subject:( Carbon Monoxide )

Virginia Commonwealth University

1. Newcomb, Alden. EVALUATION OF THE PHYSIOLOGICAL EFFECTS OF REDUCED HYDROXOCOBALAMIN ON ACUTE CARBON MONOXIDE TOXICITY.

Degree: MS, Physiology, 2014, Virginia Commonwealth University

URL: https://doi.org/10.25772/X93B-YF27 ; https://scholarscompass.vcu.edu/etd/3560

► Carbon monoxide (CO) poisoning represents a global health threat responsible for hundreds of thousands of hospital visits and tens of thousands of deaths annually.… (more)

Subjects/Keywords: carbon monoxide; carbon monoxide poisoning; Physiology

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APA (6^th Edition):

Newcomb, A. (2014). EVALUATION OF THE PHYSIOLOGICAL EFFECTS OF REDUCED HYDROXOCOBALAMIN ON ACUTE CARBON MONOXIDE TOXICITY. (Thesis). Virginia Commonwealth University. Retrieved from https://doi.org/10.25772/X93B-YF27 ; https://scholarscompass.vcu.edu/etd/3560

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Chicago Manual of Style (16^th Edition):

Newcomb, Alden. “EVALUATION OF THE PHYSIOLOGICAL EFFECTS OF REDUCED HYDROXOCOBALAMIN ON ACUTE CARBON MONOXIDE TOXICITY.” 2014. Thesis, Virginia Commonwealth University. Accessed March 06, 2021. https://doi.org/10.25772/X93B-YF27 ; https://scholarscompass.vcu.edu/etd/3560.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

MLA Handbook (7^th Edition):

Newcomb, Alden. “EVALUATION OF THE PHYSIOLOGICAL EFFECTS OF REDUCED HYDROXOCOBALAMIN ON ACUTE CARBON MONOXIDE TOXICITY.” 2014. Web. 06 Mar 2021.

Vancouver:

Newcomb A. EVALUATION OF THE PHYSIOLOGICAL EFFECTS OF REDUCED HYDROXOCOBALAMIN ON ACUTE CARBON MONOXIDE TOXICITY. [Internet] [Thesis]. Virginia Commonwealth University; 2014. [cited 2021 Mar 06]. Available from: https://doi.org/10.25772/X93B-YF27 ; https://scholarscompass.vcu.edu/etd/3560.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Council of Science Editors:

Newcomb A. EVALUATION OF THE PHYSIOLOGICAL EFFECTS OF REDUCED HYDROXOCOBALAMIN ON ACUTE CARBON MONOXIDE TOXICITY. [Thesis]. Virginia Commonwealth University; 2014. Available from: https://doi.org/10.25772/X93B-YF27 ; https://scholarscompass.vcu.edu/etd/3560

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

University of Utah

2. Poulson, Tyler R. Carbon emissions reduction strategies for Utah households operating under a budget constraint.

Degree: MS;, Economics;, 2009, University of Utah

URL: http://content.lib.utah.edu/cdm/singleitem/collection/etd2/id/1946/rec/177

► This thesis presents actions that households can take to reduce carbon dioxide emissions associated with day-to-day activities. Average annual estimates of the carbon output associated… (more)

Subjects/Keywords: Carbon monoxide mitigation

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APA (6^th Edition):

Poulson, T. R. (2009). Carbon emissions reduction strategies for Utah households operating under a budget constraint. (Masters Thesis). University of Utah. Retrieved from http://content.lib.utah.edu/cdm/singleitem/collection/etd2/id/1946/rec/177

Chicago Manual of Style (16^th Edition):

Poulson, Tyler R. “Carbon emissions reduction strategies for Utah households operating under a budget constraint.” 2009. Masters Thesis, University of Utah. Accessed March 06, 2021. http://content.lib.utah.edu/cdm/singleitem/collection/etd2/id/1946/rec/177.

MLA Handbook (7^th Edition):

Poulson, Tyler R. “Carbon emissions reduction strategies for Utah households operating under a budget constraint.” 2009. Web. 06 Mar 2021.

Vancouver:

Poulson TR. Carbon emissions reduction strategies for Utah households operating under a budget constraint. [Internet] [Masters thesis]. University of Utah; 2009. [cited 2021 Mar 06]. Available from: http://content.lib.utah.edu/cdm/singleitem/collection/etd2/id/1946/rec/177.

Council of Science Editors:

Poulson TR. Carbon emissions reduction strategies for Utah households operating under a budget constraint. [Masters Thesis]. University of Utah; 2009. Available from: http://content.lib.utah.edu/cdm/singleitem/collection/etd2/id/1946/rec/177

Oregon State University

3. Jones, Walter Denny. Vibrational relaxation time studies on carbon monoxide by the infrared spectrophone method.

Degree: PhD, Chemistry, 1957, Oregon State University

URL: http://hdl.handle.net/1957/51075

Subjects/Keywords: Carbon monoxide

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APA (6^th Edition):

Jones, W. D. (1957). Vibrational relaxation time studies on carbon monoxide by the infrared spectrophone method. (Doctoral Dissertation). Oregon State University. Retrieved from http://hdl.handle.net/1957/51075

Chicago Manual of Style (16^th Edition):

Jones, Walter Denny. “Vibrational relaxation time studies on carbon monoxide by the infrared spectrophone method.” 1957. Doctoral Dissertation, Oregon State University. Accessed March 06, 2021. http://hdl.handle.net/1957/51075.

MLA Handbook (7^th Edition):

Jones, Walter Denny. “Vibrational relaxation time studies on carbon monoxide by the infrared spectrophone method.” 1957. Web. 06 Mar 2021.

Vancouver:

Jones WD. Vibrational relaxation time studies on carbon monoxide by the infrared spectrophone method. [Internet] [Doctoral dissertation]. Oregon State University; 1957. [cited 2021 Mar 06]. Available from: http://hdl.handle.net/1957/51075.

Council of Science Editors:

Jones WD. Vibrational relaxation time studies on carbon monoxide by the infrared spectrophone method. [Doctoral Dissertation]. Oregon State University; 1957. Available from: http://hdl.handle.net/1957/51075

Oregon State University

4. Turrell, George Charles. Determination of the vibrational lifetime of carbon monoxide by the spectrophone method.

Degree: PhD, Chemistry, 1954, Oregon State University

URL: http://hdl.handle.net/1957/51044

Subjects/Keywords: Carbon monoxide

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APA (6^th Edition):

Turrell, G. C. (1954). Determination of the vibrational lifetime of carbon monoxide by the spectrophone method. (Doctoral Dissertation). Oregon State University. Retrieved from http://hdl.handle.net/1957/51044

Chicago Manual of Style (16^th Edition):

Turrell, George Charles. “Determination of the vibrational lifetime of carbon monoxide by the spectrophone method.” 1954. Doctoral Dissertation, Oregon State University. Accessed March 06, 2021. http://hdl.handle.net/1957/51044.

MLA Handbook (7^th Edition):

Turrell, George Charles. “Determination of the vibrational lifetime of carbon monoxide by the spectrophone method.” 1954. Web. 06 Mar 2021.

Vancouver:

Turrell GC. Determination of the vibrational lifetime of carbon monoxide by the spectrophone method. [Internet] [Doctoral dissertation]. Oregon State University; 1954. [cited 2021 Mar 06]. Available from: http://hdl.handle.net/1957/51044.

Council of Science Editors:

Turrell GC. Determination of the vibrational lifetime of carbon monoxide by the spectrophone method. [Doctoral Dissertation]. Oregon State University; 1954. Available from: http://hdl.handle.net/1957/51044

Oregon State University

5. Woodmansee, Wayne Earl. A variable frequency spectrophone study of carbon monoxide.

Degree: PhD, Chemistry, 1960, Oregon State University

URL: http://hdl.handle.net/1957/49282

Subjects/Keywords: Carbon monoxide

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APA (6^th Edition):

Woodmansee, W. E. (1960). A variable frequency spectrophone study of carbon monoxide. (Doctoral Dissertation). Oregon State University. Retrieved from http://hdl.handle.net/1957/49282

Chicago Manual of Style (16^th Edition):

Woodmansee, Wayne Earl. “A variable frequency spectrophone study of carbon monoxide.” 1960. Doctoral Dissertation, Oregon State University. Accessed March 06, 2021. http://hdl.handle.net/1957/49282.

MLA Handbook (7^th Edition):

Woodmansee, Wayne Earl. “A variable frequency spectrophone study of carbon monoxide.” 1960. Web. 06 Mar 2021.

Vancouver:

Woodmansee WE. A variable frequency spectrophone study of carbon monoxide. [Internet] [Doctoral dissertation]. Oregon State University; 1960. [cited 2021 Mar 06]. Available from: http://hdl.handle.net/1957/49282.

Council of Science Editors:

Woodmansee WE. A variable frequency spectrophone study of carbon monoxide. [Doctoral Dissertation]. Oregon State University; 1960. Available from: http://hdl.handle.net/1957/49282

Oregon State University

6. Redden, George Dean. Characteristics of photochemical production of carbon monoxide in seawater.

Degree: MS, Oceanography, 1982, Oregon State University

URL: http://hdl.handle.net/1957/27813

Subjects/Keywords: Carbon monoxide

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APA (6^th Edition):

Redden, G. D. (1982). Characteristics of photochemical production of carbon monoxide in seawater. (Masters Thesis). Oregon State University. Retrieved from http://hdl.handle.net/1957/27813

Chicago Manual of Style (16^th Edition):

Redden, George Dean. “Characteristics of photochemical production of carbon monoxide in seawater.” 1982. Masters Thesis, Oregon State University. Accessed March 06, 2021. http://hdl.handle.net/1957/27813.

MLA Handbook (7^th Edition):

Redden, George Dean. “Characteristics of photochemical production of carbon monoxide in seawater.” 1982. Web. 06 Mar 2021.

Vancouver:

Redden GD. Characteristics of photochemical production of carbon monoxide in seawater. [Internet] [Masters thesis]. Oregon State University; 1982. [cited 2021 Mar 06]. Available from: http://hdl.handle.net/1957/27813.

Council of Science Editors:

Redden GD. Characteristics of photochemical production of carbon monoxide in seawater. [Masters Thesis]. Oregon State University; 1982. Available from: http://hdl.handle.net/1957/27813

University of Toronto

7. Marchand, Michael. Multi-dimensional Carbon Monoxide Emissions Predictor For Preliminary Gas Turbine Combustor Design Optimization.

