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1.
Miletić Aleksandar.
Razvoj nanoslojnih i nanokompozitnih metal-nitridnih prevlaka.
Degree: 2015, University of Novi Sad
URL: https://www.cris.uns.ac.rs/DownloadFileServlet/Disertacija144767409154785.pdf?controlNumber=(BISIS)95438&fileName=144767409154785.pdf&id=4626&source=OATD&language=en
;
https://www.cris.uns.ac.rs/record.jsf?recordId=95438&source=OATD&language=en
► Razvijene su TiAlN/TiSiN i CrAlN/TiSiN nanoslojne prevlake u kojima je napravljen spoj nanoslojnog i nanokompozitnog dizajna. Akcenat je stavljen na proizvodnju prevlaka visoke tvrdoće…
(more)
▼ Razvijene su TiAlN/TiSiN i CrAlN/TiSiN nanoslojne prevlake u kojima je napravljen spoj nanoslojnog i nanokompozitnog dizajna. Akcenat je stavljen na proizvodnju prevlaka visoke tvrdoće i visoke otpornosti na lom. Proučavane su i jednoslojne TiAlN, nanokompozitne TiSiN i višeslojne TiAlN/TiSiN prevlake kako bi se utvrdilo kako dizajn utiče na osobine prevlaka. Sve prevlake pripremane su sa jednim, dva i tri stepena rotacije. Pokazano je da dizajn i vid rotacije značajno utiču na mikrostrukturu i teksturu prevlaka, a time na njihove mehaničke osobine, otpornost na lom, adheziju između prevlake i podloge, topografiju površine i tribološko ponašanje. Nanoslojne i nanokompozitne prevlake odlikuju se kompaktnom nanokristalnom mikrostrukturom, dok jednoslojne TiAlN prevlake imaju stubastu strukturu sa kristalnim zrnima veće veličine. Pri prelasku sa jednog na više stepeni rotacije mikrostruktura prevlaka postaje kompaktnija sa kristalnim zrnima manje veličine i manjom poroznošću. U skladu sa tim, najmanju hrapavost, najveću tvrdoću, najveću otpornost na lom i najveću otpornost na habanje imaju nanoslojne i nanokompozitne prevlake pripremane sa dva i tri stepena rotacije.
With the aim to develop hard coatings characterized by both, high hardness and high resistance to cracking, synergy between nanolayered and nanocomposite design was made and nanolayered TiAlN/TiSiN and CrAlN/TiSiN coatings were produced. Monolayer TiAlN, nanocomposite TiSiN and multilayer TiAlN/TiSiN were also studied in order to find the relation between the coating design and their properties. All coatings were deposited with 1-fold, 2-fold and 3-fold rotation. It is shown that coating design and type of rotation have great influence on coating microstructure and texture, and in this way on their mechanical properties, resistance to cracking, adhesion between coating and substrate, surface topography and tribological behavior. Nanolayered and nanocomposite coatings are characterized by compact nanocrystalline microstructure, while monolayer TiAlN coatings have columnar structure with larger crystalline grains. By increasing the number of rotational degrees from 1-fold to 3-fold size of crystalline grains decreases and microstructure becomes more dense. Therefore, nanolayered and nanocomposite coatings deposited with 2-fold and 3-fold rotation are characterized by the highest hardness, highest resistance to cracking, highest wear resistance and the smoothest surface topography.
Advisors/Committee Members: Škorić Branko, Kakaš Damir, Šiđanin Leposava, Panjan Peter, Radmilović Velimir.
Subjects/Keywords: Nanoslojne prevlake, nanokompozitne prevlake, mikrostruktura, mehaničke osobine, otpornost na lom,adhezija, tribološko ponašanje; Nanolayered coatings, nanocomposite coatings, microstructure, mechanical properties, crack resistance, adhesion, tribological behavior
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APA (6th Edition):
Aleksandar, M. (2015). Razvoj nanoslojnih i nanokompozitnih metal-nitridnih prevlaka. (Thesis). University of Novi Sad. Retrieved from https://www.cris.uns.ac.rs/DownloadFileServlet/Disertacija144767409154785.pdf?controlNumber=(BISIS)95438&fileName=144767409154785.pdf&id=4626&source=OATD&language=en ; https://www.cris.uns.ac.rs/record.jsf?recordId=95438&source=OATD&language=en
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Aleksandar, Miletić. “Razvoj nanoslojnih i nanokompozitnih metal-nitridnih prevlaka.” 2015. Thesis, University of Novi Sad. Accessed February 27, 2021.
https://www.cris.uns.ac.rs/DownloadFileServlet/Disertacija144767409154785.pdf?controlNumber=(BISIS)95438&fileName=144767409154785.pdf&id=4626&source=OATD&language=en ; https://www.cris.uns.ac.rs/record.jsf?recordId=95438&source=OATD&language=en.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Aleksandar, Miletić. “Razvoj nanoslojnih i nanokompozitnih metal-nitridnih prevlaka.” 2015. Web. 27 Feb 2021.
Vancouver:
Aleksandar M. Razvoj nanoslojnih i nanokompozitnih metal-nitridnih prevlaka. [Internet] [Thesis]. University of Novi Sad; 2015. [cited 2021 Feb 27].
Available from: https://www.cris.uns.ac.rs/DownloadFileServlet/Disertacija144767409154785.pdf?controlNumber=(BISIS)95438&fileName=144767409154785.pdf&id=4626&source=OATD&language=en ; https://www.cris.uns.ac.rs/record.jsf?recordId=95438&source=OATD&language=en.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Aleksandar M. Razvoj nanoslojnih i nanokompozitnih metal-nitridnih prevlaka. [Thesis]. University of Novi Sad; 2015. Available from: https://www.cris.uns.ac.rs/DownloadFileServlet/Disertacija144767409154785.pdf?controlNumber=(BISIS)95438&fileName=144767409154785.pdf&id=4626&source=OATD&language=en ; https://www.cris.uns.ac.rs/record.jsf?recordId=95438&source=OATD&language=en
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Uniwersytet im. Adama Mickiewicza w Poznaniu
2.
Pshyk, Oleksandr.
Cechy strukturalne i właściwości trybo-mechaniczne powłok nanokompozytowych TiAlBSiN
.
Degree: 2017, Uniwersytet im. Adama Mickiewicza w Poznaniu
URL: http://hdl.handle.net/10593/21355
► W pracy doktorskiej przedstawiono wyniki badań dotyczące struktury i właściwości fizycznych pokryć opartych na TiAlSiBN o strukturze amorficznej i nanokompozytowej mikrostrukturze gradientowej. Gradientowe pokrycia TiAlBSiN…
(more)
▼ W pracy doktorskiej przedstawiono wyniki badań dotyczące struktury i właściwości fizycznych pokryć opartych na TiAlSiBN o strukturze amorficznej i nanokompozytowej mikrostrukturze gradientowej. Gradientowe pokrycia TiAlBSiN były wytwarzane poprzez użycie reaktywnego/niereaktywnego magnetronowego rozpylania z targetu kompozytowego AlN-TiB2-TiSi2. Badania wykazały, iż wytworzona gradientowa powłoka złożona byłą z dwóch warstw o różnej mikrostrukturze i składzie pierwiastkowym. Obie warstwy składały się głównie z krystalicznych faz fcc-(Ti,Al)(N,O,B) i hcp-(Al,Ti)(N,O) otoczonych amorficzną fazą. Górna warstwa o grubości około 220 nm złożona była z drobnych krystalitów o wymiarach w przedziale 15-40 nm. Dolna warstwa została uformowana przez niejednorodnie rozłożone nanokryształy o wymiarach około 5-40 nm. Badania mechaniczne i trybologiczne wskazały na dobre właściwości elastyczne oraz względnie wysoką odporność na ścieranie wytworzonych materiałów.
Amorficzne pokrycia TiAlBSiN były wytwarzane z wykorzystaniem metody niereaktywnego rozpylania magnetronowego z kompozytowego targetu AlN–TiB2–TiSi2. Badana amorficzna powłoka TiAlBSiN bogata w Al wykazała lepszą stabilność termiczną w środowisku utleniającym niż powłoki oparte na TiAlBSiN opisane wcześnie w literaturze. Amorficzne pokrycia TiAlBSiN wykazują również obiecujące właściwości trybologiczne w mikroskali.
Advisors/Committee Members: Jurga, Stefan. Promotor (advisor).
Subjects/Keywords: nanokompozyt;
nanocomposite;
właściwości mechaniczne;
mechanical properties;
powłoki zabezpieczające;
protective coatings;
mikrostruktura;
microstructure;
amorficzne pokrycie;
amorphous coating
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Pshyk, O. (2017). Cechy strukturalne i właściwości trybo-mechaniczne powłok nanokompozytowych TiAlBSiN
. (Doctoral Dissertation). Uniwersytet im. Adama Mickiewicza w Poznaniu. Retrieved from http://hdl.handle.net/10593/21355
Chicago Manual of Style (16th Edition):
Pshyk, Oleksandr. “Cechy strukturalne i właściwości trybo-mechaniczne powłok nanokompozytowych TiAlBSiN
.” 2017. Doctoral Dissertation, Uniwersytet im. Adama Mickiewicza w Poznaniu. Accessed February 27, 2021.
http://hdl.handle.net/10593/21355.
MLA Handbook (7th Edition):
Pshyk, Oleksandr. “Cechy strukturalne i właściwości trybo-mechaniczne powłok nanokompozytowych TiAlBSiN
.” 2017. Web. 27 Feb 2021.
Vancouver:
Pshyk O. Cechy strukturalne i właściwości trybo-mechaniczne powłok nanokompozytowych TiAlBSiN
. [Internet] [Doctoral dissertation]. Uniwersytet im. Adama Mickiewicza w Poznaniu; 2017. [cited 2021 Feb 27].
Available from: http://hdl.handle.net/10593/21355.
Council of Science Editors:
Pshyk O. Cechy strukturalne i właściwości trybo-mechaniczne powłok nanokompozytowych TiAlBSiN
. [Doctoral Dissertation]. Uniwersytet im. Adama Mickiewicza w Poznaniu; 2017. Available from: http://hdl.handle.net/10593/21355

Anna University
3.
Radhika R.
Tribological Properties And Wear Mechanism Of Hard
Coatings;.
Degree: Crystal Growth, 2013, Anna University
URL: http://shodhganga.inflibnet.ac.in/handle/10603/27780
► In the modern technology tribologically suitable components and newlinedevices are important to increase the energy efficiency It is possible when newlineone can reduce the friction…
(more)
▼ In the modern technology tribologically suitable
components and newlinedevices are important to increase the energy
efficiency It is possible when newlineone can reduce the friction
coefficient and wear of sliding components The newlineeconomic
effectiveness can be achieved by better tribological system and
newlinetherefore research in tribology is aimed at minimizing the
energy losses newlineresulting from friction and wear In this view
hard coatings deposited by newlinephysical vapor deposition PVD are
adequate solutions for increasing the newlinework efficiency
lifetime of tools and components newlineThe present thesis deals
with hard tribological materials T Al and newlinecoatings such as
TiAlN C N N N superlattice diamond like carbon DLC newlineand
nanocrystalline diamond nanowire DNW films Various
newlinecharacterization techniques were used to study morphology
microstructure newlineand chemical state of the materials The
thesis describes tribological newlineproperties of above mentioned
hard coatings sliding against 100C 6 steel newlineAl O and SiC
balls It also describes friction and wear based on classified
newlinemechanisms and outlines material properties that influence
the performance newlineof sliding surfaces Traditionally wear is
associated with friction and wear newlinemechanisms are classified
as adhesion abrasion erosion fatigue and newlineoxidational
newlineMechanical and tribological properties of T Al alloy T AlN
newlineC N carbon based coatings of DLC and nanocrystalline DNW
were newlinereviewed The importance of such hard coatings and
critical application in newlinemachine and industries are
highlighted Moreover tribological properties and newlineevaluation
of wear mechanism is introduced in the respect of microstructure
newlineand chemical behavior of the sliding interfaces Various wear
mechanism newlinewith different combination of sliding surfaces
such as hard coating soft ball newlineand soft ball hard coating is
reviewed in order to understand the wear newlinemechanism The
fundamentals of some of the characterization techniques newlineused
to study the mechanical tribological morphological structural and
newlinechemical properties of the coating and wear track is
introduced newline
Advisors/Committee Members: Arivuoli D.
Subjects/Keywords: Hard Coatings; morphology; Tribological Properties; Wear Mechanism
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
R, R. (2013). Tribological Properties And Wear Mechanism Of Hard
Coatings;. (Thesis). Anna University. Retrieved from http://shodhganga.inflibnet.ac.in/handle/10603/27780
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
R, Radhika. “Tribological Properties And Wear Mechanism Of Hard
Coatings;.” 2013. Thesis, Anna University. Accessed February 27, 2021.
http://shodhganga.inflibnet.ac.in/handle/10603/27780.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
R, Radhika. “Tribological Properties And Wear Mechanism Of Hard
Coatings;.” 2013. Web. 27 Feb 2021.
Vancouver:
R R. Tribological Properties And Wear Mechanism Of Hard
Coatings;. [Internet] [Thesis]. Anna University; 2013. [cited 2021 Feb 27].
Available from: http://shodhganga.inflibnet.ac.in/handle/10603/27780.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
R R. Tribological Properties And Wear Mechanism Of Hard
Coatings;. [Thesis]. Anna University; 2013. Available from: http://shodhganga.inflibnet.ac.in/handle/10603/27780
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

