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You searched for subject:(Organopalladium chemistry). One record found.

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1. Nikolaev, Andrei. Palladium (II) Mediated Transformation: Exploring Synthetic Methodology for the Synthesis of Cyclopentenones from Tertiary-Cyclobutanois.

Degree: MSc -MS, Chemistry, 2015, York University

A new method for the synthesis of ring-fused cyclopentenone is described. The method utilizes the built-in strain of tertiary cyclobutanol to drive the palladium(II)-catalyzed rearrangement to the corresponding ring-fused cyclopentanone followed by Saegusa-Ito reaction to furnish final cyclopentenone product. Extensive efforts to transform this reaction into a catalytic process by screening various palladium(II) sources, ligands, oxidants, bases, solvents and reaction temperatures failed. Interesting and unexpected results were however obtained while exploring copper(II) chloride and copper(II) bromide as potential oxidants. Advisors/Committee Members: Orellana Garcia, Josue Arturo (advisor).

Subjects/Keywords: Chemistry; Chemistry; Synthetic chemistry; Organometallics; Organopalladium chemistry; Cyclopentenone; Strain; Synthetic methodology.

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APA · Chicago · MLA · Vancouver · CSE | Export to Zotero / EndNote / Reference Manager

APA (6th Edition):

Nikolaev, A. (2015). Palladium (II) Mediated Transformation: Exploring Synthetic Methodology for the Synthesis of Cyclopentenones from Tertiary-Cyclobutanois. (Masters Thesis). York University. Retrieved from http://hdl.handle.net/10315/30036

Chicago Manual of Style (16th Edition):

Nikolaev, Andrei. “Palladium (II) Mediated Transformation: Exploring Synthetic Methodology for the Synthesis of Cyclopentenones from Tertiary-Cyclobutanois.” 2015. Masters Thesis, York University. Accessed September 20, 2020. http://hdl.handle.net/10315/30036.

MLA Handbook (7th Edition):

Nikolaev, Andrei. “Palladium (II) Mediated Transformation: Exploring Synthetic Methodology for the Synthesis of Cyclopentenones from Tertiary-Cyclobutanois.” 2015. Web. 20 Sep 2020.

Vancouver:

Nikolaev A. Palladium (II) Mediated Transformation: Exploring Synthetic Methodology for the Synthesis of Cyclopentenones from Tertiary-Cyclobutanois. [Internet] [Masters thesis]. York University; 2015. [cited 2020 Sep 20]. Available from: http://hdl.handle.net/10315/30036.

Council of Science Editors:

Nikolaev A. Palladium (II) Mediated Transformation: Exploring Synthetic Methodology for the Synthesis of Cyclopentenones from Tertiary-Cyclobutanois. [Masters Thesis]. York University; 2015. Available from: http://hdl.handle.net/10315/30036

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