Degree: 2013, University of Toronto

URL: http://hdl.handle.net/1807/69796

►

The objective of this thesis was to compare the predictive capabilities of a new proposed reactor network methodology, to past methods in an attempt to… (more)

Subjects/Keywords: Emissions; Combustion; Carbon Monoxide; 0538

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APA (6^th Edition):

Marchand, M. (2013). Multi-dimensional Carbon Monoxide Emissions Predictor For Preliminary Gas Turbine Combustor Design Optimization. (Masters Thesis). University of Toronto. Retrieved from http://hdl.handle.net/1807/69796

Chicago Manual of Style (16^th Edition):

Marchand, Michael. “Multi-dimensional Carbon Monoxide Emissions Predictor For Preliminary Gas Turbine Combustor Design Optimization.” 2013. Masters Thesis, University of Toronto. Accessed March 06, 2021. http://hdl.handle.net/1807/69796.

MLA Handbook (7^th Edition):

Marchand, Michael. “Multi-dimensional Carbon Monoxide Emissions Predictor For Preliminary Gas Turbine Combustor Design Optimization.” 2013. Web. 06 Mar 2021.

Vancouver:

Marchand M. Multi-dimensional Carbon Monoxide Emissions Predictor For Preliminary Gas Turbine Combustor Design Optimization. [Internet] [Masters thesis]. University of Toronto; 2013. [cited 2021 Mar 06]. Available from: http://hdl.handle.net/1807/69796.

Council of Science Editors:

Marchand M. Multi-dimensional Carbon Monoxide Emissions Predictor For Preliminary Gas Turbine Combustor Design Optimization. [Masters Thesis]. University of Toronto; 2013. Available from: http://hdl.handle.net/1807/69796

University of Otago

8. Cho, Kyulee. Synthesis of Organic Carbon Monoxide Releasing Molecules and their application in Palladium-catalysed Aminocarbonylation .

Degree: 2013, University of Otago

URL: http://hdl.handle.net/10523/4487

This thesis describes research carried out towards the synthesis of organic carbon monoxide releasing molecules (CORMs). Analyses of their ability to release carbon monoxide (CO) and to be employed in palladium-catalysed aminocarbonylation reactions are also reported. Advisors/Committee Members: Larsen, David (advisor).

Subjects/Keywords: Carbon; Monoxide; Releasing; Molecule

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APA (6^th Edition):

Cho, K. (2013). Synthesis of Organic Carbon Monoxide Releasing Molecules and their application in Palladium-catalysed Aminocarbonylation . (Masters Thesis). University of Otago. Retrieved from http://hdl.handle.net/10523/4487

Chicago Manual of Style (16^th Edition):

Cho, Kyulee. “Synthesis of Organic Carbon Monoxide Releasing Molecules and their application in Palladium-catalysed Aminocarbonylation .” 2013. Masters Thesis, University of Otago. Accessed March 06, 2021. http://hdl.handle.net/10523/4487.

MLA Handbook (7^th Edition):

Cho, Kyulee. “Synthesis of Organic Carbon Monoxide Releasing Molecules and their application in Palladium-catalysed Aminocarbonylation .” 2013. Web. 06 Mar 2021.

Vancouver:

Cho K. Synthesis of Organic Carbon Monoxide Releasing Molecules and their application in Palladium-catalysed Aminocarbonylation . [Internet] [Masters thesis]. University of Otago; 2013. [cited 2021 Mar 06]. Available from: http://hdl.handle.net/10523/4487.

Council of Science Editors:

Cho K. Synthesis of Organic Carbon Monoxide Releasing Molecules and their application in Palladium-catalysed Aminocarbonylation . [Masters Thesis]. University of Otago; 2013. Available from: http://hdl.handle.net/10523/4487

9. Kettle, A. James. A model of the temporal and spatial distribution of carbon monoxide in the mixed layer.

Degree: 1994, MIT and Woods Hole Oceanographic Institution

URL: http://hdl.handle.net/1912/8851

► A field experiment demonstrated the presence of a diurnal cycle in the concentration of carbon monoxide ([CO]) in the upper ocean at the BATS site.… (more)

Subjects/Keywords: Carbon monoxide

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APA (6^th Edition):

Kettle, A. J. (1994). A model of the temporal and spatial distribution of carbon monoxide in the mixed layer. (Thesis). MIT and Woods Hole Oceanographic Institution. Retrieved from http://hdl.handle.net/1912/8851

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Chicago Manual of Style (16^th Edition):

Kettle, A James. “A model of the temporal and spatial distribution of carbon monoxide in the mixed layer.” 1994. Thesis, MIT and Woods Hole Oceanographic Institution. Accessed March 06, 2021. http://hdl.handle.net/1912/8851.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

MLA Handbook (7^th Edition):

Kettle, A James. “A model of the temporal and spatial distribution of carbon monoxide in the mixed layer.” 1994. Web. 06 Mar 2021.

Vancouver:

Kettle AJ. A model of the temporal and spatial distribution of carbon monoxide in the mixed layer. [Internet] [Thesis]. MIT and Woods Hole Oceanographic Institution; 1994. [cited 2021 Mar 06]. Available from: http://hdl.handle.net/1912/8851.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Council of Science Editors:

Kettle AJ. A model of the temporal and spatial distribution of carbon monoxide in the mixed layer. [Thesis]. MIT and Woods Hole Oceanographic Institution; 1994. Available from: http://hdl.handle.net/1912/8851

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

University of Illinois – Urbana-Champaign

10. Liu, Liang. Historical anthropogenic emissions of carbon monoxide, 1850 - 2000.

Degree: MS, 0231, 2013, University of Illinois – Urbana-Champaign

URL: http://hdl.handle.net/2142/42474

► We present a bottom-up emission inventory of carbon monoxide (CO) from fossil fuel and biofuel combustion from 1850 to 2000. We reconstruct fuel consumption data… (more)

Subjects/Keywords: carbon monoxide; emission inventory; technology

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APA (6^th Edition):

Liu, L. (2013). Historical anthropogenic emissions of carbon monoxide, 1850 - 2000. (Thesis). University of Illinois – Urbana-Champaign. Retrieved from http://hdl.handle.net/2142/42474

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Chicago Manual of Style (16^th Edition):

Liu, Liang. “Historical anthropogenic emissions of carbon monoxide, 1850 - 2000.” 2013. Thesis, University of Illinois – Urbana-Champaign. Accessed March 06, 2021. http://hdl.handle.net/2142/42474.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

MLA Handbook (7^th Edition):

Liu, Liang. “Historical anthropogenic emissions of carbon monoxide, 1850 - 2000.” 2013. Web. 06 Mar 2021.

Vancouver:

Liu L. Historical anthropogenic emissions of carbon monoxide, 1850 - 2000. [Internet] [Thesis]. University of Illinois – Urbana-Champaign; 2013. [cited 2021 Mar 06]. Available from: http://hdl.handle.net/2142/42474.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Council of Science Editors:

Liu L. Historical anthropogenic emissions of carbon monoxide, 1850 - 2000. [Thesis]. University of Illinois – Urbana-Champaign; 2013. Available from: http://hdl.handle.net/2142/42474

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Utah State University

11. Esquer Heredia, Hector Jose. Toxicity and Mitochondrial Delivery of Flavonol-Based Carbon Monoxide-Releasing Molecules.

Degree: MS, Animal, Dairy, and Veterinary Sciences, 2017, Utah State University

URL: https://digitalcommons.usu.edu/etd/6882

► Despite the reputation of carbon monoxide (CO) as a silent killer, new evidence suggests that this gaseous molecule has anti-inflammatory, anti-cancer and vasoprotective properties.… (more)

▼ Despite the reputation of carbon monoxide (CO) as a silent killer, new evidence suggests that this gaseous molecule has anti-inflammatory, anti-cancer and vasoprotective properties. Unfortunately, little is known about the role of CO in the body. However, proteins present in mitochondria are believed to be important targets. We previously synthesized a class of novel and structurally modifiable flavonol-based CO-releasing molecules (CORMs). Flavonols are commonly found in fruits and vegetables. The base structure, Flav-1, is fluorescent, exhibits low toxicity, and releases CO after exposure to visible light. Previous reports indicate that addition of a triphenylphosphonium (TPP) tail allows chemical structures to enter mitochondria. We hypothesized that addition of a TPP tail of two or eight carbons in length to Flav-1 (Mito-Flav-C2 or -C8) would facilitate targeting of mitochondria, and thus, localized light-induced CO release. Toxicity of these TPP-tailed molecules was determined in human umbilical vein endothelial cells (HUVECs) and lung epithelial carcinoma cells (A549), using standard cell viability assays. Evaluation of toxicity using the MTT assay revealed lower toxicity of Flav-1 in HUVECs compared to A549 cells, but addition of the TPP tails increased toxicity in both cell lines. However, unlike the MTT assay, Flav-1 with and without tails had similar toxicity when measured in HUVECs by the lactate dehydrogenase assay. Photo-degradation experiments were performed by exposing cells until their light emission was undetectable by using lasers in the near-UV and within the visible light spectrum. Localization of the compounds was observed using a confocal microscope by co-staining with MitoTracker Red (MTR) and Hoechst to visualize the mitochondria and nucleus, respectively. Fluorescence microscopy images of cells treated with Mito-Flav-C2 or -C8 revealed an increase in uptake, compared to Flav-1, plus co-localization with MTR, which suggests mitochondrial localization. A549 cells exposed to laser light or a full spectrum of light lost all fluorescence of Mito-Flav-C2, which indicates CO release. This work highlights the successful synthesis of the first mitochondria targeting CORMs, and that CO release is achievable using different light sources. Moreover, these TPP-tailed CORMs will allow for controlled and localized release of CO to further study its physiological targets. Advisors/Committee Members: Abby D. Benninghoff, ;.