University of Saskatchewan
4.
Mohammad Taheri, Masoud 1986-.
Synthesis and Characterization of Hard Cr2O3 and Superhard Cr-Zr-O PVD Coatings.
Degree: 2019, University of Saskatchewan
URL: http://hdl.handle.net/10388/12374
► Reactive radio-frequency magnetron sputter technique (RF-MS) was used to deposit Cr-O and Cr-Zr-O coatings on silicon, SS316L, WC-Co, and HSS M42 substrates. The effects of…
(more)
▼ Reactive radio-frequency magnetron sputter technique (RF-MS) was used to deposit Cr-O and Cr-Zr-O
coatings on silicon, SS316L, WC-Co, and HSS M42 substrates. The effects of deposition temperature, chemical composition, and subsequent heat treatment on microstructural, thermal stability, and
mechanical properties of both Cr-O and Cr-Zr-O
coatings were investigated. The deposited
coatings were characterized using scanning electron microscopy, Xray
diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, Energy dispersive spectroscopy, nanoindentation, Rockwell “C” indentation, optical profilometer, reciprocating wear testing, electrochemical testing, and inductively coupled plasma analysis.
The results showed that appropriate deposition conditions were required in order to obtain hard Cr2O3 coating. A Cr2O3/Cr duplex interlayer was found to be suitable for nucleation of diamond
coatings on WC-Co substrates as it restricted graphite formation before diamond nucleation,
thus, continuous diamond
coatings with good
adhesion were successfully deposited on Cr2O3/Cr interlayered WC-Co substrates. Furthermore, hard Cr2O3
coatings were shown to be a potential candidate to improve the
mechanical properties and to reduce the toxic ion release rate of
orthopedic implants. The coated SS316L substrates illustrated better wear and corrosion
resistance and lower friction coefficient compared to bare 316L substrates under a reciprocating sliding condition in saline solution. Furthermore, many fewer Cr ions were released from coated SS316L substrates after immersion tests.
Adding zirconium to Cr2O3 coating shifted the onset of crystallization for the Cr2O3 coating to higher temperatures and superhard Cr-Zr-O
coatings with a hardness value over 40 GPa could be obtained at a zirconium concentration of around 9.5 at. % and a substrate temperature of 300°C.
The obtained superhardness could be attributed to the formation of a
nanocomposite structure.
Advisors/Committee Members: Cree, Duncan, N. Oguocha, kechukwuka, Zhang, W.J. (Chris), P. Bradley, Michael.
Subjects/Keywords: PVD; Coatings; Cr2O3; Cr-Zr-O; Mechanical Properties; Microstructure
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Mohammad Taheri, M. 1. (2019). Synthesis and Characterization of Hard Cr2O3 and Superhard Cr-Zr-O PVD Coatings. (Thesis). University of Saskatchewan. Retrieved from http://hdl.handle.net/10388/12374
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Mohammad Taheri, Masoud 1986-. “Synthesis and Characterization of Hard Cr2O3 and Superhard Cr-Zr-O PVD Coatings.” 2019. Thesis, University of Saskatchewan. Accessed February 27, 2021.
http://hdl.handle.net/10388/12374.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Mohammad Taheri, Masoud 1986-. “Synthesis and Characterization of Hard Cr2O3 and Superhard Cr-Zr-O PVD Coatings.” 2019. Web. 27 Feb 2021.
Vancouver:
Mohammad Taheri M1. Synthesis and Characterization of Hard Cr2O3 and Superhard Cr-Zr-O PVD Coatings. [Internet] [Thesis]. University of Saskatchewan; 2019. [cited 2021 Feb 27].
Available from: http://hdl.handle.net/10388/12374.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Mohammad Taheri M1. Synthesis and Characterization of Hard Cr2O3 and Superhard Cr-Zr-O PVD Coatings. [Thesis]. University of Saskatchewan; 2019. Available from: http://hdl.handle.net/10388/12374
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Indian Institute of Science
5.
Yadav, Arti.
Nano Porous Alumina Based Composite Coating for Tribological Applications.
Degree: PhD, Faculty of Engineering, 2018, Indian Institute of Science
URL: http://etd.iisc.ac.in/handle/2005/3055
► Anodisation is a surface treatment process, commonly used to form a protective oxide coating on the surface of metals like aluminium. Anodised coatings, being grown…
(more)
▼ Anodisation is a surface treatment process, commonly used to form a protective oxide coating on the surface of metals like aluminium. Anodised
coatings, being grown out of the base metal have excellent interface strength but are porous and brittle. Porosity of the coating reduces the hardness and the brittle nature of the oxide induces cracking. In practice, the pores are typically filled with organic dye and sealed. Under certain controlled electrochemical conditions, anodisation results in a highly ordered hexagonal porous structure in pure aluminium. In this work, we explore the possibility of using this ordered porous alumina to form a novel metal
nanocomposite as a
tribological coating. By optimizing the nonporous structure and tuning the electrodeposition process, we uniformly filled the ordered pores with copper. We have measured the hardness of the resulting ordered and aligned
nanocomposite. We explore the possibility of using this composite coating for
tribological applications by carrying out some preliminary reciprocating wear test.
Ordered porous alumina layer is formed by a two-step anodisation process. By optimizing the anodisation conditions, we control the thickness of the coating and the pore size. The interface of the porous structure and aluminium substrate is defined by a non-conducting dense barrier oxide layer. However, to deposit metal into the pores, a conducting path should be established through the barrier layer. One possibility is to etch out the bottom of the pores at the cost of the interface strength and losing out on the main advantage of anodised
coatings. To be able to fill metal without this sacrifice, we utilised the dendritic structure in the barrier layer formed by a step-wise reduction of voltage towards the end of anodisation process. Optimisation of this dendritic structure led to uniform deposition of metal into pores, achieved by pulsed electrodeposition. In pulse lectrodeposition, a positive pulse is applied to remove accumulated charge near to the bottom of pores, followed by a negative pulse to deposit metal and a delay to allow diffusion of ions. By optimising the pulse shape and duration, we have achieved uniform growth of metal into pores. Further, monitoring the deposition current helped us to identify and control different phases of growth of the nanowire.
The
properties of the porous alumina and the
nanocomposite were measured by nanoindentation. The deformation characteristics were obtained by observing the indents in a FE-SEM. We find that dendritic modification of interface has very little effect on the hardness of the porous alumina layer. We also found that the porous alumina deformed either by compaction or by forming circumferential and radial cracks. When copper is filled in the nano pores, the hardness increased by 50% and no circumferential cracks were found up to the load of 10 mN for a film thickness of about 1 µm. Coefficient of friction of the coating reciprocated against steel in dry condition is found to be around 0.4. Minimal wear was observed…
Advisors/Committee Members: Bobji, M S (advisor).
Subjects/Keywords: Porous Alumina; Tribological Coating; Composite CoatingS; Nanocomposites; Nanocomposite Coatings; Aluimina Anodisation; Metal Electrochemical Deposition; Nanoindentation; Porous Alumina Film Desposition; Nanoporous Alumina; Ordered Porous Alumina; Mechanical Engineering
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Yadav, A. (2018). Nano Porous Alumina Based Composite Coating for Tribological Applications. (Doctoral Dissertation). Indian Institute of Science. Retrieved from http://etd.iisc.ac.in/handle/2005/3055
Chicago Manual of Style (16th Edition):
Yadav, Arti. “Nano Porous Alumina Based Composite Coating for Tribological Applications.” 2018. Doctoral Dissertation, Indian Institute of Science. Accessed February 27, 2021.
http://etd.iisc.ac.in/handle/2005/3055.
MLA Handbook (7th Edition):
Yadav, Arti. “Nano Porous Alumina Based Composite Coating for Tribological Applications.” 2018. Web. 27 Feb 2021.
Vancouver:
Yadav A. Nano Porous Alumina Based Composite Coating for Tribological Applications. [Internet] [Doctoral dissertation]. Indian Institute of Science; 2018. [cited 2021 Feb 27].
Available from: http://etd.iisc.ac.in/handle/2005/3055.
Council of Science Editors:
Yadav A. Nano Porous Alumina Based Composite Coating for Tribological Applications. [Doctoral Dissertation]. Indian Institute of Science; 2018. Available from: http://etd.iisc.ac.in/handle/2005/3055
6.
Neill, Dustin.
Characterization of mirco/nano mechanical and tribological properties of polymeric coatings deposited on steel.
Degree: MS, Physics and Astronomy, 2012, Eastern Michigan University
URL: https://commons.emich.edu/theses/416
► This study aims to characterize the mechanical and tribological properties of three different polymeric coatings—polyurethane, 2K, and melamine—deposited on steel by analyzing the hardness,…
(more)
▼ This study aims to characterize the
mechanical and
tribological properties of three different polymeric coatings—polyurethane, 2K, and melamine—deposited on steel by analyzing the hardness, elastic modulus, and scratch
resistance of each coating. This was accomplished by making indentation and scratch tests on each sample with a nano-indenter and analyzing the results with a Scanning Probe Microscope (SPM). Results of indentation tests show that melamine, with a hardness of 0.164 GPa and a modulus of 3.367 GPa, was both the hardest and stiffest of the three
coatings, while the 2K coating, with a hardness of .104 GPa and a modulus of 2.721 GPa, was both the softest and most flexible. Scratch test results showed that the highest average critical load, at which the
adhesion to the substrate steel failed, was 100.03 mN for the 2K coating, thus indicating that the 2K coating had the greater
adhesion strength.
Advisors/Committee Members: Weidian Shen, Ph.D, Chair, Alexandria Oakes, Ph.D., Patrick Koehn, Ph.D..
Subjects/Keywords: melamine; adhesion; mechanical; tribological; polymeric coatings; Physics
…characterize the tribological properties of coatings, i.e.
the scratch resistance, are the Taber test… …study the
mechanical and tribological properties of the three coatings.
Nanoindentation is a… …scratch
resistance of the tested coatings with their physical and chemical properties. In the… …it was not the main focus of characterizing the mechanical
and tribological properties of… …tribological properties of three different polymeric coatings—polyurethane, 2K, and
melamine…
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Neill, D. (2012). Characterization of mirco/nano mechanical and tribological properties of polymeric coatings deposited on steel. (Masters Thesis). Eastern Michigan University. Retrieved from https://commons.emich.edu/theses/416
Chicago Manual of Style (16th Edition):
Neill, Dustin. “Characterization of mirco/nano mechanical and tribological properties of polymeric coatings deposited on steel.” 2012. Masters Thesis, Eastern Michigan University. Accessed February 27, 2021.
https://commons.emich.edu/theses/416.
MLA Handbook (7th Edition):
Neill, Dustin. “Characterization of mirco/nano mechanical and tribological properties of polymeric coatings deposited on steel.” 2012. Web. 27 Feb 2021.
Vancouver:
Neill D. Characterization of mirco/nano mechanical and tribological properties of polymeric coatings deposited on steel. [Internet] [Masters thesis]. Eastern Michigan University; 2012. [cited 2021 Feb 27].
Available from: https://commons.emich.edu/theses/416.
Council of Science Editors:
Neill D. Characterization of mirco/nano mechanical and tribological properties of polymeric coatings deposited on steel. [Masters Thesis]. Eastern Michigan University; 2012. Available from: https://commons.emich.edu/theses/416
7.
Τριάντου, Κωστούλα.
Μελέτη απλών και σύνθετων επικαλύψεων ψυχρού ψεκασμού: μικροδομή, μηχανισμός συναπόθεσης, τριβολογία και αντοχή σε διάβρωση.
Degree: 2012, National Technical University of Athens (NTUA); Εθνικό Μετσόβιο Πολυτεχνείο (ΕΜΠ)
URL: http://hdl.handle.net/10442/hedi/27377
► The present thesis is entitled “Study of simple and composite cold sprayed coatings: microstructure, co-deposition mechanism, tribology and corrosion resistance”. A complete study of metallic…
(more)
▼ The present thesis is entitled “Study of simple and composite cold sprayed coatings: microstructure, co-deposition mechanism, tribology and corrosion resistance”. A complete study of metallic and composite (metal+ceramic) coatings produced using cold spray, was the aim of this thesis. Cold Gas Dynamic Spray or Cold Spray is the most recent development in the field of spray techniques for the production of coatings. In this process, the gas (nitrogen, helium or air) is introduced into a Laval type nozzle and produces a supersonic gas flow. Spray particles are accelerated to a high velocity (typically 300-1200 m/s) and are deposited at a temperature well below their melting temperature.
Initially in this research, three different materials with important industrial applications were cold sprayed: copper on Al2017 substrate, CoNiCrAlY on Hastelloy X substrate and titanium on Ti6Al4V substrate. The microstructure of these coatings was studied in order to determine the most suitable material for cold spraying. Also, copper and CoNiCrAlY coatings were compared with coatings obtained using conventional thermal spray techniques (High Velocity Oxy-Fuel and Wire Arc). The most suitable material for cold spray was found to be copper due to the high deformation of copper particles. Cold sprayed copper coatings were qualitatively superior, as they were fully dense, they did not contain oxides and the coating-substrate interface did not present any defects (micro-cracks, porosity or voids). Cold sprayed CoNiCrAlY coatings and Ti coatings contained porosity and voids (4.2% and 14%, respectively). Oxidation was not observed in any of the cold sprayed coatings.
Considering that copper was the most suitable material for use in cold spray, composite Cu+Al2O3 coatings on Al2017 substrate were studied. The aim was to study the microstructural characteristics of the coatings as well as to understand the way that copper and alumina particles were co-deposited. A copper powder of 13μm particle size and two alumina powders, a fine with a size range of 2-12 μm and a coarse of 15-45 μm size range, were used in order to prepare the feedstock mixtures. The copper powder was mechanically blended with each one of the alumina powders in various Al2O3 contents: 0, 10, 20, 25 and 30%wt. Porosity of all the composite and pure copper coatings was very low (<1%). Al2O3 particles were uniformly dispersed in the copper matrix of the composite coatings. Spraying with mixtures of 10, 20, 25 and 30%wt. Al2O3 resulted in coatings with 3, 5, 6 and 7% area (and volume) fraction. The %wt. percentage of deposited particles was equal to 10% of the initial percentage in the feedstock mixture. Since alumina particles could not be deformed on impact, some very small gaps (1-2μm) surrounding the hard phase particles were observed.
Craters and deformations of angular morphology were observed in the surface of the coatings. They were created from Cu and Al2O3 particles (respectively) that impacted, but rebounded and did not adhere. Also, fragmentation of large Al2O3…
Subjects/Keywords: Μεταλλικές επικαλύψεις (χαλκός, κράμα CoNiCrAlY, τιτάνιο); Σύνθετες μεταλλο-κεραμικές επικαλύψεις (χαλκός+αλούμινα; Ψυχρός ψεκασμός; Μικροδομή επικαλύψεων ψυχρού ψεκασμού; Μηχανισμός συναπόθεσης σωματιδίων κατά τον ψυχρό ψεκασμό; Συμπεριφορά σε τριβή-φθορά; Αντοχή σε διάβρωση; Metallic coatings (copper, CoNiCrAlY alloy, titanium; Composite metal+ceramic coatings (copper+alumina; Cold Spray or Cold Gas Dynamic Spray; Microstructure of cold sprayed coatings; Co-deposition mechanism of particles during cold spraying; Tribological behavior; Corrosion resistance
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Τριάντου, . . (2012). Μελέτη απλών και σύνθετων επικαλύψεων ψυχρού ψεκασμού: μικροδομή, μηχανισμός συναπόθεσης, τριβολογία και αντοχή σε διάβρωση. (Thesis). National Technical University of Athens (NTUA); Εθνικό Μετσόβιο Πολυτεχνείο (ΕΜΠ). Retrieved from http://hdl.handle.net/10442/hedi/27377
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Τριάντου, Κωστούλα. “Μελέτη απλών και σύνθετων επικαλύψεων ψυχρού ψεκασμού: μικροδομή, μηχανισμός συναπόθεσης, τριβολογία και αντοχή σε διάβρωση.” 2012. Thesis, National Technical University of Athens (NTUA); Εθνικό Μετσόβιο Πολυτεχνείο (ΕΜΠ). Accessed February 27, 2021.
http://hdl.handle.net/10442/hedi/27377.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Τριάντου, Κωστούλα. “Μελέτη απλών και σύνθετων επικαλύψεων ψυχρού ψεκασμού: μικροδομή, μηχανισμός συναπόθεσης, τριβολογία και αντοχή σε διάβρωση.” 2012. Web. 27 Feb 2021.
Vancouver:
Τριάντου . Μελέτη απλών και σύνθετων επικαλύψεων ψυχρού ψεκασμού: μικροδομή, μηχανισμός συναπόθεσης, τριβολογία και αντοχή σε διάβρωση. [Internet] [Thesis]. National Technical University of Athens (NTUA); Εθνικό Μετσόβιο Πολυτεχνείο (ΕΜΠ); 2012. [cited 2021 Feb 27].
Available from: http://hdl.handle.net/10442/hedi/27377.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Τριάντου . Μελέτη απλών και σύνθετων επικαλύψεων ψυχρού ψεκασμού: μικροδομή, μηχανισμός συναπόθεσης, τριβολογία και αντοχή σε διάβρωση. [Thesis]. National Technical University of Athens (NTUA); Εθνικό Μετσόβιο Πολυτεχνείο (ΕΜΠ); 2012. Available from: http://hdl.handle.net/10442/hedi/27377
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

