-water heat pump; floor heating; specialization of concrete construction; reinforced concrete; white tank; locally supported reinforced concrete ceiling slabs; continuous reinforced concrete slab

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APA · Chicago · MLA · Vancouver · CSE | Export to Zotero / EndNote / Reference Manager

APA (6^th Edition):

Pilík, V. (2020). Bydlení pro seniory: Housing for Seniors. (Thesis). Brno University of Technology. Retrieved from http://hdl.handle.net/11012/184553

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Chicago Manual of Style (16^th Edition):

Pilík, Václav. “Bydlení pro seniory: Housing for Seniors.” 2020. Thesis, Brno University of Technology. Accessed April 11, 2021. http://hdl.handle.net/11012/184553.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

MLA Handbook (7^th Edition):

Pilík, Václav. “Bydlení pro seniory: Housing for Seniors.” 2020. Web. 11 Apr 2021.

Vancouver:

Pilík V. Bydlení pro seniory: Housing for Seniors. [Internet] [Thesis]. Brno University of Technology; 2020. [cited 2021 Apr 11]. Available from: http://hdl.handle.net/11012/184553.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Council of Science Editors:

Pilík V. Bydlení pro seniory: Housing for Seniors. [Thesis]. Brno University of Technology; 2020. Available from: http://hdl.handle.net/11012/184553

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

11. Guerriero, Andrew. Variable pressure NMR analyses to assess compressive motion in PETNR and catalytically germane PETNR:Ligand complexes.

Degree: 2012, University of Manchester

URL: http://www.manchester.ac.uk/escholar/uk-ac-man-scw:156775

► The involvement of dynamical fluctuations in driving enzymatic processes is widely accepted. With respect to NQM tunnelling enzymes, the role of promoting motions in facilitating… (more)

▼ The involvement of dynamical fluctuations in driving enzymatic processes is widely accepted. With respect to NQM tunnelling enzymes, the role of promoting motions in facilitating hydrogenic transfers is well studied. Few studies have however, specifically attributed, dedicated dynamical fluctuations characterised by their timescales and magnitudes, as a function of a reaction coordinate, to specific groups in a protein system. An effectively full suite of backbone resonance assignments were obtained for PETNR and on relevant ligand complexes. This provided an essential platform on which residue specific, backbone amide fluctuations were assessed. This thesis documents the application of pressure up to 1500 bar, in tandem with high resolution TROSY based NMR analysis, as a means of studying residue specific, conformer exchange perturbations. Residue specific amide compression profiles of the PETNR:FMN free enzyme system, and complexes with progesterone and tetrahydropyridine dinucleotides have been obtained. The binding of progesterone appears to induce conformational tightening of residues within the active site vicinity. The complexation of PETNR:FMN with tetrahydropyridine dinucleotides, appears to stimulate conformational shifts towards intermediate, and in some cases, slow exchange regimes in multiple residues about the active site vicinity. This is evidenced by extensive intensity attenuation of 1H-15N TROSY resonances, on the binding of tetrahydropyridine dinucleotides at 1 bar pressure, and on going from 1 bar to 1500 bar pressure.Multiple regions of sequence, spatially clustering about the active site vicinity within a 10 Å sphere of the FMN binding pocket, display appreciable sensitivity to ligand binding. Differential responses of residues to the application of high pressure between complexes was noted within segments of these regions. A region of sequence, named the β-hairpin flap displays significant differential compression profiles between the PETNR:FMN free enzyme system, and associated progesterone and tetrahydropyridine dinucleotide complexes. A role in mediating ligand engagement is proposed for R130 and R142 in the β-hairpin flap.A central hydrogen bonding network, perhaps constituting a putative proton wire in the active site of the PETNR:FMN:Progesterone complex, has been identified that could enable the shuttling of protons following catalytic protonation of oxidative substrate. The resonance response behaviour of G185 acts as a sensitive reporter on the formation of these interactions, revealed by an interrogation of the differences in chemical shift changes on progesterone binding, and in response to high pressure. The recruitment of high resolution crystallographic data sets readily supported a structural and dynamical interpretation of the observed chemical shift responses to ligand binding at 1 bar pressure, and on the application high pressure.A definitive atomistic identification of fast motion contribution to activation barrier compression was not obtained. Nevertheless, detailed,… Advisors/Committee Members: Scrutton, Nigel.

Subjects/Keywords: Conformational exchange regimes; Variable pressure NMR; TROSY NMR; High pressure protein NMR; Pressure perturbation; Free energy landscape description of protein systems; Large protein NMR; Atomic fluctuations; Inter-atomic compression; Backbone amide fluctuation; Nuclear tunnelling enzyme system; Activation barrier compression; Pressure induced chemical shift changes

…thermodynamic distributions. The magnitude of the free energy barrier between substates dictates the… …protein systems (402) 8.3.1 Alteration of the free energy landscape via high pressure… …spectroscopy ZF - Zero filling ∆∆G° - The difference in free energy change (referred to in this… …conformer’ can be ascribed an associated free energy. A notional framework for describing such… …systems is the free energy landscape (25, 26). A free energy landscape relates free…

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APA · Chicago · MLA · Vancouver · CSE | Export to Zotero / EndNote / Reference Manager

APA (6^th Edition):

Guerriero, A. (2012). Variable pressure NMR analyses to assess compressive motion in PETNR and catalytically germane PETNR:Ligand complexes. (Doctoral Dissertation). University of Manchester. Retrieved from http://www.manchester.ac.uk/escholar/uk-ac-man-scw:156775

Chicago Manual of Style (16^th Edition):

Guerriero, Andrew. “Variable pressure NMR analyses to assess compressive motion in PETNR and catalytically germane PETNR:Ligand complexes.” 2012. Doctoral Dissertation, University of Manchester. Accessed April 11, 2021. http://www.manchester.ac.uk/escholar/uk-ac-man-scw:156775.

MLA Handbook (7^th Edition):

Guerriero, Andrew. “Variable pressure NMR analyses to assess compressive motion in PETNR and catalytically germane PETNR:Ligand complexes.” 2012. Web. 11 Apr 2021.

Vancouver:

Guerriero A. Variable pressure NMR analyses to assess compressive motion in PETNR and catalytically germane PETNR:Ligand complexes. [Internet] [Doctoral dissertation]. University of Manchester; 2012. [cited 2021 Apr 11]. Available from: http://www.manchester.ac.uk/escholar/uk-ac-man-scw:156775.

Council of Science Editors:

Guerriero A. Variable pressure NMR analyses to assess compressive motion in PETNR and catalytically germane PETNR:Ligand complexes. [Doctoral Dissertation]. University of Manchester; 2012. Available from: http://www.manchester.ac.uk/escholar/uk-ac-man-scw:156775

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Open Access Theses and Dissertations