Subjects/Keywords: carbon monoxide; cytotoxicity; mitochondria; carbon monoxide-releasing molecule; molecular tool; Toxicology

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APA (6^th Edition):

Esquer Heredia, H. J. (2017). Toxicity and Mitochondrial Delivery of Flavonol-Based Carbon Monoxide-Releasing Molecules. (Masters Thesis). Utah State University. Retrieved from https://digitalcommons.usu.edu/etd/6882

Chicago Manual of Style (16^th Edition):

Esquer Heredia, Hector Jose. “Toxicity and Mitochondrial Delivery of Flavonol-Based Carbon Monoxide-Releasing Molecules.” 2017. Masters Thesis, Utah State University. Accessed March 06, 2021. https://digitalcommons.usu.edu/etd/6882.

MLA Handbook (7^th Edition):

Esquer Heredia, Hector Jose. “Toxicity and Mitochondrial Delivery of Flavonol-Based Carbon Monoxide-Releasing Molecules.” 2017. Web. 06 Mar 2021.

Vancouver:

Esquer Heredia HJ. Toxicity and Mitochondrial Delivery of Flavonol-Based Carbon Monoxide-Releasing Molecules. [Internet] [Masters thesis]. Utah State University; 2017. [cited 2021 Mar 06]. Available from: https://digitalcommons.usu.edu/etd/6882.

Council of Science Editors:

Esquer Heredia HJ. Toxicity and Mitochondrial Delivery of Flavonol-Based Carbon Monoxide-Releasing Molecules. [Masters Thesis]. Utah State University; 2017. Available from: https://digitalcommons.usu.edu/etd/6882

12. Patel Femina. Synthesis and Characterization of Perovskite based Catalysts for Automotive CO Oxidation;.

Degree: 2014, Nirma University

URL: http://shodhganga.inflibnet.ac.in/handle/10603/28247

►

Air pollution generated from automobiles has been a burning issue because of poisonous gases like carbon monoxide (CO), unburned hydrocarbons (HC), nitrogen oxides (NOx) and… (more)

Subjects/Keywords: air pollution; carbon monoxide; hydro carbon

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APA (6^th Edition):

Femina, P. (2014). Synthesis and Characterization of Perovskite based Catalysts for Automotive CO Oxidation;. (Thesis). Nirma University. Retrieved from http://shodhganga.inflibnet.ac.in/handle/10603/28247

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Chicago Manual of Style (16^th Edition):

Femina, Patel. “Synthesis and Characterization of Perovskite based Catalysts for Automotive CO Oxidation;.” 2014. Thesis, Nirma University. Accessed March 06, 2021. http://shodhganga.inflibnet.ac.in/handle/10603/28247.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

MLA Handbook (7^th Edition):

Femina, Patel. “Synthesis and Characterization of Perovskite based Catalysts for Automotive CO Oxidation;.” 2014. Web. 06 Mar 2021.

Vancouver:

Femina P. Synthesis and Characterization of Perovskite based Catalysts for Automotive CO Oxidation;. [Internet] [Thesis]. Nirma University; 2014. [cited 2021 Mar 06]. Available from: http://shodhganga.inflibnet.ac.in/handle/10603/28247.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Council of Science Editors:

Femina P. Synthesis and Characterization of Perovskite based Catalysts for Automotive CO Oxidation;. [Thesis]. Nirma University; 2014. Available from: http://shodhganga.inflibnet.ac.in/handle/10603/28247

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Delft University of Technology

13. Goos, Niels (author). Electrochemical reduction of CO2 to CO in a flow-through electrolyser.

Degree: 2020, Delft University of Technology

URL: http://resolver.tudelft.nl/uuid:ba0249a6-d55e-4445-82d3-e22521b17319

► Electrochemical reduction of the \ce{CO2} into the chemically valuable \ce{CO} at an industrial scale is a promising way to reverse the worrying rise of \ce{CO2}… (more)

▼ Electrochemical reduction of the \ce{CO2} into the chemically valuable \ce{CO} at an industrial scale is a promising way to reverse the worrying rise of \ce{CO2} levels in the atmosphere. Profitable operation at an industrial scale requires high CO partial current densities, producing a CO-rich output, while keeping the energy consumption and the price of the electrolyser low. Conventional \ce{CO2} reduction (\ce{CO2}R) to CO electrolysers suffer from the competing hydrogen evolution (HEV) reaction and mass transport limitations. Therefore, they can produce a maximum CO partial current densities of 20 mA cm^-2. The current densities can be increased by working at higher pressures or using gas diffusion electrodes, but to date, both require high energy inputs. Therefore, we investigated the potential of using a flow-through electrolyser (FTE) to produce \ce{CO} partial current densities exceeding the 20 mA cm^-2, while keeping the potential attractive. Porous flow-through electrodes can overcome mass transport limitations by their large reactive surface area and their ability to decrease the diffusion boundary layer thickness. To obtain suitable porous electrodes, we electrodeposited Ag on microporous Ti substrates. We used an aqueous \ce{CO2}-saturated \ce{KHCO₃} solution, as a well-proven electrolyte for \ce{CO2}R to \ce{CO} on a Ag catalyst. Our FTE was capable of overcoming the mass transport limitations. In a one-off test, it produced a \ce{CO} partial current density of 100 mA cm^-2, at a Faradaic efficiency (FE) of 55 %. We could reproduce \ce{CO} partial current densities of 60 mA cm^-2 at a FE of 25 % in a 0.05 M \ce{KHCO₃} solution. We experienced a decrease in activity towards CO when using more concentrated electrolytes. However, high cell potentials of more than 5 V, were required to exceed \ce{CO} partial current densities of 20 mA cm^-2. The required high potentials can be ascribed to ohmic losses and low selectivities towards CO. We believe that the insufficient deposition of the Ag on the microporous Ti electrode was the main reason for the low selectivity. Implementing the improvements, that are mentioned in the report, could contribute to make the FTE a promising candidate to reduce \ce{CO2} to CO at an industrial scale effectively. Advisors/Committee Members: Haverkort, Willem (mentor), de Jong, Wiebren (graduation committee), Vermaas, David (graduation committee), Delft University of Technology (degree granting institution).

Subjects/Keywords: Carbon dioxide reduction to carbon monoxide

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APA (6^th Edition):

Goos, N. (. (2020). Electrochemical reduction of CO2 to CO in a flow-through electrolyser. (Masters Thesis). Delft University of Technology. Retrieved from http://resolver.tudelft.nl/uuid:ba0249a6-d55e-4445-82d3-e22521b17319

Chicago Manual of Style (16^th Edition):

Goos, Niels (author). “Electrochemical reduction of CO2 to CO in a flow-through electrolyser.” 2020. Masters Thesis, Delft University of Technology. Accessed March 06, 2021. http://resolver.tudelft.nl/uuid:ba0249a6-d55e-4445-82d3-e22521b17319.

MLA Handbook (7^th Edition):

Goos, Niels (author). “Electrochemical reduction of CO2 to CO in a flow-through electrolyser.” 2020. Web. 06 Mar 2021.

Vancouver:

Goos N(. Electrochemical reduction of CO2 to CO in a flow-through electrolyser. [Internet] [Masters thesis]. Delft University of Technology; 2020. [cited 2021 Mar 06]. Available from: http://resolver.tudelft.nl/uuid:ba0249a6-d55e-4445-82d3-e22521b17319.

Council of Science Editors:

Goos N(. Electrochemical reduction of CO2 to CO in a flow-through electrolyser. [Masters Thesis]. Delft University of Technology; 2020. Available from: http://resolver.tudelft.nl/uuid:ba0249a6-d55e-4445-82d3-e22521b17319

University of Utah

14. Graehl, Tyson David. Development of an airborne pollution measurement system.

Degree: MS, Mechanical Engineering, 2011, University of Utah

URL: http://content.lib.utah.edu/cdm/singleitem/collection/etd3/id/272/rec/707

► The Sky-scan Atmospheric Monitoring Instrument (SAMI) consists of a low pro-fi le, autonomous unmanned aerial vehicle (UAV) that provides a platform for remotely sampling airborne… (more)

Subjects/Keywords: Aiborne; Carbon monoxide; Pollution; Sensing; UAV

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APA (6^th Edition):

Graehl, T. D. (2011). Development of an airborne pollution measurement system. (Masters Thesis). University of Utah. Retrieved from http://content.lib.utah.edu/cdm/singleitem/collection/etd3/id/272/rec/707

Chicago Manual of Style (16^th Edition):

Graehl, Tyson David. “Development of an airborne pollution measurement system.” 2011. Masters Thesis, University of Utah. Accessed March 06, 2021. http://content.lib.utah.edu/cdm/singleitem/collection/etd3/id/272/rec/707.

MLA Handbook (7^th Edition):

Graehl, Tyson David. “Development of an airborne pollution measurement system.” 2011. Web. 06 Mar 2021.

Vancouver:

Graehl TD. Development of an airborne pollution measurement system. [Internet] [Masters thesis]. University of Utah; 2011. [cited 2021 Mar 06]. Available from: http://content.lib.utah.edu/cdm/singleitem/collection/etd3/id/272/rec/707.

Council of Science Editors:

Graehl TD. Development of an airborne pollution measurement system. [Masters Thesis]. University of Utah; 2011. Available from: http://content.lib.utah.edu/cdm/singleitem/collection/etd3/id/272/rec/707

University of California – Riverside

15. Dingwall, Stephanie. Spectroscopic and Mechanistic Studies of the Mo/Cu Carbon Monoxide Dehydrogenase From Oligotropha carboxidovorans.