University of New South Wales
8.
Wang, Jian.
Microstructure and Mechanical Properties of Compound and High Entropy Alloy Coatings.
Degree: Materials Science & Engineering, 2019, University of New South Wales
URL: http://handle.unsw.edu.au/1959.4/67994
;
https://unsworks.unsw.edu.au/fapi/datastream/unsworks:68833/SOURCE02?view=true
► Hard coatings have been widely used for decades in a range of applications, such as cutting tools or medical devices. In this thesis, the microstructure…
(more)
▼ Hard coatings have been widely used for decades in a range of applications, such as cutting tools or medical devices. In this thesis, the microstructure and mechanical properties of a number of nitride, silicide and high entropy alloy coatings were investigated. First, for molybdenum nitride coatings, the influence of nitrogen content on microstructure and mechanical properties was studied. It was shown that an increase in nitrogen concentration resulted in a structural transformation from a bcc α-Mo phase to fcc γ-Mo2N and then to fcc B1 MoN, as well as a change in the nature of the Mo-N bonds from covalent bonds to weaker ionic bonds, which led to changes in mechanical and tribological behavior. In addition, the formation of lubricious MoOx layers on MoN contributed to a low coefficient of friction. Further, for silicide-based compounds, the effects of Ag on MoO3-SiO2 and Nb5Si3 coatings, together with the effects of Al on Ta5Si3 coatings were investigated. MoO3-SiO2 coatings consisted of hexagonal-structured MoO3 together with amorphous SiO2 and a discrete fcc Ag phase. The addition of Ag increased damage tolerance, but reduced hardness and modulus and degraded scratch adhesion. For Nb5Si3 coatings it was found that Ag dissolved in solution in tetragonal α-Nb5Si3 by locating on Nb sites in the α-Nb5Si3 lattice. The contact damage resistance was increased by the addition of Ag, while both hardness and elastic modulus were reduced and scratch resistance was degraded. For Ta5Si3 coatings, it was found Al atoms substituted for Si sites in the β-Ta5Si3 unit cell. Al additions to Ta5Si3 coatings generated improved damage tolerance, but also lowered hardness, elastic modulus and coating adhesion. Finally, the effect of deposition temperature on the structure and properties of high-entropy alloy TiMoWZrHf coatings was investigated. Coatings were found to be composed of nanoscale mixtures of fcc HfO2/ZrO2-based oxides together with a bcc Mo0.4W0.6 phase. The coating deposited at the higher temperature exhibited a lower density of voids resulting in higher hardness and elastic modulus, as well as reduced damage tolerance and higher critical loads during scratch testing.
Subjects/Keywords: Compound Alloy Coatings; Microstructures; Mechanical Properties; High Entropy Alloy Coatings
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Wang, J. (2019). Microstructure and Mechanical Properties of Compound and High Entropy Alloy Coatings. (Doctoral Dissertation). University of New South Wales. Retrieved from http://handle.unsw.edu.au/1959.4/67994 ; https://unsworks.unsw.edu.au/fapi/datastream/unsworks:68833/SOURCE02?view=true
Chicago Manual of Style (16th Edition):
Wang, Jian. “Microstructure and Mechanical Properties of Compound and High Entropy Alloy Coatings.” 2019. Doctoral Dissertation, University of New South Wales. Accessed February 27, 2021.
http://handle.unsw.edu.au/1959.4/67994 ; https://unsworks.unsw.edu.au/fapi/datastream/unsworks:68833/SOURCE02?view=true.
MLA Handbook (7th Edition):
Wang, Jian. “Microstructure and Mechanical Properties of Compound and High Entropy Alloy Coatings.” 2019. Web. 27 Feb 2021.
Vancouver:
Wang J. Microstructure and Mechanical Properties of Compound and High Entropy Alloy Coatings. [Internet] [Doctoral dissertation]. University of New South Wales; 2019. [cited 2021 Feb 27].
Available from: http://handle.unsw.edu.au/1959.4/67994 ; https://unsworks.unsw.edu.au/fapi/datastream/unsworks:68833/SOURCE02?view=true.
Council of Science Editors:
Wang J. Microstructure and Mechanical Properties of Compound and High Entropy Alloy Coatings. [Doctoral Dissertation]. University of New South Wales; 2019. Available from: http://handle.unsw.edu.au/1959.4/67994 ; https://unsworks.unsw.edu.au/fapi/datastream/unsworks:68833/SOURCE02?view=true

Vilnius Gediminas Technical University
9.
Rodžianskas,
Tomas.
Elektrolankinio purškimo skirtingomis vielomis
tyrimas.
Degree: Master, Materials Engineering, 2014, Vilnius Gediminas Technical University
URL: http://vddb.laba.lt/obj/LT-eLABa-0001:E.02~2014~D_20140619_092224-76020
;
► Baigiamajame magistro darbe nagrinėjamos elektrolankiniu purškimu skirtingomis vielomis užpurkštos dangos. Atlikta terminio purškimo dangų, jų technologijų apžvalga ir analizė, pateikta dangų tyrimo metodika. Metalo paviršinis…
(more)
▼ Baigiamajame magistro darbe nagrinėjamos
elektrolankiniu purškimu skirtingomis vielomis užpurkštos dangos.
Atlikta terminio purškimo dangų, jų technologijų apžvalga ir
analizė, pateikta dangų tyrimo metodika. Metalo paviršinis
sluoksnis dengiamas siekiant pakeisti jo mechanines bei fizikines
savybes, suteikti atsparumą išorės poveikiui ir pagerinti estetinį
vaizdą. Atlikti nerūdijančio plieno, jūrinės bronzos bei jų
kombinuotos dangų mikrostruktūros, mikrokietumo, dangos tamprumo
modulio bei adhezijos tyrimai. Gauti rezultatai pateikti grafiškai.
Išnagrinėjus praktinius ir skaitinius terminio purškimo dangų
rezultatus, pateikiamos baigiamojo darbo išvados. Darbą sudaro 5
dalys: įvadas, literatūros šaltinių apžvalga ir analizė,
elektrolankiniu purškimu gautų dangų tyrimai, išvados, literatūros
sąrašas. Darbo apimtis – 59 p. teksto, 55 iliustr., 14 lent., 18
bibliografinių šaltinių.
In the final master thesis examined coatings
by arc spraying with different solid wires. The review of thermal
spray coatings technology and research methods are described. The
metal surface coating was applied to modify it‘s mechanical and
physical properties, also resistance to external impact and improve
aesthetics view. The research of stainless steel, marine bronze and
combined coating microstructures, microhardness modulus of
elesticity and adhesion were carried out. The results are presented
graphically. The experimental and numerical results of thermal
spray coatings were analysed and conclusions were given. Structure
of work: introduction, literature review and analysis, research of
coatings by arc spraying, coclusions, references. Thesis consist of
– 59 p. text, 55 pictures, 14 tables, 18 bibliografical
entries.
Advisors/Committee Members: Gedzevičius, Irmantas (Master’s thesis supervisor), Višniakas, Ivanas (Master’s thesis reviewer), Černašėjus, Olegas (Master’s thesis reviewer), Jurčius, Aurimas (Master’s degree committee chair), Valiulis, Algirdas Vaclovas (Master’s degree committee member), Višniakas, Ivanas (Master’s degree committee member), Gedzevičius, Irmantas (Master’s degree committee member), Černašėjus, Olegas (Master’s degree committee member), Nagurnas, Saulius (Master’s degree committee member), Kandrotaitė Janutienė, Rasa (Master’s degree committee member).
Subjects/Keywords: Adhezija; Dangos; Lankas; Mikrokietumas;
Mikrostruktūros; Adhesion; Arc; Coatings; Microhardness;
Microstructure
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Rodžianskas,
Tomas. (2014). Elektrolankinio purškimo skirtingomis vielomis
tyrimas. (Masters Thesis). Vilnius Gediminas Technical University. Retrieved from http://vddb.laba.lt/obj/LT-eLABa-0001:E.02~2014~D_20140619_092224-76020 ;
Note: this citation may be lacking information needed for this citation format:
Author name may be incomplete
Chicago Manual of Style (16th Edition):
Rodžianskas,
Tomas. “Elektrolankinio purškimo skirtingomis vielomis
tyrimas.” 2014. Masters Thesis, Vilnius Gediminas Technical University. Accessed February 27, 2021.
http://vddb.laba.lt/obj/LT-eLABa-0001:E.02~2014~D_20140619_092224-76020 ;.
Note: this citation may be lacking information needed for this citation format:
Author name may be incomplete
MLA Handbook (7th Edition):
Rodžianskas,
Tomas. “Elektrolankinio purškimo skirtingomis vielomis
tyrimas.” 2014. Web. 27 Feb 2021.
Note: this citation may be lacking information needed for this citation format:
Author name may be incomplete
Vancouver:
Rodžianskas,
Tomas. Elektrolankinio purškimo skirtingomis vielomis
tyrimas. [Internet] [Masters thesis]. Vilnius Gediminas Technical University; 2014. [cited 2021 Feb 27].
Available from: http://vddb.laba.lt/obj/LT-eLABa-0001:E.02~2014~D_20140619_092224-76020 ;.
Note: this citation may be lacking information needed for this citation format:
Author name may be incomplete
Council of Science Editors:
Rodžianskas,
Tomas. Elektrolankinio purškimo skirtingomis vielomis
tyrimas. [Masters Thesis]. Vilnius Gediminas Technical University; 2014. Available from: http://vddb.laba.lt/obj/LT-eLABa-0001:E.02~2014~D_20140619_092224-76020 ;
Note: this citation may be lacking information needed for this citation format:
Author name may be incomplete

University of Manchester
10.
Zhao, Yang.
Evaluation and characterisation of thermal barrier coatings.
Degree: PhD, 2013, University of Manchester
URL: https://www.research.manchester.ac.uk/portal/en/theses/evaluation-and-characterisation-of-thermal-barrier-coatings(b6b8d5ef-0cd3-4257-9563-6a6b1626cb49).html
;
http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.607074
► Evaluation and characterisation of thermal barrier coatings (TBCs) have been conducted correlating microstructure with physical and mechanical properties, to further understand TBC failure mechanisms and…
(more)
▼ Evaluation and characterisation of thermal barrier coatings (TBCs) have been conducted correlating microstructure with physical and mechanical properties, to further understand TBC failure mechanisms and performances in this thesis. A modified four-point bending test was employed to investigate the interfacial toughness of atmospheric plasma sprayed TBCs. The delamination of the TBCs occurred mainly within the topcoat. The energy release rate increased from ~50 J/m-2 for as-sprayed conditions to ~120 J/m-2 after annealing at 1150 ºC for 200 hours with a loading phase angle about 42º. Micro X-ray tomography revealed how various types of imperfections developed near the interface and the 3D interface was characterised. Stress measurements by photoluminescence piezospectroscopy (PLPS) and analytical solutions were combined to investigate the local stress around spherically symmetrical portions of a TGO layer formed on Fecralloy. Spherical indenters were used to create curvature with different curvature radii and depths on alloys. The effect of curvature radius on stress was found to be more significant than the depth of local curved area. TGO stress as a function of oxidation time at the curved areas was also discussed. Electron beam physical vapour deposited (EBPVD) TBCs with a β-(Ni,Pt)Al bond coat on CMSX4 substrate were investigated by micro X-ray computed tomography (XCT). The 3D microstructures evolution and damage accumulation were studied. 3D interfacial roughness was calculated and compared to scanning electron microscope image analysis. The calculated interfacial roughness did not change much even after 200 thermal cycles, indicating there was not obvious rumpling in this TBCs sample. Commercial simple and Pt-modified aluminide coatings were studied and compared. Both coatings consisted mainly of β-NiAl phase. Thermogravimetric analysis (TGA) tests indicated that the Pt-modified aluminide coating was much more resistive for oxidation than simple aluminide coating. Instrumented indentation was used to measure the mechanical properties, showing the coatings had similar young’s modulus around 130 GPa while Pt-modified aluminide coating was more ductile and had a higher fracture toughness than simple aluminide coating. The Raman spectra of yttria-stabilised zirconia (YSZ) in the temperature range of 25-1100 ºC were investigated. The peak shift and broadening were carefully analysed. The thermal mismatch stress was found to have a negligible effect on the Raman shift. The dependence can be used to monitor the temperature in YSZ without contact.
Subjects/Keywords: 667; thermal barrier coatings; mechanical properties
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Zhao, Y. (2013). Evaluation and characterisation of thermal barrier coatings. (Doctoral Dissertation). University of Manchester. Retrieved from https://www.research.manchester.ac.uk/portal/en/theses/evaluation-and-characterisation-of-thermal-barrier-coatings(b6b8d5ef-0cd3-4257-9563-6a6b1626cb49).html ; http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.607074
Chicago Manual of Style (16th Edition):
Zhao, Yang. “Evaluation and characterisation of thermal barrier coatings.” 2013. Doctoral Dissertation, University of Manchester. Accessed February 27, 2021.
https://www.research.manchester.ac.uk/portal/en/theses/evaluation-and-characterisation-of-thermal-barrier-coatings(b6b8d5ef-0cd3-4257-9563-6a6b1626cb49).html ; http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.607074.
MLA Handbook (7th Edition):
Zhao, Yang. “Evaluation and characterisation of thermal barrier coatings.” 2013. Web. 27 Feb 2021.
Vancouver:
Zhao Y. Evaluation and characterisation of thermal barrier coatings. [Internet] [Doctoral dissertation]. University of Manchester; 2013. [cited 2021 Feb 27].
Available from: https://www.research.manchester.ac.uk/portal/en/theses/evaluation-and-characterisation-of-thermal-barrier-coatings(b6b8d5ef-0cd3-4257-9563-6a6b1626cb49).html ; http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.607074.
Council of Science Editors:
Zhao Y. Evaluation and characterisation of thermal barrier coatings. [Doctoral Dissertation]. University of Manchester; 2013. Available from: https://www.research.manchester.ac.uk/portal/en/theses/evaluation-and-characterisation-of-thermal-barrier-coatings(b6b8d5ef-0cd3-4257-9563-6a6b1626cb49).html ; http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.607074

