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You searched for id:"tud:oai:tudelft.nl:uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf". One record found.

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Delft University of Technology

1. Meeusen, M. The importance of the time-effect in electrochemical studies of corrosion inhibitors.

Degree: 2020, Delft University of Technology

The corrosion protection of metallic substrates with corrosion inhibitors, either in solution or dispersed in a coating formulation, has been the focus of many research topics for many decades and has intensified in recent years even more with industry moving away from hexavalent chromium (Cr(VI))- based corrosion inhibitors. While mainly concentrating on the electrochemical behaviour and the underlying corrosion protective mechanism, the study of the time-effect, i.e. the study of how the electrochemical system behaves and the stabilization of the electrochemical system is altered over time, is often not taken into account when studying corrosion inhibitor-containing electrochemical systems. To gain a better understanding of the kinetic aspect of corrosion inhibitors changing the overall electrochemistry, this study focusses on the quantification of the time-effect of corrosion inhibitors’ electrochemical behaviour. Therefore odd random phase electrochemical impedance spectroscopy (ORP-EIS) is selected, a multisine alternative to the classical electrochemical impedance spectroscopy (EIS) technique, capable to measure and quantify the stability of electrochemical systems over time. Two different electrochemical systems are considered: lithium-based corrosion inhibitor technology on aluminium alloy AA2024-T3 and silica- and phosphate-based corrosion inhibitors for hot-dip galvanized steel. The former, already well-understood system, served as the proof of concept to design a well-defined methodology to study corrosion inhibitor-containing electrochemical systems, and gain deeper knowledge of the latter system. Advisors/Committee Members: Mol, J.M.C., Terryn, H.A., Delft University of Technology.

Subjects/Keywords: corrosion inhibitors; aluminium alloy AA2024-T3; galvanized steel; ORPEIS; (in)stability; time-effect

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APA · Chicago · MLA · Vancouver · CSE | Export to Zotero / EndNote / Reference Manager

APA (6th Edition):

Meeusen, M. (2020). The importance of the time-effect in electrochemical studies of corrosion inhibitors. (Doctoral Dissertation). Delft University of Technology. Retrieved from http://resolver.tudelft.nl/uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf ; urn:NBN:nl:ui:24-uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf ; 990fdc2d-bae1-4de2-9ac1-3f649bb980cf ; 10.4233/uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf ; urn:isbn:978-94-6332-615-5 ; urn:NBN:nl:ui:24-uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf ; http://resolver.tudelft.nl/uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf

Chicago Manual of Style (16th Edition):

Meeusen, M. “The importance of the time-effect in electrochemical studies of corrosion inhibitors.” 2020. Doctoral Dissertation, Delft University of Technology. Accessed June 01, 2020. http://resolver.tudelft.nl/uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf ; urn:NBN:nl:ui:24-uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf ; 990fdc2d-bae1-4de2-9ac1-3f649bb980cf ; 10.4233/uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf ; urn:isbn:978-94-6332-615-5 ; urn:NBN:nl:ui:24-uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf ; http://resolver.tudelft.nl/uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf.

MLA Handbook (7th Edition):

Meeusen, M. “The importance of the time-effect in electrochemical studies of corrosion inhibitors.” 2020. Web. 01 Jun 2020.

Vancouver:

Meeusen M. The importance of the time-effect in electrochemical studies of corrosion inhibitors. [Internet] [Doctoral dissertation]. Delft University of Technology; 2020. [cited 2020 Jun 01]. Available from: http://resolver.tudelft.nl/uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf ; urn:NBN:nl:ui:24-uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf ; 990fdc2d-bae1-4de2-9ac1-3f649bb980cf ; 10.4233/uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf ; urn:isbn:978-94-6332-615-5 ; urn:NBN:nl:ui:24-uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf ; http://resolver.tudelft.nl/uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf.

Council of Science Editors:

Meeusen M. The importance of the time-effect in electrochemical studies of corrosion inhibitors. [Doctoral Dissertation]. Delft University of Technology; 2020. Available from: http://resolver.tudelft.nl/uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf ; urn:NBN:nl:ui:24-uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf ; 990fdc2d-bae1-4de2-9ac1-3f649bb980cf ; 10.4233/uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf ; urn:isbn:978-94-6332-615-5 ; urn:NBN:nl:ui:24-uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf ; http://resolver.tudelft.nl/uuid:990fdc2d-bae1-4de2-9ac1-3f649bb980cf

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