Degree: Biochemistry and Molecular Biology, 2016, University of California – Riverside

URL: http://www.escholarship.org/uc/item/55d0k225

► The molybdenum- and copper-containing enzyme carbon monoxide dehydrogenase from Oligotropha carboxidovorans catalyzes the oxidation of carbon monoxide to carbon dioxide, bioremediating about 400 million tons… (more)

▼ The molybdenum- and copper-containing enzyme carbon monoxide dehydrogenase from Oligotropha carboxidovorans catalyzes the oxidation of carbon monoxide to carbon dioxide, bioremediating about 400 million tons of CO from the atmosphere annually. During catalysis, the substrate is oxidized at a binuclear metal center containing Mo and Cu, with electrons passed via two [2Fe-2S] clusters to a FAD cofactor before ultimately being transferred to the quinone pool of the electron transport chain. Our studies have examined different aspects of catalysis, from the nature of the electron flow through the system to an examination of the binuclear center during enzyme turnover.First, we have identified the formation of the FADH● semiquinone species during catalysis. This is the first confirmed appearance of the neutral radical species in CO dehydrogenase, revealed from enzyme-monitored turnover, quench flow, and reductive titration experiments.Next, we have determined that pH effects in CO dehydrogenase are unique to the enzyme and associated with its FAD. pH jump and reductive titration experiments at pH 6 and 10 reveal pH-dependent UV/visible spectra. Upon covalent modification of the flavin by diphenyliodonium chloride, which leads to its covalent modification and inactivation at the FAD, spectral differences at the two pH extremes are abolished. Similar experiments involving xanthine oxidase and xanthine dehydrogenase show no pH-dependent spectral differences, implying that the pH effects are unique to CO dehydrogenase.Lastly, electron nuclear double resonance (ENDOR) experiments have been performed to further characterize the binuclear center of the partially-reduced enzyme. ENDOR data of 12C and 13C bicarbonate-bound enzyme reveal that bicarbonate is bound to the copper, rather than the molybdenum of the binuclear center, and so is unlikely to be an intermediate during catalysis. Analysis of 16O and 17O Mims ENDOR indicate that the equatorial ligand in the molybdenum coordination sphere is not a Mo=O but Mo-OH, and is catalytically-labile, being incorporated into the product CO2 and regenerated from solvent in the course of each catalytic sequence.

Subjects/Keywords: Biochemistry; carbon monoxide dehydrogenase; CO dehydrogenase; molybdenum

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APA (6^th Edition):

Dingwall, S. (2016). Spectroscopic and Mechanistic Studies of the Mo/Cu Carbon Monoxide Dehydrogenase From Oligotropha carboxidovorans. (Thesis). University of California – Riverside. Retrieved from http://www.escholarship.org/uc/item/55d0k225

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Chicago Manual of Style (16^th Edition):

Dingwall, Stephanie. “Spectroscopic and Mechanistic Studies of the Mo/Cu Carbon Monoxide Dehydrogenase From Oligotropha carboxidovorans.” 2016. Thesis, University of California – Riverside. Accessed March 06, 2021. http://www.escholarship.org/uc/item/55d0k225.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

MLA Handbook (7^th Edition):

Dingwall, Stephanie. “Spectroscopic and Mechanistic Studies of the Mo/Cu Carbon Monoxide Dehydrogenase From Oligotropha carboxidovorans.” 2016. Web. 06 Mar 2021.

Vancouver:

Dingwall S. Spectroscopic and Mechanistic Studies of the Mo/Cu Carbon Monoxide Dehydrogenase From Oligotropha carboxidovorans. [Internet] [Thesis]. University of California – Riverside; 2016. [cited 2021 Mar 06]. Available from: http://www.escholarship.org/uc/item/55d0k225.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Council of Science Editors:

Dingwall S. Spectroscopic and Mechanistic Studies of the Mo/Cu Carbon Monoxide Dehydrogenase From Oligotropha carboxidovorans. [Thesis]. University of California – Riverside; 2016. Available from: http://www.escholarship.org/uc/item/55d0k225

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

University of Rochester

16. Kovach, James. Electrophilic C-H activation using a Shilov-inspired rhodium diimine complex.

Degree: PhD, 2015, University of Rochester

URL: http://hdl.handle.net/1802/29250

► The objective for the work presented in this thesis was to develop a transition metal-based system to catalyze the partial oxidation of methane to methanol… (more)

▼ The objective for the work presented in this thesis was to develop a transition metal-based system to catalyze the partial oxidation of methane to methanol using dioxygen as the oxidant. The strategy was to combine the fundamental characteristics of the Shilov system, α-diimine ligands relevant to C-H activation, and rhodium or iridium transition metal centers to approach this goal. Several new imines, imine-related bisindolines, and M(α-diimine) (M = Rh, Ir) complexes were synthesized and characterized during this study, which ultimately lead to development of an air and water stable C-H activation transition metal catalyst. </br> Work began with the synthesis of iridium(I) complexes of the type IrI(α-diimine-Ar)X(olefin) (α-diimine-Ar = 1,4-bis(Ar)-2,3-dimethyl-1,4-diaza-1,3-butadiene, Ar = 2,6-dimethylphenyl; X = Cl, I, Me; olefin = ethylene, cis-cyclooctene (COE)) from [Ir^ICl(COE)]₂. The next iteration of complexes were synthesized by treatment of Rh^I(acetoacetonate)(CO)₂ with perchloric acid followed by addition of α-diimine-Ar (Ar = 3,5-dimethylphenyl, 3,5-di-tert-butylphenyl, 3,4,5-trimethoxyphenyl, phenyl, and 4-chlorophenyl) to generate a series of complexes of the type [Rh^I(α-diimine-Ar)(CO)₂][ClO₄]. </br> Two tangential works stemmed from the IrI(α-diimine-Ar)X(olefin) and [Rh^I(α-diimine-Ar)(CO)₂][ClO₄] chemistries. The first was the synthesis and full characterization of α-diimine-Ar (Ar = 2,5-di-tert-butylphenyl) and α-iminoketones 2-[(3,5-dimethylphenyl)imino]acenaphthylen-1-one and 2-[(4-chlorophenyl)imino]acenaphthylen-1-one. The α-iminoketones displayed fluxional behavior in solution, observed with variable temperature ¹H NMR spectroscopy, which was attributed to isomerization between the E and Z form of the imine. We also reported the previously unknown X-ray crystal structures of α-diimines bis(Arimino)acenaphthene (Ar = 3,5-dimethylphenyl, 4-chlorophenyl) and α-iminoketone 2-[(2,6-dimethylphenyl)imino]acenaphthylen-1-one. </br> The second tangential work consisted of the reaction of 3,5-dimethoxyaniline with vicinal diones (2,3-butanedione, benzil, and 4-methylbenzil) producing bisindolines, indolinones, or α-iminoketones depending on the reaction conditions. We proposed the mechanism of bisindoline and indolinone formation to include a Friedel-Crafts type electrophilic attack on the electron rich aryl ring at the ring closing C-C bond forming steps, and further proposed a common carbocationic monocyclized intermediate. </br> Four new air and water stable, organometallic rhodium(III) complexes trans-Rh^III(α-diimine-Ar)(CO)I₂Me, [Rh^III(α-diimine-Ar)(C(O)Me)(H₂O)₃][BF₄]₂, [Rh^III(α-diimine-Ar)Me(H₂O)₃][BF₄]₂, and Rh^III(α-diimine-Ar)(C(O)Me)(H₂O)(OC(O)CF₃)₂ (Ar = 3,5-dimethylphenyl) were synthesized and characterized by X-ray crystallography. H/D exchange of C₆H₆ with TFA-d₁ was observed with 4 mol% loading of [Rh^III(α-diimine-Ar)Me(H₂O)₃][BF₄]₂ at 100 °C with 137 turnovers…

Subjects/Keywords: BIAN; Carbon monoxide; Catalysis; Cyclization; Lactam; Oxindole

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APA (6^th Edition):

Kovach, J. (2015). Electrophilic C-H activation using a Shilov-inspired rhodium diimine complex. (Doctoral Dissertation). University of Rochester. Retrieved from http://hdl.handle.net/1802/29250

Chicago Manual of Style (16^th Edition):

Kovach, James. “Electrophilic C-H activation using a Shilov-inspired rhodium diimine complex.” 2015. Doctoral Dissertation, University of Rochester. Accessed March 06, 2021. http://hdl.handle.net/1802/29250.

MLA Handbook (7^th Edition):

Kovach, James. “Electrophilic C-H activation using a Shilov-inspired rhodium diimine complex.” 2015. Web. 06 Mar 2021.

Vancouver:

Kovach J. Electrophilic C-H activation using a Shilov-inspired rhodium diimine complex. [Internet] [Doctoral dissertation]. University of Rochester; 2015. [cited 2021 Mar 06]. Available from: http://hdl.handle.net/1802/29250.

Council of Science Editors:

Kovach J. Electrophilic C-H activation using a Shilov-inspired rhodium diimine complex. [Doctoral Dissertation]. University of Rochester; 2015. Available from: http://hdl.handle.net/1802/29250

University of Georgia

17. Black, Alan Wayne. Winter precipitation hazards in the United States.

Degree: 2015, University of Georgia

URL: http://hdl.handle.net/10724/32521

► Winter precipitation is a significant hazard to lives and property in the United States. This study examines the two main types of indirect fatalities—situations where… (more)

▼ Winter precipitation is a significant hazard to lives and property in the United States. This study examines the two main types of indirect fatalities—situations where the winter precipitation leads to a circumstance that causes a death—due to winter precipitation in the United States: vehicle crashes and Carbon Monoxide (CO) poisonings. Over 800 people per year are killed due to winter precipitation related motor vehicle crashes, significantly more than other, prominent weather hazards such as tornadoes. The greatest risk of death due to winter precipitation related crash is found in the Great Lakes, Midwest, and western U.S. While little trend was found in motor vehicle fatalities, aviation fatalities had a significant downward trend, with most aviation fatalities occurring in the high terrain of the western U.S. Analysis of 13 cities finds that property damage, injury, and fatal crash risk increases during winter weather, especially if a reduction in driving is assumed. This risk is greatest during more intense precipitation and across the mid-Mississippi and Ohio River valleys. Finally, fatal CO poisonings related to winter weather induced power outage are examined to determine the characteristics of victims and the geographic extent of these deaths. Most fatalities were among men and those aged 65 or older, with most victims having a high school education or less. Non-Hispanic blacks and non-Hispanic whites are disproportionately affected by winter precipitation power outage related CO poisoning, but Hispanics may be more vulnerable to these events. Spatial analysis of the deaths found that most were in the mid-Atlantic, while states in the Great Plains and Intermountain West that typically see high rates of CO poisonings had no fatalities. Although winter precipitation may not receive much attention from researchers or the general public, it is a hazard which can cause significantly more deaths than other, more prominent, meteorological hazards. It is hoped that this work will provide the groundwork for future research and applications to reduce the risk of winter precipitation and ultimately save lives.

Subjects/Keywords: Winter Precipitation; Hazards; Transportation; Climatology; Carbon Monoxide

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APA (6^th Edition):

Black, A. W. (2015). Winter precipitation hazards in the United States. (Thesis). University of Georgia. Retrieved from http://hdl.handle.net/10724/32521

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Chicago Manual of Style (16^th Edition):

Black, Alan Wayne. “Winter precipitation hazards in the United States.” 2015. Thesis, University of Georgia. Accessed March 06, 2021. http://hdl.handle.net/10724/32521.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

MLA Handbook (7^th Edition):

Black, Alan Wayne. “Winter precipitation hazards in the United States.” 2015. Web. 06 Mar 2021.