Brno University of Technology
11.
Saggar, Richa.
Processing and Properties of 1D and 2D Boron Nitride Nanomaterials Reinforced Glass Composites: Processing and Properties of 1D and 2D Boron Nitride Nanomaterials Reinforced Glass Composites.
Degree: 2019, Brno University of Technology
URL: http://hdl.handle.net/11012/63681
► Glasses and ceramics offer several unique characteristics over polymers or metals. However, they suffer from a shortcoming due to their brittle nature, falling short in…
(more)
▼ Glasses and ceramics offer several unique characteristics over polymers or metals. However, they suffer from a shortcoming due to their brittle nature, falling short in terms of fracture toughness and
mechanical strength. The aim of this work is to reinforce borosilicate glass matrix with reinforcements to increase the fracture toughness and strength of the glass. Boron nitride nanomaterials, i.e. nanotubes and nanosheets have been used as possible reinforcements for the borosilicate glass matrix. The tasks of the thesis are many fold which include: 1. Reinforcement of commercially derived and morphologically different (bamboo like and cylinder like) boron nitride nanotubes in borosilicate glass with the concentration of 0 wt%, 2.5 wt% and 5 wt% by ball milling process. Same process was repeated with reinforcing cleaned boron nitride nanotubes (after acid purification) into the borosilicate glass with similar concentrations. 2. Production of boron nitride nanosheets using liquid exfoliation technique to produce high quality and high aspect ratio nanosheets. These boron nitride nanosheets were reinforced in the borosilicate glass matrix with concentrations of 0 wt%, 2.5 wt% and 5 wt% by ball milling process. The samples were consolidated using spark plasma sintering. These composites were studied in details in terms of material analysis like thermo-gravimetric analysis, detailed scanning electron microscopy and transmission electron microscopy for the quality of reinforcements etc.;
microstructure analysis which include the detailed study of the composite powder samples, the densities of bulk composite samples etc;
mechanical properties which include fracture toughness, flexural strength, micro-hardness, Young’s modulus etc. and;
tribological properties like scratch
resistance and wear
resistance. Cleaning process of boron nitride nanotubes lead to reduction in the Fe content (present in boron nitride nanotubes during their production as a catalyst) by ~54%. This leads to an improvement of ~30% of fracture toughness measured by chevron notch technique for 5 wt% boron nitride nanotubes reinforced borosilicate glass. It also contributed to the improvement of scratch
resistance by ~26% for the 5 wt% boron nitride nanotubes reinforced borosilicate glass matrix. On the other hand, boron nitride nanosheets were successfully produced using liquid exfoliation technique with average length was ~0.5 µm and thickness of the nanosheets was between 4-30 layers. It accounted to an improvement of ~45% for both fracture toughness and flexural strength by reinforcing 5 wt% of boron nitride nanosheets. The wear rates reduced by ~3 times while the coefficient of friction was reduced by ~23% for 5 wt% boron nitride nanosheets reinforcements. Resulting improvements in fracture toughness and flexural strength in the composite materials were observed due to high interfacial bonding between the boron nitride nanomaterials and borosilicate glass matrix resulting in efficient load transfer. Several toughening and strengthening mechanisms like…
Advisors/Committee Members: Dlouhý, Ivo (advisor), Cihlář, Jaroslav (referee), Tatarko, Peter (referee).
Subjects/Keywords: Keywords: Boron nitride nanosheets; Boron nitride nanotubes; Borosilicate glass; Nanocomposite; Mechanical properties; Tribological properties.; Keywords: Boron nitride nanosheets; Boron nitride nanotubes; Borosilicate glass; Nanocomposite; Mechanical properties; Tribological properties.
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Saggar, R. (2019). Processing and Properties of 1D and 2D Boron Nitride Nanomaterials Reinforced Glass Composites: Processing and Properties of 1D and 2D Boron Nitride Nanomaterials Reinforced Glass Composites. (Thesis). Brno University of Technology. Retrieved from http://hdl.handle.net/11012/63681
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Saggar, Richa. “Processing and Properties of 1D and 2D Boron Nitride Nanomaterials Reinforced Glass Composites: Processing and Properties of 1D and 2D Boron Nitride Nanomaterials Reinforced Glass Composites.” 2019. Thesis, Brno University of Technology. Accessed February 27, 2021.
http://hdl.handle.net/11012/63681.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Saggar, Richa. “Processing and Properties of 1D and 2D Boron Nitride Nanomaterials Reinforced Glass Composites: Processing and Properties of 1D and 2D Boron Nitride Nanomaterials Reinforced Glass Composites.” 2019. Web. 27 Feb 2021.
Vancouver:
Saggar R. Processing and Properties of 1D and 2D Boron Nitride Nanomaterials Reinforced Glass Composites: Processing and Properties of 1D and 2D Boron Nitride Nanomaterials Reinforced Glass Composites. [Internet] [Thesis]. Brno University of Technology; 2019. [cited 2021 Feb 27].
Available from: http://hdl.handle.net/11012/63681.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Saggar R. Processing and Properties of 1D and 2D Boron Nitride Nanomaterials Reinforced Glass Composites: Processing and Properties of 1D and 2D Boron Nitride Nanomaterials Reinforced Glass Composites. [Thesis]. Brno University of Technology; 2019. Available from: http://hdl.handle.net/11012/63681
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

University of Manchester
12.
Eaves, Elizabeth.
Soft-soft nanocomposite coating materials produced by
emulsion polymerisation.
Degree: 2015, University of Manchester
URL: http://www.manchester.ac.uk/escholar/uk-ac-man-scw:266749
► AbstractElizabeth EavesThe University of ManchesterPhD Polymer Science and Engineering“Soft-soft nanocomposite coating materials produced by emulsion polymerisation”March 2015This thesis reports on the challenge of applying an…
(more)
▼ AbstractElizabeth EavesThe University of
ManchesterPhD Polymer Science and Engineering“Soft-soft
nanocomposite coating materials produced by emulsion
polymerisation”March 2015This thesis reports on the challenge of
applying an innovative ‘soft-soft nanocomposite’ design strategy to
establish synthesis parameters that affect the performance of
coatings based upon water-borne latexes, which is driven by the
environmental and legislative need to develop feasible alternatives
to solvent-borne coatings. A framework emulsion polymerisation
formulation to synthesise core-shell latexes with (poly[(butyl
acrylate)-co-(butyl methacrylate)]) core and (poly[(butyl
acrylate)-co-(butyl methacrylate)-co-(diacetone acrylamide)]) shell
copolymer phases in a controlled manner was established, with high
monomer conversions and approximately constant particle numbers.
Retention of particle morphology in the films was confirmed using
atomic force microscopy (AFM). The effect of adding adipic acid
dihydrazide to the latex post-polymerisation to facilitate
crosslinking of the shell phase during film formation was found to
have a significant effect on the stress-strain properties of latex
films. A core:shell mass ratio of 80:20 was found to be optimum in
all crosslinked systems tested. Increasing the amount of
crosslinking in the shell phase of the particles was found to have
an effect on the large strain tensile properties of films, leading
to strain hardening with reduced extension to break and higher
failure stresses at higher crosslinker levels. Core phase copolymer
Tg had a very significant effect upon the low strain mechanical
properties, with Young’s modulus values of 5-180 MPa being
accessible in the range of core Tg¬s from 5 – 25 °C, although
little difference in mechanical behaviour was seen when varying the
shell phase Tg from 5 – 15 °C. Adding 2 wt% methacrylic acid (MAA)
to the shell phase copolymer gave an additional improvement in the
low strain tensile region, with a Young’s modulus of 425 MPa being
realised. However, it was found that additional amounts of MAA (up
to 5 wt% in the shell phase) were deterious to film properties,
with low Young’s modulus and poor extensibility. This was
interpreted as being due to an increased concentration of ionomeric
crosslinks restricting interparticle chain diffusion and
keto-hydrazide crosslinking. Studies to evaluate the mechanical
performance of soft-soft nanocomposite films compared to binder
latexes used in commercial products were favourable, and showed
that a high level of versatility with regards to mechanical
properties is possible.
None
None
Advisors/Committee Members: Lovell, Peter.
Subjects/Keywords: Polymer; Film formation; Coatings; Nanocomposite
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MLA ·
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APA (6th Edition):
Eaves, E. (2015). Soft-soft nanocomposite coating materials produced by
emulsion polymerisation. (Doctoral Dissertation). University of Manchester. Retrieved from http://www.manchester.ac.uk/escholar/uk-ac-man-scw:266749
Chicago Manual of Style (16th Edition):
Eaves, Elizabeth. “Soft-soft nanocomposite coating materials produced by
emulsion polymerisation.” 2015. Doctoral Dissertation, University of Manchester. Accessed February 27, 2021.
http://www.manchester.ac.uk/escholar/uk-ac-man-scw:266749.
MLA Handbook (7th Edition):
Eaves, Elizabeth. “Soft-soft nanocomposite coating materials produced by
emulsion polymerisation.” 2015. Web. 27 Feb 2021.
Vancouver:
Eaves E. Soft-soft nanocomposite coating materials produced by
emulsion polymerisation. [Internet] [Doctoral dissertation]. University of Manchester; 2015. [cited 2021 Feb 27].
Available from: http://www.manchester.ac.uk/escholar/uk-ac-man-scw:266749.
Council of Science Editors:
Eaves E. Soft-soft nanocomposite coating materials produced by
emulsion polymerisation. [Doctoral Dissertation]. University of Manchester; 2015. Available from: http://www.manchester.ac.uk/escholar/uk-ac-man-scw:266749

Brno University of Technology
13.
Ivanič, Michal.
Materiály a metody testování vlastností žárově stříkaných povlaků: Thermal spray coatings; materials and techniques for testing its properties.
Degree: 2019, Brno University of Technology
URL: http://hdl.handle.net/11012/67406
► Bachelor thesis deals with the distribution of thermal spray coatings according to their use, and methods used to testing their properties. The first part describes…
(more)
▼ Bachelor thesis deals with the distribution of thermal spray
coatings according to their use, and methods used to testing their
properties. The first part describes the
properties of the
coatings, their interaction with the environment and selected types of the thermally sprayed
coatings. The second part is focused on representative testing methods, designed to evaluate the
coatings properties.
Advisors/Committee Members: Čelko, Ladislav (advisor), Jech, David (referee).
Subjects/Keywords: tepelný nástrek; materiály povlakov; vlastnosti povlakov; adhézne testy povlakov; testy odolnosti povlakov voči opotrebeniu; testovanie povlakov pre vysokoteplotné aplikácie; thermal spray coatings; coatings materials; coatings properties; adhesion tests; wear resistance tests; high temperature tests
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APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
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APA (6th Edition):
Ivanič, M. (2019). Materiály a metody testování vlastností žárově stříkaných povlaků: Thermal spray coatings; materials and techniques for testing its properties. (Thesis). Brno University of Technology. Retrieved from http://hdl.handle.net/11012/67406
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Ivanič, Michal. “Materiály a metody testování vlastností žárově stříkaných povlaků: Thermal spray coatings; materials and techniques for testing its properties.” 2019. Thesis, Brno University of Technology. Accessed February 27, 2021.
http://hdl.handle.net/11012/67406.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Ivanič, Michal. “Materiály a metody testování vlastností žárově stříkaných povlaků: Thermal spray coatings; materials and techniques for testing its properties.” 2019. Web. 27 Feb 2021.
Vancouver:
Ivanič M. Materiály a metody testování vlastností žárově stříkaných povlaků: Thermal spray coatings; materials and techniques for testing its properties. [Internet] [Thesis]. Brno University of Technology; 2019. [cited 2021 Feb 27].
Available from: http://hdl.handle.net/11012/67406.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Ivanič M. Materiály a metody testování vlastností žárově stříkaných povlaků: Thermal spray coatings; materials and techniques for testing its properties. [Thesis]. Brno University of Technology; 2019. Available from: http://hdl.handle.net/11012/67406
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
14.
Ilangovan, S.
Investigation of the mechanical properties and wear
behaviour of sand cast copper nickel tin alloys; -.
Degree: Engineering, 2004, Amrita Vishwa Vidyapeetham (University)
URL: http://shodhganga.inflibnet.ac.in/handle/10603/13062
► The effect of strengthening by spinodal decomposition on the mechanical properties and the wear behavior has been investigated on cast copper-nickel-tin alloys. The investigation was…
(more)
▼ The effect of strengthening by spinodal
decomposition on the mechanical properties and the wear behavior
has been investigated on cast copper-nickel-tin alloys. The
investigation was performed under various conditions by varying (a)
newlinenickel content from 4 to 15 wt. % while tin content is kept
at 6 wt. % (b) tin content newlinefrom 4 to 8 wt. % while nickel
content is kept at 6 wt. % and (c) aging temperature newlinefrom
300° C to 400° C with fixed alloy composition of Cu-5Ni-5Sn. After
the casting process, the specimens were homogenized, solution heat
treated and aged to induce spinodal decomposition and ordering
reaction. Then, the specimens were tested / examined for (a)
microstructure (b) micro-hardness (c) tensile strength, yield
strength and % elongation and (d) wear rate and coefficient of
friction. It was found that nickel contributes significantly to the
spinodal/ordering newlineprocess whereby increasing the magnitude
of the peak hardness, whereas the newlinecontribution of Sn is
marginal. Both Ni and Sn contribute significantly to the kinetics
newlineof the transformation whereby reducing the aging time, when
either of these elements newlineis increased. The wear rate was
found to be a function of hardness. The coefficient of friction is
observed to be a constant (0.4 - 0.6) and independent of hardness
(138 HV- 368 HV). Further, the peak hardness increases with aging
temperatures up to 400° C. The yield stress and tensile stress were
found to be proportional to the hardness of the newlinealloy. The
percent elongation decreases with increase in the hardness. The
yield stress newlineof the alloy was found to increase two times
than that of traditional cast Bronze alloys.
References p.97-102
Advisors/Committee Members: Sellamuthu, R.
Subjects/Keywords: Mechanical Engineering; Copper; Mechanical properties; Nickel; Tin; Hardening; Tribological behaviour
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APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
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APA (6th Edition):
Ilangovan, S. (2004). Investigation of the mechanical properties and wear
behaviour of sand cast copper nickel tin alloys; -. (Thesis). Amrita Vishwa Vidyapeetham (University). Retrieved from http://shodhganga.inflibnet.ac.in/handle/10603/13062
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Ilangovan, S. “Investigation of the mechanical properties and wear
behaviour of sand cast copper nickel tin alloys; -.” 2004. Thesis, Amrita Vishwa Vidyapeetham (University). Accessed February 27, 2021.
http://shodhganga.inflibnet.ac.in/handle/10603/13062.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Ilangovan, S. “Investigation of the mechanical properties and wear
behaviour of sand cast copper nickel tin alloys; -.” 2004. Web. 27 Feb 2021.
Vancouver:
Ilangovan S. Investigation of the mechanical properties and wear
behaviour of sand cast copper nickel tin alloys; -. [Internet] [Thesis]. Amrita Vishwa Vidyapeetham (University); 2004. [cited 2021 Feb 27].
Available from: http://shodhganga.inflibnet.ac.in/handle/10603/13062.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Ilangovan S. Investigation of the mechanical properties and wear
behaviour of sand cast copper nickel tin alloys; -. [Thesis]. Amrita Vishwa Vidyapeetham (University); 2004. Available from: http://shodhganga.inflibnet.ac.in/handle/10603/13062
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Colorado School of Mines
15.
Ward, Logan.
Tribological and structural properties of titanium nitride and titanium aluminum nitride coatings deposited with modulated pulsed power magnetron sputtering.
Degree: MS(M.S.), Metallurgical and Materials Engineering, 2014, Colorado School of Mines
URL: http://hdl.handle.net/11124/508
► The demand for economical high-performance materials has brought attention to the development of advanced coatings. Recent advances in high power magnetron sputtering (HPPMS) have shown…
(more)
▼ The demand for economical high-performance materials has brought attention to the development of advanced
coatings. Recent advances in high power magnetron sputtering (HPPMS) have shown to improve
tribological properties of
coatings. These
coatings offer increased wear and oxidation
resistance, which may facilitate the use of more economical materials in harsh applications. This study demonstrates the use of novel forms of HPPMS, namely modulated pulsed-power magnetron sputtering (MPPMS) and deep oscillation magnetron sputtering (DOMS), for depositing TiN and Ti[subscript 1-x]Al[subscript x]N
tribological coatings on commonly used alloys, such as Ti-6Al-4V and Inconel 718. Both technologies have been shown to offer unique plasma characteristics in the physical vapor deposition (PVD) process. High power pulses lead to a high degree of ionization compared to traditional direct-current magnetron sputtering (DCMS) and pulsed magnetron sputtering (PMS). Such a high degree of ionization was previously only achievable by cathodic arc deposition (CAD); however, CAD can lead to increased macroparticles that are unfavorable in high friction and corrosive environments. MPPMS, DOMS, and other HPPMS techniques offer unique plasma characteristics and have been shown to produce
coatings with refined grain structure, improved density, hardness,
adhesion, and wear
resistance. Using DOMS and MPPMS, TiN and Ti[subscript 1-x]Al[subscript x]N
coatings were deposited using PMS to compare microstructures and
tribological performance. For Ti[subscript 1-x]Al[subscript x]N, two sputtering target compositions, 50Ti-50Al and 30Ti-70Al, were used to evaluate the effects of MPPMS on the coating's composition and
tribological properties. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD) were used to characterize
microstructure and crystallographic texture. Several
tribological properties were evaluated including: wear rate, coefficient of friction,
adhesion, and nanohardness. Results show that substrate material can have a significant effect on
adhesion and the
mechanical response between the coating and substrate. Depending on deposition parameters and the selected material MPPMS and DOMS are promising alternatives to DCMS, PMS, and CAD.
Advisors/Committee Members: Kaufman, Michael J. (advisor), Reimanis, Ivar E. (Ivar Edmund) (committee member), Lin, Jianliang (committee member).
Subjects/Keywords: tribological; high power magnetron sputtering; coatings; thin films; modulated pulsed power magnetron sputtering; wear resistant; Coatings; Magnetron sputtering; Titanium nitride; Tribology; Microstructure
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Ward, L. (2014). Tribological and structural properties of titanium nitride and titanium aluminum nitride coatings deposited with modulated pulsed power magnetron sputtering. (Masters Thesis). Colorado School of Mines. Retrieved from http://hdl.handle.net/11124/508
Chicago Manual of Style (16th Edition):
Ward, Logan. “Tribological and structural properties of titanium nitride and titanium aluminum nitride coatings deposited with modulated pulsed power magnetron sputtering.” 2014. Masters Thesis, Colorado School of Mines. Accessed February 27, 2021.
http://hdl.handle.net/11124/508.
MLA Handbook (7th Edition):
Ward, Logan. “Tribological and structural properties of titanium nitride and titanium aluminum nitride coatings deposited with modulated pulsed power magnetron sputtering.” 2014. Web. 27 Feb 2021.
Vancouver:
Ward L. Tribological and structural properties of titanium nitride and titanium aluminum nitride coatings deposited with modulated pulsed power magnetron sputtering. [Internet] [Masters thesis]. Colorado School of Mines; 2014. [cited 2021 Feb 27].
Available from: http://hdl.handle.net/11124/508.
Council of Science Editors:
Ward L. Tribological and structural properties of titanium nitride and titanium aluminum nitride coatings deposited with modulated pulsed power magnetron sputtering. [Masters Thesis]. Colorado School of Mines; 2014. Available from: http://hdl.handle.net/11124/508