Vancouver:

Black AW. Winter precipitation hazards in the United States. [Internet] [Thesis]. University of Georgia; 2015. [cited 2021 Mar 06]. Available from: http://hdl.handle.net/10724/32521.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Council of Science Editors:

Black AW. Winter precipitation hazards in the United States. [Thesis]. University of Georgia; 2015. Available from: http://hdl.handle.net/10724/32521

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

18. Reddy, C Vijaya Bhaskar. Fabrication and development of iosensor for corbonmonoxide detection in automotive vehicles.

Degree: Mechanical Engineering, 2013, Jawaharlal Nehru Technological University, Anantapuram

URL: http://shodhganga.inflibnet.ac.in/handle/10603/11438

►

ABSTRACT newlineTo a certain extent, all processes for energy conversion are associated with the newlineproduction of toxic by-products such as Carbon monoxide (CO) Oxides of… (more)

▼

ABSTRACT newlineTo a certain extent, all processes for energy conversion are associated with the newlineproduction of toxic by-products such as Carbon monoxide (CO) Oxides of Nitrogen newline(NOx) and aromatic hydro carbon. The significant part of Carbon monoxide and newlineOxides of Nitrogen emissions originates from exhaust of motor vehicles due to their newlinepoor maintenance, tremendous increase in their number, and use of out dated vehicles. newlineIndia is one of the largest automotive manufacturers in the world. Consequently, due newlineto the combustion of fossil fuels, the vehicle pollution has become the cause of major newlineconcern. All these pollutants due to their toxicity are harmful not only to human newlinebeings but also to plants. It is observed from both the gasoline/petrol or diesel newlinevehicles that the main component of automobile emission causing harm to human and newlineenvironment is carbon monoxide. newlineDetection of carbon monoxide plays a vital role for many scientific, household, newlineenvironmental and industrial applications. As per the Indian government Automotive newlineNorms for pollution checkup, the vehicle has to be taken to a Pollution Under Control newline(PUC) centre for the measurement of carbon monoxide present in the exhaust gases newlinereleased from vehicles. There is no in-situ measuring instrument for the detection of newlineCarbon monoxide while the vehicle is on road. The equipment and infrastructure at newlinethe Pollution Under Control centres are expensive and uses conventional sensors. As newlinean alternative, Biosensors which have got wide applications in medical field can offer newlinescope for their use in automotive applications. newlineBiosensors are analytical tools for the analysis of bio-material samples in medical newlinefield to gain an understanding of their bio-composition, structure and function by newlineconverting a biological response into an electrical signal. The biological recognition newlineelement (Sensing Technique) is functionalised with enzyme, antibodies, Deoxyribo newlineNucleic Acid (DNA), or cell membrane. The enzyme or Antibodies react with only newlineparticular analyte (sample) Antigen only. With thi

conclusion- 152-154, references- 155-172

Advisors/Committee Members: Narasaiah Chetty, K.

Subjects/Keywords: BIOSENSOR; CARBON MONOXIDE DETECTION IN AUTOMOTIVE VEHICLES

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APA (6^th Edition):

Reddy, C. V. B. (2013). Fabrication and development of iosensor for corbonmonoxide detection in automotive vehicles. (Thesis). Jawaharlal Nehru Technological University, Anantapuram. Retrieved from http://shodhganga.inflibnet.ac.in/handle/10603/11438

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Chicago Manual of Style (16^th Edition):

Reddy, C Vijaya Bhaskar. “Fabrication and development of iosensor for corbonmonoxide detection in automotive vehicles.” 2013. Thesis, Jawaharlal Nehru Technological University, Anantapuram. Accessed March 06, 2021. http://shodhganga.inflibnet.ac.in/handle/10603/11438.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

MLA Handbook (7^th Edition):

Reddy, C Vijaya Bhaskar. “Fabrication and development of iosensor for corbonmonoxide detection in automotive vehicles.” 2013. Web. 06 Mar 2021.

Vancouver:

Reddy CVB. Fabrication and development of iosensor for corbonmonoxide detection in automotive vehicles. [Internet] [Thesis]. Jawaharlal Nehru Technological University, Anantapuram; 2013. [cited 2021 Mar 06]. Available from: http://shodhganga.inflibnet.ac.in/handle/10603/11438.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Council of Science Editors:

Reddy CVB. Fabrication and development of iosensor for corbonmonoxide detection in automotive vehicles. [Thesis]. Jawaharlal Nehru Technological University, Anantapuram; 2013. Available from: http://shodhganga.inflibnet.ac.in/handle/10603/11438

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Penn State University

19. Bhimanapati, Ganesh Rahul. Graphene Oxide Supported Ruthenium for CO Methanation.

Degree: 2013, Penn State University

URL: https://submit-etda.libraries.psu.edu/catalog/16164

► The sustainable exploration of space requires minimization of re-supply from Earth through the implementation of In-Situ Resources Utilization (ISRU) strategies developed by NASA. One such… (more)

▼ The sustainable exploration of space requires minimization of re-supply from Earth through the implementation of In-Situ Resources Utilization (ISRU) strategies developed by NASA. One such strategy for lunar exploration is the production of oxygen from lunar regolith, a complex mix of minerals with large oxygen content. In the case of carbothermal-based oxygen production, reaction byproducts, i.e. carbon oxides, should be converted to methane for reintroduction into the carbothermal system. For this purpose, development of a methanation reactor to efficiently convert the mixed-carbon oxides into methane is essential to the integrity of the ISRU process. Nickel has been the favored catalyst for the methanation reaction because of its activity, selectivity and catalyst life. Yet Ni and Ni-based catalysts are particularly sensitive to poisoning by sulfur and coking by carbon. For these reasons Group VIII metals, in general far less prone to such detriments, have been in focus as alternatives to Ni, particularly Ru. Presently recent literature on methanation catalysts is concerned with preparative techniques and catalyst support, factors markedly affecting catalyst properties. The research reported here is focused on developing a new, more-efficient catalyst for the methanation component in NASA’s ISRU oxygen scheme. Efficiency generally translates into high catalyst exposure or high surface-area availability in heterogeneous catalysis. As a high surface area support graphene was chosen. Dispersion of Ru on graphene was achieved via a two-step decoration process using graphene oxide as a precursor. Notably GO production also facilitates graphene layer separation to create a high surface-area support. Yet agglomeration can occur during its reduction and deposition within a reactor bed, thereby lessening the effectiveness of the catalyst dispersion it supports. This is particularly problematic for nanoscale carbon materials as supports, given their high self-affinity between particles or platelets. Preventing this agglomeration will provide an increase in the accessibility to the surface metal sites on the support and ultimately could increase the performance activity of the catalysts. Towards this goal different Ru-based catalyst systems, using grapheme, were prepared and compared. The support of interest, grapheme, was first prepared as graphene oxide (GO) by the modified Hummers process and later decorated with ruthenium using a poly-ol process. A traditional catalyst system of ruthenium supported on alumina (Al2O3) was also prepared using the same process so as to facilitate comparisons. Another catalyst was synthesized in which the alumina was also introduced in the synthesis process along with GO to produce a mixed catalyst with the alumina helping to separate the graphene sheets, thereby partially alleviating their agglomeration.. These catalysts were then impregnated within hierarchical alumina foams and loaded into a microchannel methanation reactor based upon a simple pipe construction and Swagelok… Advisors/Committee Members: Randy Vander Wal, Thesis Advisor/Co-Advisor.

Subjects/Keywords: Graphene Oxide; Ruthenium; carbon monoxide; methanation; alumina.

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APA (6^th Edition):

Bhimanapati, G. R. (2013). Graphene Oxide Supported Ruthenium for CO Methanation. (Thesis). Penn State University. Retrieved from https://submit-etda.libraries.psu.edu/catalog/16164

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Chicago Manual of Style (16^th Edition):

Bhimanapati, Ganesh Rahul. “Graphene Oxide Supported Ruthenium for CO Methanation.” 2013. Thesis, Penn State University. Accessed March 06, 2021. https://submit-etda.libraries.psu.edu/catalog/16164.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

MLA Handbook (7^th Edition):

Bhimanapati, Ganesh Rahul. “Graphene Oxide Supported Ruthenium for CO Methanation.” 2013. Web. 06 Mar 2021.

Vancouver:

Bhimanapati GR. Graphene Oxide Supported Ruthenium for CO Methanation. [Internet] [Thesis]. Penn State University; 2013. [cited 2021 Mar 06]. Available from: https://submit-etda.libraries.psu.edu/catalog/16164.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Council of Science Editors:

Bhimanapati GR. Graphene Oxide Supported Ruthenium for CO Methanation. [Thesis]. Penn State University; 2013. Available from: https://submit-etda.libraries.psu.edu/catalog/16164

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

20. Belanger, Andrea Mary. Biophysical Studies Aimed at Potential Therapies of Hemoglobin Associated Diseases.

Degree: 2015, Wake Forest University

URL: http://hdl.handle.net/10339/57124

► Hemoglobin (Hb), the most abundant protein found in the red blood cell (RBC), carries gases like oxygen and carbon dioxide throughout the body. However, various… (more)

Subjects/Keywords: carbon monoxide

…body, such as the presence of carbon monoxide (CO), can lead to diminished Hb… …antidote for carbon monoxide (CO) poisoning. If inhaled, CO – a colorless, odorless gas… …carries gases like oxygen and carbon dioxide throughout the body. However, various conditions… …Hemoglobin (Hb) is a quarternary metalloprotein that transports oxygen, carbon dioxide… …carbon dioxide produced by the breakdown of sugar and fat in cells into carbonic acid and…

13 more images…

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APA (6^th Edition):

Belanger, A. M. (2015). Biophysical Studies Aimed at Potential Therapies of Hemoglobin Associated Diseases. (Thesis). Wake Forest University. Retrieved from http://hdl.handle.net/10339/57124

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Chicago Manual of Style (16^th Edition):

Belanger, Andrea Mary. “Biophysical Studies Aimed at Potential Therapies of Hemoglobin Associated Diseases.” 2015. Thesis, Wake Forest University. Accessed March 06, 2021. http://hdl.handle.net/10339/57124.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

MLA Handbook (7^th Edition):

Belanger, Andrea Mary. “Biophysical Studies Aimed at Potential Therapies of Hemoglobin Associated Diseases.” 2015. Web. 06 Mar 2021.

Vancouver:

Belanger AM. Biophysical Studies Aimed at Potential Therapies of Hemoglobin Associated Diseases. [Internet] [Thesis]. Wake Forest University; 2015. [cited 2021 Mar 06]. Available from: http://hdl.handle.net/10339/57124.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Council of Science Editors:

Belanger AM. Biophysical Studies Aimed at Potential Therapies of Hemoglobin Associated Diseases. [Thesis]. Wake Forest University; 2015. Available from: http://hdl.handle.net/10339/57124

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

University of Connecticut

21. Leamon, Eric G. The Effect of Fuel and Air Side Contaminants in a Proton Exchange Membrane Fuel Cell and Methods for Mitigation.

Degree: MS, Mechanical Engineering, 2016, University of Connecticut

URL: https://opencommons.uconn.edu/gs_theses/873

► Investigations into the effects of fuel and air side contaminants within a proton exchange membrane fuel cell (PEMFC) were conducted via the introduction of… (more)

Subjects/Keywords: Fuel Cells; Carbon Monoxide; Mitigation; Air Contaminants

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APA (6^th Edition):

Leamon, E. G. (2016). The Effect of Fuel and Air Side Contaminants in a Proton Exchange Membrane Fuel Cell and Methods for Mitigation. (Masters Thesis). University of Connecticut. Retrieved from https://opencommons.uconn.edu/gs_theses/873

Chicago Manual of Style (16^th Edition):

Leamon, Eric G. “The Effect of Fuel and Air Side Contaminants in a Proton Exchange Membrane Fuel Cell and Methods for Mitigation.” 2016. Masters Thesis, University of Connecticut. Accessed March 06, 2021. https://opencommons.uconn.edu/gs_theses/873.

MLA Handbook (7^th Edition):

Leamon, Eric G. “The Effect of Fuel and Air Side Contaminants in a Proton Exchange Membrane Fuel Cell and Methods for Mitigation.” 2016. Web. 06 Mar 2021.

Vancouver:

Leamon EG. The Effect of Fuel and Air Side Contaminants in a Proton Exchange Membrane Fuel Cell and Methods for Mitigation. [Internet] [Masters thesis]. University of Connecticut; 2016. [cited 2021 Mar 06]. Available from: https://opencommons.uconn.edu/gs_theses/873.

Council of Science Editors:

Leamon EG. The Effect of Fuel and Air Side Contaminants in a Proton Exchange Membrane Fuel Cell and Methods for Mitigation. [Masters Thesis]. University of Connecticut; 2016. Available from: https://opencommons.uconn.edu/gs_theses/873

University of Gothenburg / Göteborgs Universitet

22. Ahlström, Katarina. Energy-metabolic aspects of ischemia and pre-treatment: studies in porcine myocardium.

Degree: 2011, University of Gothenburg / Göteborgs Universitet

URL: http://hdl.handle.net/2077/24621

► The focus of this thesis is to clarify mechanisms involved in protective pre-treatment of ischemia by carbon monoxide (CO) and ischemic preconditioning (IP), so that… (more)

▼ The focus of this thesis is to clarify mechanisms involved in protective pre-treatment of ischemia by carbon monoxide (CO) and ischemic preconditioning (IP), so that new pro-tective therapies can be designed. This is studied in heart muscle, where the clinical gain would ultimately be to be able to prolong the period during a threatened myocardial infarction where permanent injury can be prevented. The aim is to elucidate energy meta-bolic relations as a basis for temporary metabolic adaptation to threatened injury in heart muscle, with focus on the biological relevance of this mechanism. All studies were conducted in an open-chest, anesthetized pig model using microdialysis sampling. Methods: In anesthetized 40 kg pigs, regional myocardial ischemia was produced by transient snare-ligation of a branch of the left anterior descending coronary artery. Micro-dialysis catheters were used for local sampling of interstitial fluid in the ischemic area. In Studies 1 and 2, CO was administered before prolonged ischemia in a clinically relevant dose (5% increase in carboxyhemoglobin). In Study 2, 45Ca2+ was administered locally by microperfusate to ischemic myocardium with 45Ca2+ recovery used as a marker for intra-cellular calcium overload during ischemia. Myocardial injury markers glycerol and glut-amate (and taurine in Studies 3 and 4) were measured in microdialysate. In Studies 3 and 4, IP was performed by 4 brief transient cycles of coronary occlusion and reperfusion before a prolonged index ischemic episode was performed. In Study 3, 14C-marked adenosine was administered locally via microdialysis catheters in the heart muscle wall, and when this was metabolized during ischemia as an energy source, it was detected as 14C-marked lactate. In Study 4, a water-soluble purine nucleoside phosphorylase inhibitor was administered to heart muscle via microdialysis which was treated by IP before an index ischemia. Markers of glycolysis were measured serially before and during ischemia for Studies 1-4. Radio-labelled markers were analyzed using liquid chromatography and scintigraphy. Results: Study 1 results showed clear signs of metabolic advantage as far as glycolytic markers related to CO during myocardial ischemia. Study 2 results demonstrated no apparent energy metabolic advantage including for 45Ca2+ recovery and no diminishment of injury markers related to the single tested carbon monoxide dose during ischemia. Study 3 showed that IP led to enhanced radio-marked adenosine consumption as an energy-metabolic substrate, and that glycolytic flow (as less glucose consumption and lactate formation) was slower in IP-treated heart muscle. Study 4 showed that local purine nucleoside phosphorylase blockade inhibits adenosine utilization as an energy-metabolic substrate during ischemia, but this did not have an effect on glycolysis or injury markers during prolonged ischemia after IP. Conclusions: From Studies 1 and 2, we concluded that CO in this dose could show effects on glycolysis during ischemia but does not seem to confer cell…

Subjects/Keywords: myocardial ischemia; adenosine; preconditioning; carbon monoxide

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APA (6^th Edition):

Ahlström, K. (2011). Energy-metabolic aspects of ischemia and pre-treatment: studies in porcine myocardium. (Thesis). University of Gothenburg / Göteborgs Universitet. Retrieved from http://hdl.handle.net/2077/24621

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Chicago Manual of Style (16^th Edition):

Ahlström, Katarina. “Energy-metabolic aspects of ischemia and pre-treatment: studies in porcine myocardium.” 2011. Thesis, University of Gothenburg / Göteborgs Universitet. Accessed March 06, 2021. http://hdl.handle.net/2077/24621.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

MLA Handbook (7^th Edition):

Ahlström, Katarina. “Energy-metabolic aspects of ischemia and pre-treatment: studies in porcine myocardium.” 2011. Web. 06 Mar 2021.

Vancouver:

Ahlström K. Energy-metabolic aspects of ischemia and pre-treatment: studies in porcine myocardium. [Internet] [Thesis]. University of Gothenburg / Göteborgs Universitet; 2011. [cited 2021 Mar 06]. Available from: http://hdl.handle.net/2077/24621.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Council of Science Editors:

Ahlström K. Energy-metabolic aspects of ischemia and pre-treatment: studies in porcine myocardium. [Thesis]. University of Gothenburg / Göteborgs Universitet; 2011. Available from: http://hdl.handle.net/2077/24621

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Montana State University

23. Gaines, Jack R. A study of the reactions of carbon monoxide with B-Dicarbonyl compounds and their derivatives [and] the synthesis of aldehydes by the reaction of formyl fluoride with organocadmium bromides.

Degree: MS, College of Letters & Science, 1950, Montana State University

URL: https://scholarworks.montana.edu/xmlui/handle/1/5259

Subjects/Keywords: Carbon monoxide.; Aldehydes.

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APA (6^th Edition):

Gaines, J. R. (1950). A study of the reactions of carbon monoxide with B-Dicarbonyl compounds and their derivatives [and] the synthesis of aldehydes by the reaction of formyl fluoride with organocadmium bromides. (Masters Thesis). Montana State University. Retrieved from https://scholarworks.montana.edu/xmlui/handle/1/5259

Chicago Manual of Style (16^th Edition):

Gaines, Jack R. “A study of the reactions of carbon monoxide with B-Dicarbonyl compounds and their derivatives [and] the synthesis of aldehydes by the reaction of formyl fluoride with organocadmium bromides.” 1950. Masters Thesis, Montana State University. Accessed March 06, 2021. https://scholarworks.montana.edu/xmlui/handle/1/5259.

MLA Handbook (7^th Edition):

Gaines, Jack R. “A study of the reactions of carbon monoxide with B-Dicarbonyl compounds and their derivatives [and] the synthesis of aldehydes by the reaction of formyl fluoride with organocadmium bromides.” 1950. Web. 06 Mar 2021.

Vancouver:

Gaines JR. A study of the reactions of carbon monoxide with B-Dicarbonyl compounds and their derivatives [and] the synthesis of aldehydes by the reaction of formyl fluoride with organocadmium bromides. [Internet] [Masters thesis]. Montana State University; 1950. [cited 2021 Mar 06]. Available from: https://scholarworks.montana.edu/xmlui/handle/1/5259.

Council of Science Editors:

Gaines JR. A study of the reactions of carbon monoxide with B-Dicarbonyl compounds and their derivatives [and] the synthesis of aldehydes by the reaction of formyl fluoride with organocadmium bromides. [Masters Thesis]. Montana State University; 1950. Available from: https://scholarworks.montana.edu/xmlui/handle/1/5259

University of Illinois – Urbana-Champaign

24. Ambrosi, Andrea. I. Mechanistic significance of the Si-O-Pd linkage in the cross-coupling of organosilanolates; II. Applications of the water-gas shift reaction in organic synthesis.