University of Windsor
16.
Zhang, Ying.
Tribological properties of diamond-like carbon and boron carbide coatings against aluminum: Adhesion & friction at different temperatures and environments.
Degree: MA, Mechanical, Automotive, and Materials Engineering, 2007, University of Windsor
URL: https://scholar.uwindsor.ca/etd/7024
Subjects/Keywords: ADHESION; ALUMINUM; BORON; CARBIDE; CARBON; COATINGS; DIAMOND; DIFFERENT; ENVIRONMENTS; FRICTION; LIKE; PROPERTIES; TEMPERATURES; TRIBOLOGICAL
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Zhang, Y. (2007). Tribological properties of diamond-like carbon and boron carbide coatings against aluminum: Adhesion & friction at different temperatures and environments. (Masters Thesis). University of Windsor. Retrieved from https://scholar.uwindsor.ca/etd/7024
Chicago Manual of Style (16th Edition):
Zhang, Ying. “Tribological properties of diamond-like carbon and boron carbide coatings against aluminum: Adhesion & friction at different temperatures and environments.” 2007. Masters Thesis, University of Windsor. Accessed February 27, 2021.
https://scholar.uwindsor.ca/etd/7024.
MLA Handbook (7th Edition):
Zhang, Ying. “Tribological properties of diamond-like carbon and boron carbide coatings against aluminum: Adhesion & friction at different temperatures and environments.” 2007. Web. 27 Feb 2021.
Vancouver:
Zhang Y. Tribological properties of diamond-like carbon and boron carbide coatings against aluminum: Adhesion & friction at different temperatures and environments. [Internet] [Masters thesis]. University of Windsor; 2007. [cited 2021 Feb 27].
Available from: https://scholar.uwindsor.ca/etd/7024.
Council of Science Editors:
Zhang Y. Tribological properties of diamond-like carbon and boron carbide coatings against aluminum: Adhesion & friction at different temperatures and environments. [Masters Thesis]. University of Windsor; 2007. Available from: https://scholar.uwindsor.ca/etd/7024

University of New South Wales
17.
Li, Ann.
Effect of chromium on the microstructure and mechanical properties of amorphous carbon coatings.
Degree: Materials Science & Engineering, 2014, University of New South Wales
URL: http://handle.unsw.edu.au/1959.4/54857
;
https://unsworks.unsw.edu.au/fapi/datastream/unsworks:36061/SOURCE02?view=true
► Amorphous carbon (a-C) films, known for exhibiting an attractive combination of mechanical and physical properties, have been extensively studied. However, the inherent residual stresses affecting…
(more)
▼ Amorphous carbon (a-C) films, known for exhibiting an attractive combination of
mechanical and physical
properties, have been extensively studied. However, the inherent residual stresses affecting their
adhesion to substrates often prevent the growth of thicker films and limit the usage of carbon films. Carbide forming metals such as W, Ti, Cr and Al, when incorporated into the carbon network, can help to stabilise the film structure, reduce compressive residual stresses and improve performance. This thesis focuses on the
microstructure, composition, and
mechanical property characterization under contact loading of amorphous carbon based films containing chromium. The films were fabricated using an unbalanced magnetron sputtering deposition system, with four C and two Cr targets and Ar gas. M2 steel, with two different hardness values (Rockwell 20 and 60), was used for the substrate, with roughly half of samples deposited on each substrate type. The Cr concentration in the films of the samples (from 0% up to ~48at.%) was controlled by varying the current (up to 3A) on the Cr targets. The
microstructure and composition of the carbon were characterised by transmission electron microscopy (TEM), energy-dispersive x-ray spectrometer (EDS), X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy. The hardness and elastic modulus of the
coatings were analysed with nanoindentation tests using both a Hysitron Triboscope and a UMIS 2000 nanoindentation system. The latter indenter was used to study the deformation behaviour of the coating-substrate composites, with a maximum applied load up to 500mN. The indented areas were cross-sectioned and examined using a focused ion beam microscope (FIB). Raman and XPS analysis suggested that all the films had a low sp3/sp2 ratio. The results showed that both pure a-C, and carbon films with very low Cr contents, exhibited the highest hardness and elastic modulus, while a-C with medium Cr content (~16 at.%) were found to have the lowest hardness and modulus values. Incorporation of more Cr results in, possibly, the presence of chromium carbide phase and led to an increase in hardness compared to the medium-Cr samples. Films deposited on the softer substrate exhibited significant cracking on contact loading compared to the
coatings on the harder substrates.This thesis focuses on the
microstructure, composition, and
mechanical property characterization under contact loading of amorphous carbon based films containing chromium. The films were fabricated using an unbalanced magnetron sputtering deposition system, with four C and two Cr targets and Ar gas. M2 steel, with two different hardness values (Rockwell 20 and 60), was used for the substrate, with roughly half of samples deposited on each substrate type. The Cr concentration in the films of the samples (from 0% up to ~48at.%) was controlled by varying the current (up to 3A) on the Cr targets. The
microstructure and composition of the carbon were characterised by transmission electron microscopy (TEM), energy-dispersive x-ray…
Advisors/Committee Members: Munroe, Paul, Materials Science & Engineering, Faculty of Science, UNSW.
Subjects/Keywords: Amorphous carbon coatings; Chromium; Microstructure
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Li, A. (2014). Effect of chromium on the microstructure and mechanical properties of amorphous carbon coatings. (Masters Thesis). University of New South Wales. Retrieved from http://handle.unsw.edu.au/1959.4/54857 ; https://unsworks.unsw.edu.au/fapi/datastream/unsworks:36061/SOURCE02?view=true
Chicago Manual of Style (16th Edition):
Li, Ann. “Effect of chromium on the microstructure and mechanical properties of amorphous carbon coatings.” 2014. Masters Thesis, University of New South Wales. Accessed February 27, 2021.
http://handle.unsw.edu.au/1959.4/54857 ; https://unsworks.unsw.edu.au/fapi/datastream/unsworks:36061/SOURCE02?view=true.
MLA Handbook (7th Edition):
Li, Ann. “Effect of chromium on the microstructure and mechanical properties of amorphous carbon coatings.” 2014. Web. 27 Feb 2021.
Vancouver:
Li A. Effect of chromium on the microstructure and mechanical properties of amorphous carbon coatings. [Internet] [Masters thesis]. University of New South Wales; 2014. [cited 2021 Feb 27].
Available from: http://handle.unsw.edu.au/1959.4/54857 ; https://unsworks.unsw.edu.au/fapi/datastream/unsworks:36061/SOURCE02?view=true.
Council of Science Editors:
Li A. Effect of chromium on the microstructure and mechanical properties of amorphous carbon coatings. [Masters Thesis]. University of New South Wales; 2014. Available from: http://handle.unsw.edu.au/1959.4/54857 ; https://unsworks.unsw.edu.au/fapi/datastream/unsworks:36061/SOURCE02?view=true
18.
Σαράφογλου, Χαρίκλεια.
Μεταλλουργικός και τριβολογικός χαρακτηρισμός μεταλλικών και κεραμικών επιστρωμάτων που παράγονται με χρήση προηγμένων τεχνικών θερμικ...
Degree: 2012, National Technical University of Athens (NTUA); Εθνικό Μετσόβιο Πολυτεχνείο (ΕΜΠ)
URL: http://hdl.handle.net/10442/hedi/28196
► The present thesis deals with the microstructural characteristics and tribological properties of metallic and ceramic thermal sprayed coatings. These properties as well as the overall…
(more)
▼ The present thesis deals with the microstructural characteristics and tribological properties of metallic and ceramic thermal sprayed coatings. These properties as well as the overall quality of thermal sprayed coatings depend on many factors such as spraying parameters, feedstock materials and adoption of the spraying method. This study brought into focus on five parameters that seem to influence substantially the quality of coatings and need to be taken into account during design the spraying procedure.
Firstly, the influence of substrate metallurgy on the properties of coatings was studied, by selecting two stainless steels of different metallurgical and thermal properties. A martensitic and an austenitic stainless steel were chosen as substrates to be coated with a metallic (Mo-based) and a ceramic (ZrO2-24%MgO) coating by using atmospheric plasma spraying technique (APS). When forming the metallic and the ceramic coating, the higher thermal conductivity of the martensitic steel compared to austenitic resulted in the rapid dissipation of heat from the surface and hence lower substrate temperature. This led to unsatisfactory deposition and solidification of molten particles of powder and hence the forming layers of the coating, resulting in degradation of microstructural characteristics.
Secondly, the effect of a metallic bond coating (NiAl) in the properties of ceramic coating (Cr¬2O3¬¬) is investigated. More precisely, the microstructural, tribological and mechanical properties of three coatings (Cr¬2O3¬¬, NiAl and Cr2O3¬¬–bond coating NiAl), obtained by atmospheric plasma spraying on medium carbon steel was studied focusing on the influence of bond coating. The application of Ni-5% Al, as a bonding layer between the steel and ceramic coating Cr2O3, led to increased microhardness values, reduced percentage of porosity (by ~ 27%), increased the adhesion strength and improve wear behavior.
Another factor that was investigated was the feedstock powder. More precisely, the development of Mo and Cr-Mn alloyed steel thermal spray coatings, produced by conventional and nanostructured feedstock was studied. The coatings have been developed by APS and HVOF on AISI 1045 substrates. The purpose was the development of APS and HVOF alloyed steel coatings from nanostructured feedstock materials and their comparison with the respective conventional coatings in terms of microstructure, mechanical properties and tribological behavior. The atmospheric plasma spraying of conventional powder FeCr (Mn) C and nanocrystalline, provided two coatings of different properties as expected. Although the conventional coating showed lower roughness and porosity compared to the nanocrystalline coating, which due to these characteristics showed lower adhesion strength, microhardness was the same while friction and wear behavior was improved. By HVOF spraying technique conventional and nanostructured coatings presented similar microstructure characteristics. However, the nanocrystalline coating offers a reduced friction coefficient by about…
Subjects/Keywords: Θερμικός ψεκασμός; Συμπεριφορά σε τριβή-φθορά; Μεταλλικά επιστρώματα; Κεραμικά επιστρώματα; Επίδραση παραγόντων ψεκασμού; Thermal spraying; Microstructural study; Tribological behaviour; Ceramic coatings; Metallic coatings; Spraying parameters effect
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APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
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APA (6th Edition):
Σαράφογλου, . . (2012). Μεταλλουργικός και τριβολογικός χαρακτηρισμός μεταλλικών και κεραμικών επιστρωμάτων που παράγονται με χρήση προηγμένων τεχνικών θερμικ... (Thesis). National Technical University of Athens (NTUA); Εθνικό Μετσόβιο Πολυτεχνείο (ΕΜΠ). Retrieved from http://hdl.handle.net/10442/hedi/28196
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Σαράφογλου, Χαρίκλεια. “Μεταλλουργικός και τριβολογικός χαρακτηρισμός μεταλλικών και κεραμικών επιστρωμάτων που παράγονται με χρήση προηγμένων τεχνικών θερμικ...” 2012. Thesis, National Technical University of Athens (NTUA); Εθνικό Μετσόβιο Πολυτεχνείο (ΕΜΠ). Accessed February 27, 2021.
http://hdl.handle.net/10442/hedi/28196.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Σαράφογλου, Χαρίκλεια. “Μεταλλουργικός και τριβολογικός χαρακτηρισμός μεταλλικών και κεραμικών επιστρωμάτων που παράγονται με χρήση προηγμένων τεχνικών θερμικ...” 2012. Web. 27 Feb 2021.
Vancouver:
Σαράφογλου . Μεταλλουργικός και τριβολογικός χαρακτηρισμός μεταλλικών και κεραμικών επιστρωμάτων που παράγονται με χρήση προηγμένων τεχνικών θερμικ... [Internet] [Thesis]. National Technical University of Athens (NTUA); Εθνικό Μετσόβιο Πολυτεχνείο (ΕΜΠ); 2012. [cited 2021 Feb 27].
Available from: http://hdl.handle.net/10442/hedi/28196.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Σαράφογλου . Μεταλλουργικός και τριβολογικός χαρακτηρισμός μεταλλικών και κεραμικών επιστρωμάτων που παράγονται με χρήση προηγμένων τεχνικών θερμικ... [Thesis]. National Technical University of Athens (NTUA); Εθνικό Μετσόβιο Πολυτεχνείο (ΕΜΠ); 2012. Available from: http://hdl.handle.net/10442/hedi/28196
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