Degree: PhD, Chemistry, 2016, University of Illinois – Urbana-Champaign

URL: http://hdl.handle.net/2142/95551

► The first half of the present dissertation describes the mechanistic investigation of the palladium-catalyzed cross-coupling reaction of alkenyl- and arylsilanolates. The combination of reaction kinetics… (more)

▼ The first half of the present dissertation describes the mechanistic investigation of the palladium-catalyzed cross-coupling reaction of alkenyl- and arylsilanolates. The combination of reaction kinetics (both stoichiometric and catalytic), solution and solid state characterization of arylpalladium(II) organosilanolate complexes, and computational analysis, enabled the formulation of a detailed mechanistic picture for the cross-coupling of these classes of nucleophiles. The intermediacy of covalent adducts containing Si-O-Pd linkages in the cross-coupling reactions of organosilanolates has been unambiguously established. From such intermediates, two mechanistically distinct transmetalation pathways have been demonstrated: (1) transmetalation via a neutral 8-Si-4 intermediate (thermal transmetalation); (2) transmetalation via an anionic 10-Si-5 intermediate (activated transmetalation). In general, potassium salts of alkenylsilanolates react via neutral intermediates (8-Si-4), whereas the enhanced nucleophilicity of cesium alkenylsilanolates allows for the reaction to access the 10-Si-5 intermediate and proceed via the anionically-activated pathway. However, if the direct transmetalation is slower, as in the case of arylsilanolates (which require interruption of aromaticity), then anionic activation via the 10-Si-5 intermediate is predominant, regardless of the cation employed. These conclusions mandate a revision of the paradigm that organosilicon compounds must be anionically activated to engage in transmetalation processes (Hiyama-Hatanaka paradigm). Through the agency of the critical Si-O-Pd linkage, direct transmetalation of silicon to palladium can be achieved under mild conditions without anionic activation. The thorough mechanistic understanding of the transmetalation step for organosilanolates was leveraged in the study of the cross-coupling of γ-disubstituted allenylsilanolates. For the cross-coupling reaction of this class of nucleophiles, it was concluded that the transmetalation pathway (activated vs. thermal) dictates which isomer is accessed (α vs. γ). The second half of this dissertation details the efforts made toward the application of the Water-Gas Shift Reaction (WGSR) in the catalysis of fundamental C-C bond forming reactions. To this end, three strategies were envisioned and investigated. In a first approach, the CO/H2O couple was exploited as the terminal reducing agent for a metal catalyst that is directly involved in the formation of a new C-C bond. This strategy was studied in the context of carbonyl addition and reductive homocoupling reactions. The multiple conditions that must be strictly met for this approach to be successful (ranging from electrochemical requirements to properly balanced bond enthalpies of the complexes along the catalytic pathway) made the development of new, WGSR-based catalytic methods quite challenging. In a second approach, the CO/H2O couple provides reducing equivalents for an organocatalyst that is implicated in the C-C bond formation. This second strategy poses… Advisors/Committee Members: Denmark, Scott E (advisor), Denmark, Scott E (Committee Chair), Burke, Martin D (committee member), Fout, Alison R (committee member), Sarlah, David (committee member).

Subjects/Keywords: Cross-coupling; Silanolates; Carbon monoxide; Organic synthesis

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APA (6^th Edition):

Ambrosi, A. (2016). I. Mechanistic significance of the Si-O-Pd linkage in the cross-coupling of organosilanolates; II. Applications of the water-gas shift reaction in organic synthesis. (Doctoral Dissertation). University of Illinois – Urbana-Champaign. Retrieved from http://hdl.handle.net/2142/95551

Chicago Manual of Style (16^th Edition):

Ambrosi, Andrea. “I. Mechanistic significance of the Si-O-Pd linkage in the cross-coupling of organosilanolates; II. Applications of the water-gas shift reaction in organic synthesis.” 2016. Doctoral Dissertation, University of Illinois – Urbana-Champaign. Accessed March 06, 2021. http://hdl.handle.net/2142/95551.

MLA Handbook (7^th Edition):

Ambrosi, Andrea. “I. Mechanistic significance of the Si-O-Pd linkage in the cross-coupling of organosilanolates; II. Applications of the water-gas shift reaction in organic synthesis.” 2016. Web. 06 Mar 2021.

Vancouver:

Ambrosi A. I. Mechanistic significance of the Si-O-Pd linkage in the cross-coupling of organosilanolates; II. Applications of the water-gas shift reaction in organic synthesis. [Internet] [Doctoral dissertation]. University of Illinois – Urbana-Champaign; 2016. [cited 2021 Mar 06]. Available from: http://hdl.handle.net/2142/95551.

Council of Science Editors:

Ambrosi A. I. Mechanistic significance of the Si-O-Pd linkage in the cross-coupling of organosilanolates; II. Applications of the water-gas shift reaction in organic synthesis. [Doctoral Dissertation]. University of Illinois – Urbana-Champaign; 2016. Available from: http://hdl.handle.net/2142/95551

University of Illinois – Urbana-Champaign

25. Matesich, Zachery D. Catalytic allylation of aldehydes mediated via the water-gas shift reaction.

Degree: PhD, Chemistry, 2017, University of Illinois – Urbana-Champaign

URL: http://hdl.handle.net/2142/98283

► This dissertation details the progress made in the catalytic, nucleophilic allylation of aldehydes, as mediated through the action of the Water-Gas Shift reaction (WGSR). Through… (more)

Subjects/Keywords: Carbon monoxide; Allylation; Enantioselective; Photochemical; Organometallic

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APA (6^th Edition):

Matesich, Z. D. (2017). Catalytic allylation of aldehydes mediated via the water-gas shift reaction. (Doctoral Dissertation). University of Illinois – Urbana-Champaign. Retrieved from http://hdl.handle.net/2142/98283

Chicago Manual of Style (16^th Edition):

Matesich, Zachery D. “Catalytic allylation of aldehydes mediated via the water-gas shift reaction.” 2017. Doctoral Dissertation, University of Illinois – Urbana-Champaign. Accessed March 06, 2021. http://hdl.handle.net/2142/98283.

MLA Handbook (7^th Edition):

Matesich, Zachery D. “Catalytic allylation of aldehydes mediated via the water-gas shift reaction.” 2017. Web. 06 Mar 2021.

Vancouver:

Matesich ZD. Catalytic allylation of aldehydes mediated via the water-gas shift reaction. [Internet] [Doctoral dissertation]. University of Illinois – Urbana-Champaign; 2017. [cited 2021 Mar 06]. Available from: http://hdl.handle.net/2142/98283.

Council of Science Editors:

Matesich ZD. Catalytic allylation of aldehydes mediated via the water-gas shift reaction. [Doctoral Dissertation]. University of Illinois – Urbana-Champaign; 2017. Available from: http://hdl.handle.net/2142/98283

Louisiana State University

26. King, Caitlin Elizabeth. Diversity and activity of aerobic thermophilic carbon monoxide-oxidizing bacteria on Kilauea Volcano, Hawaii.

Degree: PhD, 2013, Louisiana State University

URL: etd-10032013-112549 ; https://digitalcommons.lsu.edu/gradschool_dissertations/690

► Aerobic carbon monoxide (CO) oxidation is used by phylogenetically and physiologically diverse microorganisms inhabiting a variety of terrestrial and aquatic ecosystems. Activity assays, culture-based studies,… (more)

▼ Aerobic carbon monoxide (CO) oxidation is used by phylogenetically and physiologically diverse microorganisms inhabiting a variety of terrestrial and aquatic ecosystems. Activity assays, culture-based studies, and molecular-based approaches targeting the coxL gene, encoding the large subunit of CO dehydrogenase, were used to investigate the role of temperature in structuring CO-oxidizing communities at Kilauea Volcano, Hawai’i. CO uptake activity was assessed for unvegetated and vegetated temperate volcanic deposits that experience different temperature regimes due to plant development during ecosystem succession. Both CO-oxidizing communities had similar short-term responses to temperature; however, results from extended incubations (30 d) at elevated temperature (55 °C) indicate that succession expanded the capacity of the vegetated community to adapt to high temperature. Aerobic CO uptake was also examined for geothermal sites including two soils and two microbial biofilms at the Puhimau geothermal area and Kilauea Iki crater. CO oxidation occurred at elevated temperatures for all sites assessed; however, cardinal temperatures for CO activity were not strongly correlated to in situ temperatures. These results also extended the known upper temperature limit (80 °C) for aerobic CO oxidation. Culture-based methods targeting thermophiles at these sites yielded 31 newly isolated thermophilic CO-oxidizing strains in 8 genera. Two strains were formally described as novel species. The isolation of multiple Thermogemmatispora strains (Class: Ktedonobacteria) led to exploration of CO oxidation in this group; CO oxidation was found to be a common trait among Ktedonobacteria. Additionally, geothermally-heated biofilms at Puhimau were dominated by Ktedonobacteria as determined from coxL clone libraries, 16S rRNA gene pyrosequencing, and analysis of coxL fragments from a biofilm metagenome. Thermophiles are known to exist in temperate environments, but their maintenance and activity remain unclear. We examined the activity of thermophilic CO-oxidizing bacteria under different temperature regimes including 25 °C, 55 °C, and an oscillating temperature regime (20 – 55 °C). Three hours per day above 45 °C was sufficient for growth and CO oxidation activity. CO oxidation at moderate temperatures could contribute to maintenance metabolism and survival of thermophiles under suboptimal conditions. Collectively these studies show that thermophilic CO oxidizers are active and abundant in thermal systems on Kilauea Volcano.

Subjects/Keywords: carbon monoxide; bacteria; microbial ecology; coxL; thermophile

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APA (6^th Edition):

King, C. E. (2013). Diversity and activity of aerobic thermophilic carbon monoxide-oxidizing bacteria on Kilauea Volcano, Hawaii. (Doctoral Dissertation). Louisiana State University. Retrieved from etd-10032013-112549 ; https://digitalcommons.lsu.edu/gradschool_dissertations/690

Chicago Manual of Style (16^th Edition):

King, Caitlin Elizabeth. “Diversity and activity of aerobic thermophilic carbon monoxide-oxidizing bacteria on Kilauea Volcano, Hawaii.” 2013. Doctoral Dissertation, Louisiana State University. Accessed March 06, 2021. etd-10032013-112549 ; https://digitalcommons.lsu.edu/gradschool_dissertations/690.

MLA Handbook (7^th Edition):

King, Caitlin Elizabeth. “Diversity and activity of aerobic thermophilic carbon monoxide-oxidizing bacteria on Kilauea Volcano, Hawaii.” 2013. Web. 06 Mar 2021.