University of Zambia
19.
Simpemba, Prospery C.
Growth and Characterisation of Spray Pyrolytic Doped Zinc and Aluminium Oxide Spectral-Selective thin Films
.
Degree: 2012, University of Zambia
URL: http://hdl.handle.net/123456789/1995
► Metal oxide thin films have been used in thin film solar cells and other solar energy applications for many years. The main concern has been…
(more)
▼ Metal oxide thin films have been used in thin film solar cells and other solar energy applications for many years. The main concern has been to improve their physical, electrical and optical properties in order to increase their efficiency and lower their production costs. Zinc oxide doped with aluminium (ZnO:Al) and aluminium oxide doped with zinc (A^CbiZn) thin films have been produced by a spray pyrolysis process onto standard microscope glass slides at different substrate temperatures and for different solution concentrations, spray times and pressure. The main objective was to produce single, double and triple layer thin films and characterized them for their optical, electrical and structural properties. The spectral selectiveness of these oxide thin films and their applicability in producing efficient solar cells has been investigated. Optical measurements in the ultraviolet, visible and near infrared ranges have been performed using the Perkin-Elmer Lambda 19 spectrophotometer. Further optical characterization in the far infrared has been performed using the BX Fourier Transform Infrared (FT-IR) spectrophotometer at the University of Dar es Salaam Solar Energy Research Laboratory. Structural characterization for determination of surface morphology and film thickness has been done using the Atomic Force Microscope and the Tencor Alpha Step IQ Profiler. On the other hand electrical properties have been investigated using the four-point resistance square probe. The transmittance, reflectance and thickness of the thin films as well as the sheet resistance have been experimentally obtained. The solar transmittance of 88 percent has been achieved for Al-doped zinc oxide (ZnO) films whereas 71.94 per cent has been obtained for Zn-doped aluminium oxide (AlaOa). The film thicknesses fall in the range 0.14 - 87.7 um. The films have low reflectance in the order of 10 percent. Peak reflectance of 25 per cent has been recorded for the wavelength range 8-12,0m. The wavelength-dependent refractive index of the films has been evaluated from reflectance and transmittance measurements. In the VIS-NIR, the obtained refractive indices were 1.28 for ZnO, 1.97 for ZnO:Al and 2.0 for A^OsiZn. Features of the film surface microstructure have been analyzed and related to how they affect the general properties of the films. The properties of these thin films have been modeled using the Bruggeman and Maxwell-Garnett effective medium theories obtaining effective values for the permeability constants and using these to calculate the effective values of refractive indices. The film sheet resistance values of 0.75 Q, 9.5 Q and corresponding resistivity values of 9.59 x 10"4Qm and 2.43 x 10~4Q m have been obtained for ZnO:Al, and resistance values of 5.56Q and 12 Q with corresponding resistivity values of 4.47 x 10"4Qm and 11.80 x 10"4Qm have been achieved for A^C^Zn. These film properties have been related to applications in thin film solar cells.
Subjects/Keywords: Thin Films – coatings;
Thin Films(metal oxide) – Mechanical properties
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Simpemba, P. C. (2012). Growth and Characterisation of Spray Pyrolytic Doped Zinc and Aluminium Oxide Spectral-Selective thin Films
. (Thesis). University of Zambia. Retrieved from http://hdl.handle.net/123456789/1995
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Simpemba, Prospery C. “Growth and Characterisation of Spray Pyrolytic Doped Zinc and Aluminium Oxide Spectral-Selective thin Films
.” 2012. Thesis, University of Zambia. Accessed February 27, 2021.
http://hdl.handle.net/123456789/1995.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Simpemba, Prospery C. “Growth and Characterisation of Spray Pyrolytic Doped Zinc and Aluminium Oxide Spectral-Selective thin Films
.” 2012. Web. 27 Feb 2021.
Vancouver:
Simpemba PC. Growth and Characterisation of Spray Pyrolytic Doped Zinc and Aluminium Oxide Spectral-Selective thin Films
. [Internet] [Thesis]. University of Zambia; 2012. [cited 2021 Feb 27].
Available from: http://hdl.handle.net/123456789/1995.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Simpemba PC. Growth and Characterisation of Spray Pyrolytic Doped Zinc and Aluminium Oxide Spectral-Selective thin Films
. [Thesis]. University of Zambia; 2012. Available from: http://hdl.handle.net/123456789/1995
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
20.
Simpemba, Prospery C.
Growth and Characterisation of Spray Pyrolytic Doped Zinc and Aluminium Oxide Spectral-Selective thin Films.
Degree: 2012, University of Zimbabwe
URL: http://dspace.unza.zm/handle/123456789/1218
► Metal oxide thin films have been used in thin film solar cells and other solar energy applications for many years. The main concern has been…
(more)
▼ Metal oxide thin films have been used in thin film solar cells and other solar energy applications for many years. The main concern has been to improve their physical, electrical and optical properties in order to increase their efficiency and lower their production costs. Zinc oxide doped with aluminium (ZnO:Al) and aluminium oxide doped with zinc (Al2O3:Zn) thin films have been produced by a spray pyrolysis process onto standard microscope glass slides at different substrate temperatures and for different solution concentrations, spray times and pressure. The main objective was to produce single, double and triple layer thin films and characterized them for their optical, electrical and structural properties. The spectral selectiveness of these oxide thin films and their applicability in producing efficient solar cells has been investigated. Optical measurements in the ultraviolet, visible and near infrared ranges have been performed using the Perkin-Elmer Lambda 19 spectrophotometer. Further optical characterization in the far infrared has been performed using the BX Fourier Transform Infrared (FT-IR) spectrophotometer at the University of Dar es Salaam Solar Energy Research Laboratory. Structural characterization for determination of surface morphology and film thickness has been done using the Atomic Force Microscope and the Tencor Alpha Step IQ Profiler. On the other hand electrical properties have been investigated using the four-point resistance square probe. The transmittance, reflectance and thickness of the thin films as well as the sheet resistance have been experimentally obtained. The solar transmittance of 88 percent has been achieved for Al-doped zinc oxide (ZnO) films whereas 71.94 per cent has been obtained for Zn-doped aluminium oxide (Al2O3). The film thicknesses fall in the range 0.14 - 87.7 μm. The films have low reflectance in the order of 10 percent. Peak reflectance of 25 per cent has been recorded for the wavelength range 8-12 m. The wavelength-dependent refractive index of the films has been evaluated from reflectance and transmittance measurements. In the VIS-NIR, the obtained refractive indices were 1.28 for ZnO, 1.97 for ZnO:Al and 2.0 for Al2O3:Zn. Features of the film surface microstructure have been analyzed and related to how they affect the general properties of the films. The properties of these thin films have been modeled using the Bruggeman and Maxwell-Garnett effective medium theories obtaining effective values for the permeability constants and using these to calculate the effective values of refractive indices. The film sheet resistance values of 0.75 , 9.5 and corresponding resistivity values of 9.59 x 10-4 m and 2.43 x 10-4 m have been obtained for ZnO:Al, and resistance values of 5.56 and 12 with corresponding resistivity values of 4.47 x 10-4 m and 11.80 x 10-4 m have been achieved for Al2O3:Zn. These film properties have been related to applications in thin film solar cells.
Subjects/Keywords: Thin Films – coatings; Thin Films(metal oxide) – Mechanical properties
Record Details
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Record Details
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Simpemba, P. C. (2012). Growth and Characterisation of Spray Pyrolytic Doped Zinc and Aluminium Oxide Spectral-Selective thin Films. (Thesis). University of Zimbabwe. Retrieved from http://dspace.unza.zm/handle/123456789/1218
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Simpemba, Prospery C. “Growth and Characterisation of Spray Pyrolytic Doped Zinc and Aluminium Oxide Spectral-Selective thin Films.” 2012. Thesis, University of Zimbabwe. Accessed February 27, 2021.
http://dspace.unza.zm/handle/123456789/1218.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Simpemba, Prospery C. “Growth and Characterisation of Spray Pyrolytic Doped Zinc and Aluminium Oxide Spectral-Selective thin Films.” 2012. Web. 27 Feb 2021.
Vancouver:
Simpemba PC. Growth and Characterisation of Spray Pyrolytic Doped Zinc and Aluminium Oxide Spectral-Selective thin Films. [Internet] [Thesis]. University of Zimbabwe; 2012. [cited 2021 Feb 27].
Available from: http://dspace.unza.zm/handle/123456789/1218.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Simpemba PC. Growth and Characterisation of Spray Pyrolytic Doped Zinc and Aluminium Oxide Spectral-Selective thin Films. [Thesis]. University of Zimbabwe; 2012. Available from: http://dspace.unza.zm/handle/123456789/1218
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
21.
Simpemba, Prospery C.
Growth and Characterisation of Spray Pyrolytic Doped Zinc and Aluminium Oxide Spectral-Selective thin Films.
Degree: 2012, University of Zimbabwe
URL: http://dspace.unza.zm/handle/123456789/1281
► Metal oxide thin films have been used in thin film solar cells and other solar energy applications for many years. The main concern has been…
(more)
▼ Metal oxide thin films have been used in thin film solar cells and other solar energy applications for many years. The main concern has been to improve their physical, electrical and optical properties in order to increase their efficiency and lower their production costs. Zinc oxide doped with aluminium (ZnO:Al) and aluminium oxide doped with zinc (Al2O3:Zn) thin films have been produced by a spray pyrolysis process onto standard microscope glass slides at different substrate temperatures and for different solution concentrations, spray times and pressure. The main objective was to produce single, double and triple layer thin films and characterized them for their optical, electrical and structural properties. The spectral selectiveness of these oxide thin films and their applicability in producing efficient solar cells has been investigated. Optical measurements in the ultraviolet, visible and near infrared ranges have been performed using the Perkin-Elmer Lambda 19 spectrophotometer. Further optical characterization in the far infrared has been performed using the BX Fourier Transform Infrared (FT-IR) spectrophotometer at the University of Dar es Salaam Solar Energy Research Laboratory. Structural characterization for determination of surface morphology and film thickness has been done using the Atomic Force Microscope and the Tencor Alpha Step IQ Profiler. On the other hand electrical properties have been investigated using the four-point resistance square probe. The transmittance, reflectance and thickness of the thin films as well as the sheet resistance have been experimentally obtained. The solar transmittance of 88 percent has been achieved for Al-doped zinc oxide (ZnO) films whereas 71.94 per cent has been obtained for Zn-doped aluminium oxide (Al2O3). The film thicknesses fall in the range 0.14 - 87.7 μm. The films have low reflectance in the order of 10 percent. Peak reflectance of 25 per cent has been recorded for the wavelength range 8-12 m. The wavelength-dependent refractive index of the films has been evaluated from reflectance and transmittance measurements. In the VIS-NIR, the obtained refractive indices were 1.28 for ZnO, 1.97 for ZnO:Al and 2.0 for Al2O3:Zn. Features of the film surface microstructure have been analyzed and related to how they affect the general properties of the films. The properties of these thin films have been modeled using the Bruggeman and Maxwell-Garnett effective medium theories obtaining effective values for the permeability constants and using these to calculate the effective values of refractive indices. The film sheet resistance values of 0.75 , 9.5 and corresponding resistivity values of 9.59 x 10-4 m and 2.43 x 10-4 m have been obtained for ZnO:Al, and resistance values of 5.56 and 12 with corresponding resistivity values of 4.47 x 10-4 m and 11.80 x 10-4 m have been achieved for Al2O3:Zn. These film properties have been related to applications in thin film solar cells.
Subjects/Keywords: Thin Films – coatings; Thin Films(metal oxide) – Mechanical properties
Record Details
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Record Details
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Simpemba, P. C. (2012). Growth and Characterisation of Spray Pyrolytic Doped Zinc and Aluminium Oxide Spectral-Selective thin Films. (Thesis). University of Zimbabwe. Retrieved from http://dspace.unza.zm/handle/123456789/1281
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Simpemba, Prospery C. “Growth and Characterisation of Spray Pyrolytic Doped Zinc and Aluminium Oxide Spectral-Selective thin Films.” 2012. Thesis, University of Zimbabwe. Accessed February 27, 2021.
http://dspace.unza.zm/handle/123456789/1281.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Simpemba, Prospery C. “Growth and Characterisation of Spray Pyrolytic Doped Zinc and Aluminium Oxide Spectral-Selective thin Films.” 2012. Web. 27 Feb 2021.
Vancouver:
Simpemba PC. Growth and Characterisation of Spray Pyrolytic Doped Zinc and Aluminium Oxide Spectral-Selective thin Films. [Internet] [Thesis]. University of Zimbabwe; 2012. [cited 2021 Feb 27].
Available from: http://dspace.unza.zm/handle/123456789/1281.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Simpemba PC. Growth and Characterisation of Spray Pyrolytic Doped Zinc and Aluminium Oxide Spectral-Selective thin Films. [Thesis]. University of Zimbabwe; 2012. Available from: http://dspace.unza.zm/handle/123456789/1281
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
22.
Noferesti, Amir Darabi.
Microstructural Characteristics and Mechanical Behavior of Anticorrosive Al-Zn Thermal Spray Coatings Deposited by Wire Arc Spraying and Cold Spraying Techniques.
Degree: 2019, North Dakota State University
URL: http://hdl.handle.net/10365/31645
► Mechanical properties of thermal spray deposited coatings are highly influenced by their microstructural characteristics. The objective of this investigation is to evaluate the mechanical properties…
(more)
▼ Mechanical properties of thermal spray deposited coatings are highly influenced by their microstructural characteristics. The objective of this investigation is to evaluate the mechanical properties of thermally sprayed coatings consisted of aluminum and zinc based on the coating microstructure, using an image based computational scheme. Microstructural images of coating samples were subjected to image-based finite element analysis and the results were validated by experimental tests and analytical models. Comparison of the experimental data with FEA was used to explain the microstructural basis of the mechanical characteristics of Al-Zn coatings and the differences between two methods of thermal spray techniques. It was concluded that the cold spraying technique produces higher-quality coatings with less porosity and higher hardness compared to wire arc deposition. An isotropic behavior was observed in the cold sprayed coating. Finally, the electrochemical tests showed that the coating with a higher amount of zinc had better anti-corrosion properties.
Subjects/Keywords: Al-Zn; finite element; mechanical properties; microstructural features; thermal spray coatings
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Noferesti, A. D. (2019). Microstructural Characteristics and Mechanical Behavior of Anticorrosive Al-Zn Thermal Spray Coatings Deposited by Wire Arc Spraying and Cold Spraying Techniques. (Thesis). North Dakota State University. Retrieved from http://hdl.handle.net/10365/31645
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Noferesti, Amir Darabi. “Microstructural Characteristics and Mechanical Behavior of Anticorrosive Al-Zn Thermal Spray Coatings Deposited by Wire Arc Spraying and Cold Spraying Techniques.” 2019. Thesis, North Dakota State University. Accessed February 27, 2021.
http://hdl.handle.net/10365/31645.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Noferesti, Amir Darabi. “Microstructural Characteristics and Mechanical Behavior of Anticorrosive Al-Zn Thermal Spray Coatings Deposited by Wire Arc Spraying and Cold Spraying Techniques.” 2019. Web. 27 Feb 2021.
Vancouver:
Noferesti AD. Microstructural Characteristics and Mechanical Behavior of Anticorrosive Al-Zn Thermal Spray Coatings Deposited by Wire Arc Spraying and Cold Spraying Techniques. [Internet] [Thesis]. North Dakota State University; 2019. [cited 2021 Feb 27].
Available from: http://hdl.handle.net/10365/31645.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Noferesti AD. Microstructural Characteristics and Mechanical Behavior of Anticorrosive Al-Zn Thermal Spray Coatings Deposited by Wire Arc Spraying and Cold Spraying Techniques. [Thesis]. North Dakota State University; 2019. Available from: http://hdl.handle.net/10365/31645
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Delft University of Technology
23.
Rueda Ruiz, M. (author).
Mechanical testing and quantification of crack healing in self-healing yttria-stabilized zirconia thermal barrier coating.
Degree: 2016, Delft University of Technology
URL: http://resolver.tudelft.nl/uuid:acd7365a-1001-43ae-b6c0-2b7e74dc3dbe
► Thermal barrier coatings (TBC) are often applied to hot components of modern turbojet engines. These coatings increase the performance of the engine and enhance the…
(more)
▼ Thermal barrier coatings (TBC) are often applied to hot components of modern turbojet engines. These coatings increase the performance of the engine and enhance the lifetime of its structural components. Thus, improving the TBC lifetime is related with a reduction of maintenance costs and increased reliability. As an alternative to conventional design approaches, a self-healing mechanism is implemented in the TBC material. To this end, alumina encapsulated MoSi2B-based YSZ composites were prepared via spark plasma sintering. First, a qualitative study of the crack healing behaviour was conducted using an indentation technique. In most of the cases, indentation cracks fracture the particles in line with the crack path. Then, a sufficient particle-matrix interface strength exists. Upon oxidation at 1100 ºC for 1, 4 and 16 h in laboratory air, the fractured particles oxidize and form glassy SiO2, that filled the crack. It has been observed that the SiO2 further reacts with the YSZ matrix and forms a well-bonded healing product, ZrSiO4. As a second step, a quantitative characterization of the recovery of load bearing capability for the self-healing TBC was performed. For this purpose, two novel mechanical test methods were developed to create a controlled crack that can be stopped, healed and re-tested. This enables to measure in the same specimen the virginal, residual and healed strength of the material. These two set-ups are the Brazilian Disc (BD) test and the Wedge-Loaded Double Cantilever Beam (WL-DCB) test. The application of both the WL-DCB and BD test to the self-healing TBC material was successful because the growth of a crack could be controlled in the brittle material. The WL-DCB test is potentially more suitable for quantification of recovery of load bearing capability. The BD test is more straightforward for determining strength of the material. Application of this BD test to benchmark YSZ material gave a strength value of around 550 MPa, which is accordance with previously reported values for this material. Following the successful achievement of controlled cracking with both methods, the quantification of load bearing capability in the healed material remains an issue of future work.
Aerospace Engineering
Aerospace Structures and Materials
Advisors/Committee Members: Sloof, W.G. (mentor), Van der Zwaag, S. (mentor).
Subjects/Keywords: self-healing; thermal barrier coatings; mechanical characterization; strength and fracture testing; crack healing
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Rueda Ruiz, M. (. (2016). Mechanical testing and quantification of crack healing in self-healing yttria-stabilized zirconia thermal barrier coating. (Masters Thesis). Delft University of Technology. Retrieved from http://resolver.tudelft.nl/uuid:acd7365a-1001-43ae-b6c0-2b7e74dc3dbe
Chicago Manual of Style (16th Edition):
Rueda Ruiz, M (author). “Mechanical testing and quantification of crack healing in self-healing yttria-stabilized zirconia thermal barrier coating.” 2016. Masters Thesis, Delft University of Technology. Accessed February 27, 2021.
http://resolver.tudelft.nl/uuid:acd7365a-1001-43ae-b6c0-2b7e74dc3dbe.
MLA Handbook (7th Edition):
Rueda Ruiz, M (author). “Mechanical testing and quantification of crack healing in self-healing yttria-stabilized zirconia thermal barrier coating.” 2016. Web. 27 Feb 2021.
Vancouver:
Rueda Ruiz M(. Mechanical testing and quantification of crack healing in self-healing yttria-stabilized zirconia thermal barrier coating. [Internet] [Masters thesis]. Delft University of Technology; 2016. [cited 2021 Feb 27].
Available from: http://resolver.tudelft.nl/uuid:acd7365a-1001-43ae-b6c0-2b7e74dc3dbe.
Council of Science Editors:
Rueda Ruiz M(. Mechanical testing and quantification of crack healing in self-healing yttria-stabilized zirconia thermal barrier coating. [Masters Thesis]. Delft University of Technology; 2016. Available from: http://resolver.tudelft.nl/uuid:acd7365a-1001-43ae-b6c0-2b7e74dc3dbe