Vancouver:

King CE. Diversity and activity of aerobic thermophilic carbon monoxide-oxidizing bacteria on Kilauea Volcano, Hawaii. [Internet] [Doctoral dissertation]. Louisiana State University; 2013. [cited 2021 Mar 06]. Available from: etd-10032013-112549 ; https://digitalcommons.lsu.edu/gradschool_dissertations/690.

Council of Science Editors:

King CE. Diversity and activity of aerobic thermophilic carbon monoxide-oxidizing bacteria on Kilauea Volcano, Hawaii. [Doctoral Dissertation]. Louisiana State University; 2013. Available from: etd-10032013-112549 ; https://digitalcommons.lsu.edu/gradschool_dissertations/690

Kansas State University

27. Wiens, Robert Elmer. Colorimetric methods for the determination of carbon monoxide in air.

Degree: 1973, Kansas State University

URL: http://hdl.handle.net/2097/10914

Subjects/Keywords: Carbon monoxide; Spectrophotometry

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APA (6^th Edition):

Wiens, R. E. (1973). Colorimetric methods for the determination of carbon monoxide in air. (Thesis). Kansas State University. Retrieved from http://hdl.handle.net/2097/10914

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Chicago Manual of Style (16^th Edition):

Wiens, Robert Elmer. “Colorimetric methods for the determination of carbon monoxide in air.” 1973. Thesis, Kansas State University. Accessed March 06, 2021. http://hdl.handle.net/2097/10914.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

MLA Handbook (7^th Edition):

Wiens, Robert Elmer. “Colorimetric methods for the determination of carbon monoxide in air.” 1973. Web. 06 Mar 2021.

Vancouver:

Wiens RE. Colorimetric methods for the determination of carbon monoxide in air. [Internet] [Thesis]. Kansas State University; 1973. [cited 2021 Mar 06]. Available from: http://hdl.handle.net/2097/10914.

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

Council of Science Editors:

Wiens RE. Colorimetric methods for the determination of carbon monoxide in air. [Thesis]. Kansas State University; 1973. Available from: http://hdl.handle.net/2097/10914

Note: this citation may be lacking information needed for this citation format:
Not specified: Masters Thesis or Doctoral Dissertation

University of British Columbia

28. Plackett, David Victor. Activation of carbon monoxide by ruthenium carbonyl complexes in solution.

Degree: PhD, Chemistry, 1977, University of British Columbia

URL: http://hdl.handle.net/2429/20913

► The thesis describes some aspects of the aqueous solution chemistry of chlororuthenate(III) and chlorocarbonylruthenate(III or II) complexes including their reactivity toward carbon monoxide. This led… (more)

▼ The thesis describes some aspects of the aqueous solution chemistry of chlororuthenate(III) and chlorocarbonylruthenate(III or II) complexes including their reactivity toward carbon monoxide. This led to the synthesis and characterisation of a polymeric complex [HRu(CO)₃][sub n], which is formally a Ru(I) derivative. The use of these ruthenium complexes for activating CO catalytically was studied, especially for the carbonylation of amines. The [HRu(CO)₃][sub n] polymer was characterised by microanalysis, infra-red and high-field ¹H n.m.r. , and its chemistry In donor solvents in which it was soluble. The polymer may be formed by reductive carbonylation of chloro complexes of Ru[sup II], Ru[sup III](CO), Ru[sup II] (CO), Ru[sup II] (C0)₂ and Ru[sup II]CO)₃, and stoichiometric evidence suggests processes such as: [chemical reactions 1 to 4]. Increasing acidity and chloride concentration inhibit the reductive carbonylation process, which likely requires simultaneous coordination of cis CO and OH ligands. Reactions (1) - (4) are accompanied by formation of smaller amounts of low valent ruthenium complexes including Ru₃(CO)₁₂, which could result from a reductive carbonylation process such as [chemical reaction 5] or via 'combination' of Ru[sup I] and Ru[sup -I] species. Evidence is presented for reaction (5) starting with CsRu(CO)₃Cl₃. Reductive carbonylation 2- of Ru(CO)₂Cl₄⁻² (reaction (4)) shows autocatalytic gas uptake plots, indicating catalysis of the reaction via a Ru(0) or Ru(I) intermediate. The kinetics for the carbonylation of piperidine to N-formyl piperidine catalysed by each of the complexes [HRu(CO)₃][sub n], [Ru(CO)₂(OAc)(pip)]₂, and CsRu(CO)₃Cl₃, have been studied under mild conditions. Mechanisms are proposed to explain the observed kinetics and in each case a tricarbonyl monomeric species appears to be the active catalyst. A CO insertion reaction in a Ru(CO)₃ (pip)[sub x] intermediate must be involved. A scheme such as (6) e.g. [chemical reaction 6] requires a hydride shift, likely metal activated. Alternatively, piperidine could behave as a proton acceptor with the reaction proceeding via a carbamoyl intermediate (reaction (7)). [chemical reaction 7] Both [HRu(CO)₃][sub n] and CsRu(C0)₃Cl₃ carbonylate piperidine in a stoichiometric reaction in the absence of CO, and in the case of the cesium salt evidence suggests the following reactions: [chemical reactions 8-9] Only secondary amines were carbonylated effectively. Attempts to isolate and characterise ruthenium complexes via the reactions [HRu(CO)₃][sub n] or CsRu(C0)₃Cl₃with piperidine proved frustrating, although one complex isolated from the polymer reaction is thought to be H₂Ru₂(CO)₄(pip)₃, and an oxygenated solution of [HRu(CO)₃][sub n] in piperidine yielded a complex which analysed well for [HRu(CO)₂(pip)]₂•0₂.

Subjects/Keywords: Ruthenium; Carbon monoxide

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APA (6^th Edition):

Plackett, D. V. (1977). Activation of carbon monoxide by ruthenium carbonyl complexes in solution. (Doctoral Dissertation). University of British Columbia. Retrieved from http://hdl.handle.net/2429/20913

Chicago Manual of Style (16^th Edition):

Plackett, David Victor. “Activation of carbon monoxide by ruthenium carbonyl complexes in solution.” 1977. Doctoral Dissertation, University of British Columbia. Accessed March 06, 2021. http://hdl.handle.net/2429/20913.

MLA Handbook (7^th Edition):

Plackett, David Victor. “Activation of carbon monoxide by ruthenium carbonyl complexes in solution.” 1977. Web. 06 Mar 2021.

Vancouver:

Plackett DV. Activation of carbon monoxide by ruthenium carbonyl complexes in solution. [Internet] [Doctoral dissertation]. University of British Columbia; 1977. [cited 2021 Mar 06]. Available from: http://hdl.handle.net/2429/20913.

Council of Science Editors:

Plackett DV. Activation of carbon monoxide by ruthenium carbonyl complexes in solution. [Doctoral Dissertation]. University of British Columbia; 1977. Available from: http://hdl.handle.net/2429/20913

Utah State University

29. Anderson, Stacey N. Carbon Monoxide on Demand: Light-Induced CO Release of Flavonols.

Degree: PhD, Chemistry and Biochemistry, 2018, Utah State University

URL: https://digitalcommons.usu.edu/etd/7388

► Carbon monoxide (CO) is an extremely useful molecule with applications in industrial manufacturing, synthetic procedures as a C1 building block, and as a potential… (more)

Subjects/Keywords: carbon; monoxide; light; co-release; flavonols; Chemistry

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APA (6^th Edition):

Anderson, S. N. (2018). Carbon Monoxide on Demand: Light-Induced CO Release of Flavonols. (Doctoral Dissertation). Utah State University. Retrieved from https://digitalcommons.usu.edu/etd/7388

Chicago Manual of Style (16^th Edition):

Anderson, Stacey N. “Carbon Monoxide on Demand: Light-Induced CO Release of Flavonols.” 2018. Doctoral Dissertation, Utah State University. Accessed March 06, 2021. https://digitalcommons.usu.edu/etd/7388.

MLA Handbook (7^th Edition):

Anderson, Stacey N. “Carbon Monoxide on Demand: Light-Induced CO Release of Flavonols.” 2018. Web. 06 Mar 2021.

Vancouver:

Anderson SN. Carbon Monoxide on Demand: Light-Induced CO Release of Flavonols. [Internet] [Doctoral dissertation]. Utah State University; 2018. [cited 2021 Mar 06]. Available from: https://digitalcommons.usu.edu/etd/7388.

Council of Science Editors:

Anderson SN. Carbon Monoxide on Demand: Light-Induced CO Release of Flavonols. [Doctoral Dissertation]. Utah State University; 2018. Available from: https://digitalcommons.usu.edu/etd/7388

The Ohio State University

30. Thiede, Frederick Clayton. Pulmonary and cardiovascular response mechanisms in dogs during inhalation of low concentrations of carbon monoxide .

Degree: PhD, Graduate School, 1959, The Ohio State University

URL: http://rave.ohiolink.edu/etdc/view?acc_num=osu1486731881015021

Subjects/Keywords: Biology; Carbon monoxide

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APA (6^th Edition):

Thiede, F. C. (1959). Pulmonary and cardiovascular response mechanisms in dogs during inhalation of low concentrations of carbon monoxide . (Doctoral Dissertation). The Ohio State University. Retrieved from http://rave.ohiolink.edu/etdc/view?acc_num=osu1486731881015021

Chicago Manual of Style (16^th Edition):

Thiede, Frederick Clayton. “Pulmonary and cardiovascular response mechanisms in dogs during inhalation of low concentrations of carbon monoxide .” 1959. Doctoral Dissertation, The Ohio State University. Accessed March 06, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=osu1486731881015021.

MLA Handbook (7^th Edition):

Thiede, Frederick Clayton. “Pulmonary and cardiovascular response mechanisms in dogs during inhalation of low concentrations of carbon monoxide .” 1959. Web. 06 Mar 2021.

Vancouver:

Thiede FC. Pulmonary and cardiovascular response mechanisms in dogs during inhalation of low concentrations of carbon monoxide . [Internet] [Doctoral dissertation]. The Ohio State University; 1959. [cited 2021 Mar 06]. Available from: http://rave.ohiolink.edu/etdc/view?acc_num=osu1486731881015021.

Council of Science Editors:

Thiede FC. Pulmonary and cardiovascular response mechanisms in dogs during inhalation of low concentrations of carbon monoxide . [Doctoral Dissertation]. The Ohio State University; 1959. Available from: http://rave.ohiolink.edu/etdc/view?acc_num=osu1486731881015021

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