University of Manchester
24.
Eaves, Elizabeth.
Soft-soft nanocomposite coating materials produced by emulsion polymerisation.
Degree: PhD, 2015, University of Manchester
URL: https://www.research.manchester.ac.uk/portal/en/theses/softsoft-nanocomposite-coating-materials-produced-by-emulsion-polymerisation(2ccdd0fe-22d3-4dea-bf0c-ecf7ef8c7da2).html
;
https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.809284
► This thesis reports on the challenge of applying an innovative 'soft-soft nanocomposite' design strategy to establish synthesis parameters that affect the performance of coatings based…
(more)
▼ This thesis reports on the challenge of applying an innovative 'soft-soft nanocomposite' design strategy to establish synthesis parameters that affect the performance of coatings based upon water-borne latexes, which is driven by the environmental and legislative need to develop feasible alternatives to solvent-borne coatings. A framework emulsion polymerisation formulation to synthesise core-shell latexes with (poly[(butyl acrylate)-co-(butyl methacrylate)]) core and (poly[(butyl acrylate)-co-(butyl methacrylate)-co-(diacetone acrylamide)]) shell copolymer phases in a controlled manner was established, with high monomer conversions and approximately constant particle numbers. Retention of particle morphology in the films was confirmed using atomic force microscopy (AFM). The effect of adding adipic acid dihydrazide to the latex post-polymerisation to facilitate crosslinking of the shell phase during film formation was found to have a significant effect on the stress-strain properties of latex films. A core:shell mass ratio of 80:20 was found to be optimum in all crosslinked systems tested. Increasing the amount of crosslinking in the shell phase of the particles was found to have an effect on the large strain tensile properties of films, leading to strain hardening with reduced extension to break and higher failure stresses at higher crosslinker levels. Core phase copolymer Tg had a very significant effect upon the low strain mechanical properties, with Young's modulus values of 5-180 MPa being accessible in the range of core Tg¬s from 5-25 °C, although little difference in mechanical behaviour was seen when varying the shell phase Tg from 5-15 °C. Adding 2 wt% methacrylic acid (MAA) to the shell phase copolymer gave an additional improvement in the low strain tensile region, with a Young's modulus of 425 MPa being realised. However, it was found that additional amounts of MAA (up to 5 wt% in the shell phase) were deterious to film properties, with low Young's modulus and poor extensibility. This was interpreted as being due to an increased concentration of ionomeric crosslinks restricting interparticle chain diffusion and keto-hydrazide crosslinking. Studies to evaluate the mechanical performance of soft-soft nanocomposite films compared to binder latexes used in commercial products were favourable, and showed that a high level of versatility with regards to mechanical properties is possible.
Subjects/Keywords: 668.9; Film formation; Coatings; Polymer; Nanocomposite
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Eaves, E. (2015). Soft-soft nanocomposite coating materials produced by emulsion polymerisation. (Doctoral Dissertation). University of Manchester. Retrieved from https://www.research.manchester.ac.uk/portal/en/theses/softsoft-nanocomposite-coating-materials-produced-by-emulsion-polymerisation(2ccdd0fe-22d3-4dea-bf0c-ecf7ef8c7da2).html ; https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.809284
Chicago Manual of Style (16th Edition):
Eaves, Elizabeth. “Soft-soft nanocomposite coating materials produced by emulsion polymerisation.” 2015. Doctoral Dissertation, University of Manchester. Accessed February 27, 2021.
https://www.research.manchester.ac.uk/portal/en/theses/softsoft-nanocomposite-coating-materials-produced-by-emulsion-polymerisation(2ccdd0fe-22d3-4dea-bf0c-ecf7ef8c7da2).html ; https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.809284.
MLA Handbook (7th Edition):
Eaves, Elizabeth. “Soft-soft nanocomposite coating materials produced by emulsion polymerisation.” 2015. Web. 27 Feb 2021.
Vancouver:
Eaves E. Soft-soft nanocomposite coating materials produced by emulsion polymerisation. [Internet] [Doctoral dissertation]. University of Manchester; 2015. [cited 2021 Feb 27].
Available from: https://www.research.manchester.ac.uk/portal/en/theses/softsoft-nanocomposite-coating-materials-produced-by-emulsion-polymerisation(2ccdd0fe-22d3-4dea-bf0c-ecf7ef8c7da2).html ; https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.809284.
Council of Science Editors:
Eaves E. Soft-soft nanocomposite coating materials produced by emulsion polymerisation. [Doctoral Dissertation]. University of Manchester; 2015. Available from: https://www.research.manchester.ac.uk/portal/en/theses/softsoft-nanocomposite-coating-materials-produced-by-emulsion-polymerisation(2ccdd0fe-22d3-4dea-bf0c-ecf7ef8c7da2).html ; https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.809284

Delft University of Technology
25.
Murali, Sneha (author).
Micromechanical Modelling of Fracture Behaviour in Self-Healing Thermal Barrier Coatings.
Degree: 2017, Delft University of Technology
URL: http://resolver.tudelft.nl/uuid:eaa0262e-1fb6-4439-b40d-9840f04e9131
► Crack initiation and propagation in composite structures exists as a prominent knowledge gap in computational fracture mechanics. Prior to the development and implementation of fracture…
(more)
▼ Crack initiation and propagation in composite structures exists as a prominent knowledge gap in computational fracture mechanics. Prior to the development and implementation of fracture modules in FEM solvers, most studies were constrained to simple geometries and load cases. The set of parametric studies that constitute this thesis aims to partially fill this knowledge gap by studying the fracture
behavior of air-plasma sprayed thermal barrier
coatings (APS-TBCs) using cohesive zone modelling (CZM) in conjunction with FEM. Two-dimensional projections of the TBC microstructures were developed and subjected to a thermomechanical analysis involving thermal strains between the different components of the TBC system. The parametric study was split into three sections. The preliminary study, set O, was executed to discern the most appropriate set of boundary conditions that would produce realistic
crack patterns in an expedient manner. Set A and Set B studied the fracture behaviour of conventional TBCs and the recently developed self-healing TBC composite, comprised of lamellae and pores and for Set B, self-healing particles. Qualitative observations reveal the influence of feature dimensions and relative placement to one another. The results appear to indicate that TBC top-coats that are comprised of finer lamellae exhibit higher fracture
resistance on both conventional and self-healing systems, and that smaller particles in self-healing systems mitigate damage caused by pores less than larger particles.
Advisors/Committee Members: van der Zwaag, Sybrand (mentor), Turteltaub, Sergio (mentor), Chen, Boyang (graduation committee), Delft University of Technology (degree granting institution).
Subjects/Keywords: fracture behaviour; Self-healing; coatings
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APA (6th Edition):
Murali, S. (. (2017). Micromechanical Modelling of Fracture Behaviour in Self-Healing Thermal Barrier Coatings. (Masters Thesis). Delft University of Technology. Retrieved from http://resolver.tudelft.nl/uuid:eaa0262e-1fb6-4439-b40d-9840f04e9131
Chicago Manual of Style (16th Edition):
Murali, Sneha (author). “Micromechanical Modelling of Fracture Behaviour in Self-Healing Thermal Barrier Coatings.” 2017. Masters Thesis, Delft University of Technology. Accessed February 27, 2021.
http://resolver.tudelft.nl/uuid:eaa0262e-1fb6-4439-b40d-9840f04e9131.
MLA Handbook (7th Edition):
Murali, Sneha (author). “Micromechanical Modelling of Fracture Behaviour in Self-Healing Thermal Barrier Coatings.” 2017. Web. 27 Feb 2021.
Vancouver:
Murali S(. Micromechanical Modelling of Fracture Behaviour in Self-Healing Thermal Barrier Coatings. [Internet] [Masters thesis]. Delft University of Technology; 2017. [cited 2021 Feb 27].
Available from: http://resolver.tudelft.nl/uuid:eaa0262e-1fb6-4439-b40d-9840f04e9131.
Council of Science Editors:
Murali S(. Micromechanical Modelling of Fracture Behaviour in Self-Healing Thermal Barrier Coatings. [Masters Thesis]. Delft University of Technology; 2017. Available from: http://resolver.tudelft.nl/uuid:eaa0262e-1fb6-4439-b40d-9840f04e9131

University of Windsor
26.
Abou Gharam, Ahmed.
Tribological behaviour of H- and W-DLC coatings: Effects of
environment and temperature on adhesion.
Degree: PhD, Mechanical, Automotive, and Materials
Engineering, 2014, University of Windsor
URL: http://scholar.uwindsor.ca/etd/5058
► The objective of this study was to gain insight into the friction, aluminum adhesion, and wear mechanisms of diamond-like carbon (DLC) coatings, and to…
(more)
▼ The objective of this study was to
gain insight into the friction, aluminum
adhesion, and wear
mechanisms of diamond-like carbon (DLC)
coatings, and to provide
guidelines for coating design and development. Mechanisms that
control the
tribological behaviour of DLC
coatings and the effects
of dopants (i.e. hydrogen (H-DLC), and tungsten (W-DLC)) against
aluminum alloys were investigated under various environments and
test temperatures. The effects of temperature and an oxygen-rich
environment on dopant-free DLC, H- DLC, and W- DLC were
investigated. Experimental analyses of dopant-free DLC showed that,
when it was tested in an atmosphere consisting of 50% oxygen and
45% moisture, a high COF of 0.6 observed during the running-in
against aluminum was eliminated compared to environment without
moisture. At elevated temperatures, presence of hydrogen reduced
the COF of H-DLC (e.g., to 0.06 at 200 °C). W-DLC
coatings provided
a low COF of 0.18 and minimized aluminum
adhesion at temperatures
ranging between 400 °C and 500 °C, which was attributed to the
formation of a tungsten oxide film. Additionally, DLC
coatings were
found to generate a low COF at subzero temperatures (-196 °C), with
W-DLC and H-DLC generating a COF of 0.18. The work of
adhesion (W
ad ) was determined using a nano-indentation pull-off force method.
In this way, insight was gained into the nature of atomic
interactions contributing to
tribological mechanisms at elevated
temperatures. The results showed that the
adhesion of the diamond
tip against all four samples tested (H-DLC, dopant-free DLC, W-DLC,
and aluminum) decreased with temperature. At 25 °C, no aluminum
adhesion was observed on the diamond tip, due to OH passivation of
the diamond surface in agreement with the low COF of 0.12 for the
dopant-free DLC coating. The elimination of meniscus forces due to
adsorbed water molecules on the sample surface was identified as an
important factor contributing to the
adhesion at room temperature.
The results also confirmed that the hydrogen in the H-DLC mitigated
interatomic interactions at the surface and reduced Wad to as low
as 0.01 J/m 2 at 200 °C. At 25 °C, there was no aluminum
adhesion
observed on the diamond tip, due to OH passivation of the diamond
surface in agreement with the low COF of 0.12 for the dopant-free
DLC coating.
Advisors/Committee Members: Alpas, Ahmet.
Subjects/Keywords: Applied sciences; Carbon coatings; Adhesion; Diamond like carbon; Friction; Wear; Engineering; Mechanical Engineering
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APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Abou Gharam, A. (2014). Tribological behaviour of H- and W-DLC coatings: Effects of
environment and temperature on adhesion. (Doctoral Dissertation). University of Windsor. Retrieved from http://scholar.uwindsor.ca/etd/5058
Chicago Manual of Style (16th Edition):
Abou Gharam, Ahmed. “Tribological behaviour of H- and W-DLC coatings: Effects of
environment and temperature on adhesion.” 2014. Doctoral Dissertation, University of Windsor. Accessed February 27, 2021.
http://scholar.uwindsor.ca/etd/5058.
MLA Handbook (7th Edition):
Abou Gharam, Ahmed. “Tribological behaviour of H- and W-DLC coatings: Effects of
environment and temperature on adhesion.” 2014. Web. 27 Feb 2021.
Vancouver:
Abou Gharam A. Tribological behaviour of H- and W-DLC coatings: Effects of
environment and temperature on adhesion. [Internet] [Doctoral dissertation]. University of Windsor; 2014. [cited 2021 Feb 27].
Available from: http://scholar.uwindsor.ca/etd/5058.
Council of Science Editors:
Abou Gharam A. Tribological behaviour of H- and W-DLC coatings: Effects of
environment and temperature on adhesion. [Doctoral Dissertation]. University of Windsor; 2014. Available from: http://scholar.uwindsor.ca/etd/5058

University of Akron
27.
Appleby, Matthew P.
High Temperature Damage Characterization Of Ceramic
Composites And Protective Coatings.
Degree: PhD, Mechanical Engineering, 2016, University of Akron
URL: http://rave.ohiolink.edu/etdc/view?acc_num=akron1461932405
► Novel high-temperature experiments were conducted in ordered to address some of the most critical life-limiting issues facing woven melt-infiltrated, silicon carbide (SiC) fiber-reinforced SiC ceramic…
(more)
▼ Novel high-temperature experiments were conducted in
ordered to address some of the most critical life-limiting issues
facing woven melt-infiltrated, silicon carbide (SiC)
fiber-reinforced SiC ceramic matrix composites (CMCs) as well as
protective thermal and environmental barrier
coatings (T/EBC).
Heating of specimens was achieved using laser-based approaches that
simulate the high heat-flux thermal gradient environments that
these materials will be subjected to in service. Specialized
non-destructive evaluation (NDE) and inspection techniques were
developed to investigate damage modes and material response. First,
in order to examine the capabilities of utilizing the emerging
technique of electrical
resistance (ER) measurement for use in high
temperature
mechanical testing in SiC/SiC CMCs, the temperature
dependent ER response of several systems was determined. A model
was developed to establish the contribution to overall ER from the
individual composite constituents and applied thermal gradient.
Then, elevated temperature tensile tests were performed to
characterize the damage of composite materials to localized stress
concentrations. Further experiments were done to assess the
differences in damage mechanisms and retained tensile strength
properties of uncoated SiC/SiC CMCs and EBC-CMC systems after
prolonged exposure to high pressure, high velocity water vapor
containing environments. Differences in damage modes were described
using ER monitoring and post-test inspection. Localized strain
fields were measured using a novel digital image correlation (DIC)
technique and stress-dependent matrix
crack accumulation was
monitored using in-situ modal acoustic emission (AE). Coupled AE
and thermography measurements were also used to describe failure of
protective ceramic
coatings due to the life-limiting case of
thermal cyclic loading. Due to the complex nature of T/EBC failure,
the decrease in coating life and durability due to thermal stress
concentrations and degradation via molten
calcium-magnesium-aluminosilicate (CMAS) infiltration was also
examined. Finally, the use of ER measurements for damage
characterization was extended to the complex case of creep and
stress-rupture of damaged and undamaged composites as well as the
dramatic increase in stress-rupture life to SiC/SiC CMCs from
environmental barrier
coatings. Post-test microscopy was performed
to further explain differences in material response and damage
morphology.
Advisors/Committee Members: Morscher, Gregory (Advisor).
Subjects/Keywords: Mechanical Engineering; ceramic matrix composites; environmental barrier coatings, thermal barrier
coatings; non-destructive evaluation; electrical resistance; acoustic emission; digital image correlation
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Appleby, M. P. (2016). High Temperature Damage Characterization Of Ceramic
Composites And Protective Coatings. (Doctoral Dissertation). University of Akron. Retrieved from http://rave.ohiolink.edu/etdc/view?acc_num=akron1461932405
Chicago Manual of Style (16th Edition):
Appleby, Matthew P. “High Temperature Damage Characterization Of Ceramic
Composites And Protective Coatings.” 2016. Doctoral Dissertation, University of Akron. Accessed February 27, 2021.
http://rave.ohiolink.edu/etdc/view?acc_num=akron1461932405.
MLA Handbook (7th Edition):
Appleby, Matthew P. “High Temperature Damage Characterization Of Ceramic
Composites And Protective Coatings.” 2016. Web. 27 Feb 2021.
Vancouver:
Appleby MP. High Temperature Damage Characterization Of Ceramic
Composites And Protective Coatings. [Internet] [Doctoral dissertation]. University of Akron; 2016. [cited 2021 Feb 27].
Available from: http://rave.ohiolink.edu/etdc/view?acc_num=akron1461932405.
Council of Science Editors:
Appleby MP. High Temperature Damage Characterization Of Ceramic
Composites And Protective Coatings. [Doctoral Dissertation]. University of Akron; 2016. Available from: http://rave.ohiolink.edu/etdc/view?acc_num=akron1461932405

Delft University of Technology
28.
Guerriero, G.L.
Liquid crystalline thermosetting polymers as protective coatings for aerospace.
Degree: 2012, Delft University of Technology
URL: http://resolver.tudelft.nl/uuid:e15e7cec-4355-43f0-9137-0b4608530eb4
;
urn:NBN:nl:ui:24-uuid:e15e7cec-4355-43f0-9137-0b4608530eb4
;
urn:NBN:nl:ui:24-uuid:e15e7cec-4355-43f0-9137-0b4608530eb4
;
http://resolver.tudelft.nl/uuid:e15e7cec-4355-43f0-9137-0b4608530eb4
► Environmental regulations are driving the development of new aerospace coating systems, mainly to eliminate chromates and reduce volatile organic compound (VOC) emissions. Among the various…
(more)
▼ Environmental regulations are driving the development of new aerospace coating systems, mainly to eliminate chromates and reduce volatile organic compound (VOC) emissions. Among the various potential options for new coating materials, liquid crystalline polymers (LCPs) are attractive due to their unique combination of
mechanical properties and chemical
resistance. Their use, however, has been limited mainly due to poor
adhesion properties. Thermotropic liquid crystalline thermosets displayed the
properties of traditional LCPs, while having the potential to overcome their disadvantages. The present research has been set to investigate the real potential of phenylethynyl terminated liquid crystalline thermosets (LCTs) for coating applications. The
coatings were initially manufactured by melt-pressing the LCT resins onto aluminum substrates. This method was selected mainly due to its simplicity and minimal powder requirements. As a first step, the effects of the thermal curing and the molecular weight of the coating resins were investigated. Then, the influence of temperature and molecular orientation were examined. Subsequently, the
adhesion and the environmental
resistance of the LCT
coatings were analyzed. Finally, the applicability of LCTs on aluminum and composite substrates using atmospheric plasma spraying (APS) was explored to address the industrial limitations of melt-pressing (on size, shape, and thermal
resistance of the substrate). Being the first approach to the use of these LCTs as
coatings, the present work has contributed to the knowledge and understanding of several aspects of the coating. The incorporation of the end-groups was found to promote the
adhesion of the coating compared to the thermoplastic Vectra®, while it did not affect the environmental
resistance. In addition, the new polymer chemistry allowed the polymers to be ground into a powder suitable for more versatile deposition methods like APS, expanding the range of applications. These LCTs, however, also present several disadvantages. An extra curing step at high temperature is required, during which, the
properties are not significantly improved. In addition, the LCTs investigated here become more brittle after curing, which can be a disadvantage for
tribological applications. Furthermore,
mechanical properties such as the elastic modulus are not significantly higher than those of the thermoplastic LCP; and the formation of aggregate-aggregate interfaces constitute paths for
crack propagation. Finally, untreated coating substrate interfaces constitute paths for environmental attack. The main characteristic of these
coatings appeared to be their high chemical
resistance and low permeability. These
coatings are, therefore, applicable for the protection of surfaces exposed to aggressive liquids or flowing gases. Examples include heat exchangers, gearbox housings, undercarriage components, flooring, and hatches. Since these
coatings constitute a passive protection, however, the development of a coating system that includes an active protection…
Advisors/Committee Members: Benedictus, R..
Subjects/Keywords: environmental resistance; atmospheric plasma spraying; liquid crystalline polymers; thermosets; coatings; mechanical properties
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Guerriero, G. L. (2012). Liquid crystalline thermosetting polymers as protective coatings for aerospace. (Doctoral Dissertation). Delft University of Technology. Retrieved from http://resolver.tudelft.nl/uuid:e15e7cec-4355-43f0-9137-0b4608530eb4 ; urn:NBN:nl:ui:24-uuid:e15e7cec-4355-43f0-9137-0b4608530eb4 ; urn:NBN:nl:ui:24-uuid:e15e7cec-4355-43f0-9137-0b4608530eb4 ; http://resolver.tudelft.nl/uuid:e15e7cec-4355-43f0-9137-0b4608530eb4
Chicago Manual of Style (16th Edition):
Guerriero, G L. “Liquid crystalline thermosetting polymers as protective coatings for aerospace.” 2012. Doctoral Dissertation, Delft University of Technology. Accessed February 27, 2021.
http://resolver.tudelft.nl/uuid:e15e7cec-4355-43f0-9137-0b4608530eb4 ; urn:NBN:nl:ui:24-uuid:e15e7cec-4355-43f0-9137-0b4608530eb4 ; urn:NBN:nl:ui:24-uuid:e15e7cec-4355-43f0-9137-0b4608530eb4 ; http://resolver.tudelft.nl/uuid:e15e7cec-4355-43f0-9137-0b4608530eb4.
MLA Handbook (7th Edition):
Guerriero, G L. “Liquid crystalline thermosetting polymers as protective coatings for aerospace.” 2012. Web. 27 Feb 2021.
Vancouver:
Guerriero GL. Liquid crystalline thermosetting polymers as protective coatings for aerospace. [Internet] [Doctoral dissertation]. Delft University of Technology; 2012. [cited 2021 Feb 27].
Available from: http://resolver.tudelft.nl/uuid:e15e7cec-4355-43f0-9137-0b4608530eb4 ; urn:NBN:nl:ui:24-uuid:e15e7cec-4355-43f0-9137-0b4608530eb4 ; urn:NBN:nl:ui:24-uuid:e15e7cec-4355-43f0-9137-0b4608530eb4 ; http://resolver.tudelft.nl/uuid:e15e7cec-4355-43f0-9137-0b4608530eb4.
Council of Science Editors:
Guerriero GL. Liquid crystalline thermosetting polymers as protective coatings for aerospace. [Doctoral Dissertation]. Delft University of Technology; 2012. Available from: http://resolver.tudelft.nl/uuid:e15e7cec-4355-43f0-9137-0b4608530eb4 ; urn:NBN:nl:ui:24-uuid:e15e7cec-4355-43f0-9137-0b4608530eb4 ; urn:NBN:nl:ui:24-uuid:e15e7cec-4355-43f0-9137-0b4608530eb4 ; http://resolver.tudelft.nl/uuid:e15e7cec-4355-43f0-9137-0b4608530eb4
29.
Mohammed, Yunus.
Investigations on the properties of industrial ceramic
coatings and characterization; -.
Degree: Mechanical Engineering, 2014, Anna University
URL: http://shodhganga.inflibnet.ac.in/handle/10603/26634
► Thermally sprayed ceramic coatings are more generally used on industrial components for meeting their functional requirements like high strength at elevated temperatures resistance to chemical…
(more)
▼ Thermally sprayed ceramic coatings are more
generally used on industrial components for meeting their
functional requirements like high strength at elevated temperatures
resistance to chemical degradation wear resistance and
environmental corrosion protection in Engineering components The
design of an engineering component which basically involves the
design of enveloping surface of the components are achieved with
some suitable modification techniques High Velocity Oxy Fuel and
Plasma spraying are more precise to achieve thinner coatings
without affecting substrate quality HVOF spraying process has been
used for thermal spraying of bonding material and plasma spraying
process is widely used for the deposition of films hard materials
such as ceramics on relatively softer substrate Before deciding on
a particular type of coating, it is necessary to look into
essential characteristics related to mechanical and tribological
properties in addition to their machinability characteristics for
control of surface quality of end products
-
Advisors/Committee Members: Ramesh, A.
Subjects/Keywords: Ceramic coatings; Mechanical engineering; Mechanical properties; Plasma spraying; Precision machining; Velocity oxy fuel
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Mohammed, Y. (2014). Investigations on the properties of industrial ceramic
coatings and characterization; -. (Thesis). Anna University. Retrieved from http://shodhganga.inflibnet.ac.in/handle/10603/26634
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Chicago Manual of Style (16th Edition):
Mohammed, Yunus. “Investigations on the properties of industrial ceramic
coatings and characterization; -.” 2014. Thesis, Anna University. Accessed February 27, 2021.
http://shodhganga.inflibnet.ac.in/handle/10603/26634.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
MLA Handbook (7th Edition):
Mohammed, Yunus. “Investigations on the properties of industrial ceramic
coatings and characterization; -.” 2014. Web. 27 Feb 2021.
Vancouver:
Mohammed Y. Investigations on the properties of industrial ceramic
coatings and characterization; -. [Internet] [Thesis]. Anna University; 2014. [cited 2021 Feb 27].
Available from: http://shodhganga.inflibnet.ac.in/handle/10603/26634.
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation
Council of Science Editors:
Mohammed Y. Investigations on the properties of industrial ceramic
coatings and characterization; -. [Thesis]. Anna University; 2014. Available from: http://shodhganga.inflibnet.ac.in/handle/10603/26634
Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

University of New Mexico
30.
Hutchins, Karen.
Measurement of Interfacial Adhesion in Glass-Epoxy Systems Using the Indentation Method.
Degree: Mechanical Engineering, 2015, University of New Mexico
URL: http://hdl.handle.net/1928/30342
► The adhesion of coatings often controls the performance of the substrate-coating system. Certain engineering applications require an epoxy coating on a brittle substrate to protect…
(more)
▼ The
adhesion of
coatings often controls the performance of the substrate-coating system. Certain engineering applications require an epoxy coating on a brittle substrate to protect and improve the performance of the substrate. Experimental observations and measurements of interfacial
adhesion in glass-epoxy systems are described in this thesis. A comparison study of how different glass treatments affect
adhesion was also conducted: smooth versus rough, clean versus unclean, stressed versus non-stressed. The Oliver and Pharr method was utilized to calculate the bulk epoxy hardness and elastic modulus. Spherical indentations were used to induce delaminations at the substrate-coating interface. The delamination sizes as a function of load were used to calculate the interfacial toughness. The interfacial fracture energy of my samples is an order of magnitude higher than a previous group who studied a similar glass-epoxy system.
Advisors/Committee Members: Khraishi, Tariq, Tehrani, Mehran, Tandon, Rajan.
Subjects/Keywords: Adhesion; Indentation; Glass; Epoxy; Interfaces; Bonding; Coatings
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❌
APA ·
Chicago ·
MLA ·
Vancouver ·
CSE |
Export
to Zotero / EndNote / Reference
Manager
APA (6th Edition):
Hutchins, K. (2015). Measurement of Interfacial Adhesion in Glass-Epoxy Systems Using the Indentation Method. (Masters Thesis). University of New Mexico. Retrieved from http://hdl.handle.net/1928/30342
Chicago Manual of Style (16th Edition):
Hutchins, Karen. “Measurement of Interfacial Adhesion in Glass-Epoxy Systems Using the Indentation Method.” 2015. Masters Thesis, University of New Mexico. Accessed February 27, 2021.
http://hdl.handle.net/1928/30342.
MLA Handbook (7th Edition):
Hutchins, Karen. “Measurement of Interfacial Adhesion in Glass-Epoxy Systems Using the Indentation Method.” 2015. Web. 27 Feb 2021.
Vancouver:
Hutchins K. Measurement of Interfacial Adhesion in Glass-Epoxy Systems Using the Indentation Method. [Internet] [Masters thesis]. University of New Mexico; 2015. [cited 2021 Feb 27].
Available from: http://hdl.handle.net/1928/30342.
Council of Science Editors:
Hutchins K. Measurement of Interfacial Adhesion in Glass-Epoxy Systems Using the Indentation Method. [Masters Thesis]. University of New Mexico; 2015. Available from: http://hdl.handle.net/1928/30342
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